The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques

Alzadma Himed; Mousa May; Balhassn Ali

doi:doi:10.11648/j.ajmme.20200402.11

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The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques

Alzadma Himed, Mousa May, Balhassn Ali

Published in American Journal of Mechanical and Materials Engineering (Volume 4, Issue 2)

Received: 15 February 2020 Accepted: 9 March 2020 Published: 12 May 2020

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Abstract

Dolomite known as dolostone is a double carbonate of calcium and magnesium, CaCO₃. MgCO₃. After calcite, it is the second most important and abundant of the carbonate minerals. This work aims at processing, investigation and characterization of four different Libyan raw dolomite samples via simple chemical method. Based on a previous geological survey carried out by the industrial research centre (Tripoli), four dolomite samples selected from different locations of Libya namely; El-azizia, Souk El-khamees (sample P1), Nalout, Abu Rashada route, Gherian (sample P2), Sedi El-said, Abu Reshada route, El-gabl El-gharby (sample P3) and Abu Ghilan, north Kaf- Takoot (sample P4), were processed (crushed, ground and sieved), then investigated through their chemical composition using x-ray fluorescence (XRF) technique. Their mineralogical compositions were investigated using x-ray diffraction technique (XRD) and scanning electron microscope (SEM). All the measurement techniques in this work indicated that qualitatively the four investigated samples have a dolomitic nature. It was conformed that the percent of CaO in sample P1 (31.19%) is relatively higher than the standard dolomite (30.8%) which confirms the prediction of the presence of some content of calcite CaCO₃ accompanied with dolomite sample P1. In spite of the limited variance in the chemical constitutions determined by x-ray fluorescence compared with classical wet method, the results confirm that the four investigated samples are mainly dolomite and that samples P1 and P2 are relatively purer than samples P3 and P4 which contain larger contents of Fe₂O₃, Al₂O₃ and SiO₂.

Published in	American Journal of Mechanical and Materials Engineering (Volume 4, Issue 2)
DOI	10.11648/j.ajmme.20200402.11
Page(s)	18-25
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Dolomite, X-ray Diffraction XRD, X-ray Fluorescence XRF, CaCO₃

