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Preparation and Properties of Flame Retardant ABS/POK Alloy

Received: 9 March 2020     Accepted: 23 March 2020     Published: 14 April 2020
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Abstract

Background ABS material has excellent mechanical properties, but its solvent resistance is poor. Acid solvents are prone to cracking, which will affect the normal use of the product. Technical research is needed to improve this performance defect and solve the technical bottleneck of poor solvent resistance of ABS material, so as to meet the technical demand of energy and other fields and improve the market application field of ABS material. Subject Using ABS and POK resin alloy as matrix resin, a high performance flame retardant ABS alloy material was prepared by developing a high efficiency flame retardant system of brominated antimony. Methods The mechanical properties, crystallization behavior, wear resistance, solvent resistance and heat resistance of the alloy materials were characterized by Fourier infrared spectroscopy, differential scanning calorimeter, universal testing machine, scanning electron microscope and friction tester. Result ABS has a good compatibility with POK, and the alloy material containing 20% POK has excellent mechanical properties and heat resistance, good ice acetic acid resistance and excellent solvent resistance. Through the DSC curve of the alloy material, the relationship between the melting peak area and the content of POK resin was obtained. POK resin can significantly improve the wear resistance of ABS and has a good glossiness retention rate.

Published in American Journal of Mechanical and Materials Engineering (Volume 4, Issue 1)
DOI 10.11648/j.ajmme.20200401.12
Page(s) 12-17
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

POK, Flame Retardant Alloy, Solvent Resistance, Wear Resistance

References
[1] Lei W, Bin S, Enzhu H, Kunhong H, Xianguo H. Reuse of spent bleaching clay for supporting MoS2 nanoparticles as a lubricating filler in ABS plastics [J]. Tribology International. 2019, 131 (000): 415-423.
[2] Se Lyn Kim; Min Young Liyu. Adhesive strengths between glass fiber-filled ABS and metal in insert molding with engraved and embossed metal surface treatments [J]. Polymer Engineering and Science. 2019, 59 (Sup1): E93-E100.
[3] J. H. H. Rossato; H. G. Lemos; G. L. Mantovani. The influence of viscosity and composition of ABS on the ABS/SBS blend morphology and properties [J]. Journal of Applied Polymer