References

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[2]	M. Mehmood, M. Yaseen, E. U. Khan and M. J. Khan, 2018 ”Dolomite and dolomitization model - a short review” Journal of advanced applied geology, Vol. 2, No. 5, pp: 549‒553.
[3]	T. Pichler and J. D. Humphrey, 2001 “Formation of Dolomite in Recent Island-Arc Sediments due to Gas-Seawater-Sediment Interaction: Errata” Journal of Sedimentary Research, vol. 7, No. 6, pp 394-399.
[4]	J. C. Frye, Ph. D., D. Sc, Chief, 1967 “Handbook on limestone and dolomite for Illinois quarry operators” State Geological Survey, Printed by Authority of State of Illinois, Ch. 127, IRS, Par. 58.25
[5]	J. John and S. Edwin, 2007 “Chemistry, microstructure, and reduction characteristics of dolomite-fluxed magnetite pellets” Metallurgical and Materials Transactions B, vol. 11, No. 2, pp. 233-243,.
[6]	Li W, Liu L, Chen W et al. (2010) “Calcium carbonate precipitation and crystal morphology induced by microbial carbonic anhydrase and other biological factors” Process Biochem, No 45, pp1017-1021.
[7]	A. Royani, E. Sulistiyono, A. B. Prasetiyo and R. Subagja, 2018 “Extraction of magnesium from calcined dolomite ore using hydrochloric acid leaching” AIP Conference Proceedings, vol. 1964, No, 1, 020017; https://doi.org/10.1063/1.5038299.
[8]	R. Agila, N. Khalil and H. Othman, 2008 “Mineralogical Study And Evaluation Of Some South Libya-Clays As A Source Of Al2O3 Extraction”, Journal of Sebha University-(Pure and Applied Sciences)-Vol. 7 No. 1, pp 14-33.
[9]	F. H. Norton, 1974“Elements of ceramics, Addison-Wisely series in metallurgy and materials” 2nd Edition, 311 pages.
[10]	J. George, Simandl, D. Nicole Robinson and S. Paradis, 2007 “Dolomite in British Columbia: Geology, current producers and possible development opportunities along the west coast” pp. 197-203.
[11]	X. Wen, W. Pan and Q. Tan, 2015 “Development for dolomite national reference materials” International Conference on Information Sciences, Machinery, Materials and Energy (ICISMME 2015).
[12]	J. Coates, 2000 “Interpretation of Infrared Spectra, A Practical Approach, Encyclopedia of Analytical Chemistry” R. A, Meyers (Ed.) pp. 10815-10837.
[13]	K. H. Paula, A. Y. Mark, D. K Paul and H. G. Vicki, 2008 “Coupled infrared extinction spectra and size distribution measurements for several non-clay components of mineral dust aerosol” quartz, calcite, and dolomite, vol. 30, no. 115.
[14]	S. G. Strow, L. L. Hannon and S. E. Motteler, 2006 “Infrared dust spectral signatures from AIRS” Geophysical Research Letters 33, L 03801.
[15]	R. J. Reeder, 2000 “Constraints on Cation Order in Calcium-rich Sedimentary Dolomite” Aquatic Geochemistry, Vol. 6, No. 2, pp 213–226.
[16]	S. E. Kaczmarek, J. M. Gregg, D. L. Bish, H. G. Machel, B. W. Fouke, 2017 “Dolomite, Very High-Magnesium Calcite, And Microbes— Implications For the Microbial Model Of Dolomitization” Characterization and Modeling of Carbonates–Mountjoy Symposium 1, pp 1-14, DOI: https://doi.org/10.2110/sepmsp.109.01.
[17]	S. Gorg, 1980 “Chemistry, microstructure, and reduction characteristics of dolomite-fluxed magnetite pellets” J. Metallurgical and Materials Transactions B, vol. 11, no. 2.
[18]	H. Sijing, H. Keke, L. Jie and L. Yefang, 2014 “The relationship between dolomite textures and their formation temperature: a case study from the Permian-Triassic of the Sichuan Basin and the Lower Paleozoic of the Tarim Basin” Pet. Sci. vol. 11, pp 39-51.
[19]	S. Wei, H. Cui, Z. Jiang, H. Liu, H. He, N. Fang, 2015 “Biomineralization processes of calcite induced by bacteria isolated from marine sediments” Brazilian Journal of Microbiology vol. 46, No. 2, pp455-464.

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APA Style

Alzadma Himed, Mousa May, Balhassn Ali. (2020). The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques. American Journal of Mechanical and Materials Engineering, 4(2), 18-25. https://doi.org/10.11648/j.ajmme.20200402.11

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ACS Style

Alzadma Himed; Mousa May; Balhassn Ali. The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques. Am. J. Mech. Mater. Eng. 2020, 4(2), 18-25. doi: 10.11648/j.ajmme.20200402.11

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AMA Style

Alzadma Himed, Mousa May, Balhassn Ali. The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques. Am J Mech Mater Eng. 2020;4(2):18-25. doi: 10.11648/j.ajmme.20200402.11

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@article{10.11648/j.ajmme.20200402.11,
  author = {Alzadma Himed and Mousa May and Balhassn Ali},
  title = {The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques},
  journal = {American Journal of Mechanical and Materials Engineering},
  volume = {4},
  number = {2},
  pages = {18-25},
  doi = {10.11648/j.ajmme.20200402.11},
  url = {https://doi.org/10.11648/j.ajmme.20200402.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmme.20200402.11},
  abstract = {Dolomite known as dolostone is a double carbonate of calcium and magnesium, CaCO3. MgCO3. After calcite, it is the second most important and abundant of the carbonate minerals. This work aims at processing, investigation and characterization of four different Libyan raw dolomite samples via simple chemical method. Based on a previous geological survey carried out by the industrial research centre (Tripoli), four dolomite samples selected from different locations of Libya namely; El-azizia, Souk El-khamees (sample P1), Nalout, Abu Rashada route, Gherian (sample P2), Sedi El-said, Abu Reshada route, El-gabl El-gharby (sample P3) and Abu Ghilan, north Kaf- Takoot (sample P4), were processed (crushed, ground and sieved), then investigated through their chemical composition using x-ray fluorescence (XRF) technique. Their mineralogical compositions were investigated using x-ray diffraction technique (XRD) and scanning electron microscope (SEM). All the measurement techniques in this work indicated that qualitatively the four investigated samples have a dolomitic nature. It was conformed that the percent of CaO in sample P1 (31.19%) is relatively higher than the standard dolomite (30.8%) which confirms the prediction of the presence of some content of calcite CaCO3 accompanied with dolomite sample P1. In spite of the limited variance in the chemical constitutions determined by x-ray fluorescence compared with classical wet method, the results confirm that the four investigated samples are mainly dolomite and that samples P1 and P2 are relatively purer than samples P3 and P4 which contain larger contents of Fe2O3, Al2O3 and SiO2.},
 year = {2020}
}

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TY  - JOUR
T1  - The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques
AU  - Alzadma Himed
AU  - Mousa May
AU  - Balhassn Ali
Y1  - 2020/05/12
PY  - 2020
N1  - https://doi.org/10.11648/j.ajmme.20200402.11
DO  - 10.11648/j.ajmme.20200402.11
T2  - American Journal of Mechanical and Materials Engineering
JF  - American Journal of Mechanical and Materials Engineering
JO  - American Journal of Mechanical and Materials Engineering
SP  - 18
EP  - 25
PB  - Science Publishing Group
SN  - 2639-9652
UR  - https://doi.org/10.11648/j.ajmme.20200402.11
AB  - Dolomite known as dolostone is a double carbonate of calcium and magnesium, CaCO3. MgCO3. After calcite, it is the second most important and abundant of the carbonate minerals. This work aims at processing, investigation and characterization of four different Libyan raw dolomite samples via simple chemical method. Based on a previous geological survey carried out by the industrial research centre (Tripoli), four dolomite samples selected from different locations of Libya namely; El-azizia, Souk El-khamees (sample P1), Nalout, Abu Rashada route, Gherian (sample P2), Sedi El-said, Abu Reshada route, El-gabl El-gharby (sample P3) and Abu Ghilan, north Kaf- Takoot (sample P4), were processed (crushed, ground and sieved), then investigated through their chemical composition using x-ray fluorescence (XRF) technique. Their mineralogical compositions were investigated using x-ray diffraction technique (XRD) and scanning electron microscope (SEM). All the measurement techniques in this work indicated that qualitatively the four investigated samples have a dolomitic nature. It was conformed that the percent of CaO in sample P1 (31.19%) is relatively higher than the standard dolomite (30.8%) which confirms the prediction of the presence of some content of calcite CaCO3 accompanied with dolomite sample P1. In spite of the limited variance in the chemical constitutions determined by x-ray fluorescence compared with classical wet method, the results confirm that the four investigated samples are mainly dolomite and that samples P1 and P2 are relatively purer than samples P3 and P4 which contain larger contents of Fe2O3, Al2O3 and SiO2.
VL  - 4
IS  - 2
ER  -

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Author Information

Alzadma Himed

General Department, Faculty of Energy and Mining Eng., Sebha University, Sebha, Libya
Mousa May

General Department, Faculty of Energy and Mining Eng., Sebha University, Sebha, Libya
Balhassn Ali

College of Petroleum Engineering, Al-Jafra University, Zalla, Libya

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APA Style

Alzadma Himed, Mousa May, Balhassn Ali. (2020). The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques. American Journal of Mechanical and Materials Engineering, 4(2), 18-25. https://doi.org/10.11648/j.ajmme.20200402.11

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ACS Style

Alzadma Himed; Mousa May; Balhassn Ali. The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques. Am. J. Mech. Mater. Eng. 2020, 4(2), 18-25. doi: 10.11648/j.ajmme.20200402.11

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AMA Style

Alzadma Himed, Mousa May, Balhassn Ali. The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques. Am J Mech Mater Eng. 2020;4(2):18-25. doi: 10.11648/j.ajmme.20200402.11

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@article{10.11648/j.ajmme.20200402.11,
  author = {Alzadma Himed and Mousa May and Balhassn Ali},
  title = {The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques},
  journal = {American Journal of Mechanical and Materials Engineering},
  volume = {4},
  number = {2},
  pages = {18-25},
  doi = {10.11648/j.ajmme.20200402.11},
  url = {https://doi.org/10.11648/j.ajmme.20200402.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmme.20200402.11},
  abstract = {Dolomite known as dolostone is a double carbonate of calcium and magnesium, CaCO3. MgCO3. After calcite, it is the second most important and abundant of the carbonate minerals. This work aims at processing, investigation and characterization of four different Libyan raw dolomite samples via simple chemical method. Based on a previous geological survey carried out by the industrial research centre (Tripoli), four dolomite samples selected from different locations of Libya namely; El-azizia, Souk El-khamees (sample P1), Nalout, Abu Rashada route, Gherian (sample P2), Sedi El-said, Abu Reshada route, El-gabl El-gharby (sample P3) and Abu Ghilan, north Kaf- Takoot (sample P4), were processed (crushed, ground and sieved), then investigated through their chemical composition using x-ray fluorescence (XRF) technique. Their mineralogical compositions were investigated using x-ray diffraction technique (XRD) and scanning electron microscope (SEM). All the measurement techniques in this work indicated that qualitatively the four investigated samples have a dolomitic nature. It was conformed that the percent of CaO in sample P1 (31.19%) is relatively higher than the standard dolomite (30.8%) which confirms the prediction of the presence of some content of calcite CaCO3 accompanied with dolomite sample P1. In spite of the limited variance in the chemical constitutions determined by x-ray fluorescence compared with classical wet method, the results confirm that the four investigated samples are mainly dolomite and that samples P1 and P2 are relatively purer than samples P3 and P4 which contain larger contents of Fe2O3, Al2O3 and SiO2.},
 year = {2020}
}

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TY  - JOUR
T1  - The Characterization of Libyan Raw Dolomite Samples Using Chemical Techniques
AU  - Alzadma Himed
AU  - Mousa May
AU  - Balhassn Ali
Y1  - 2020/05/12
PY  - 2020
N1  - https://doi.org/10.11648/j.ajmme.20200402.11
DO  - 10.11648/j.ajmme.20200402.11
T2  - American Journal of Mechanical and Materials Engineering
JF  - American Journal of Mechanical and Materials Engineering
JO  - American Journal of Mechanical and Materials Engineering
SP  - 18
EP  - 25
PB  - Science Publishing Group
SN  - 2639-9652
UR  - https://doi.org/10.11648/j.ajmme.20200402.11
AB  - Dolomite known as dolostone is a double carbonate of calcium and magnesium, CaCO3. MgCO3. After calcite, it is the second most important and abundant of the carbonate minerals. This work aims at processing, investigation and characterization of four different Libyan raw dolomite samples via simple chemical method. Based on a previous geological survey carried out by the industrial research centre (Tripoli), four dolomite samples selected from different locations of Libya namely; El-azizia, Souk El-khamees (sample P1), Nalout, Abu Rashada route, Gherian (sample P2), Sedi El-said, Abu Reshada route, El-gabl El-gharby (sample P3) and Abu Ghilan, north Kaf- Takoot (sample P4), were processed (crushed, ground and sieved), then investigated through their chemical composition using x-ray fluorescence (XRF) technique. Their mineralogical compositions were investigated using x-ray diffraction technique (XRD) and scanning electron microscope (SEM). All the measurement techniques in this work indicated that qualitatively the four investigated samples have a dolomitic nature. It was conformed that the percent of CaO in sample P1 (31.19%) is relatively higher than the standard dolomite (30.8%) which confirms the prediction of the presence of some content of calcite CaCO3 accompanied with dolomite sample P1. In spite of the limited variance in the chemical constitutions determined by x-ray fluorescence compared with classical wet method, the results confirm that the four investigated samples are mainly dolomite and that samples P1 and P2 are relatively purer than samples P3 and P4 which contain larger contents of Fe2O3, Al2O3 and SiO2.
VL  - 4
IS  - 2
ER  -

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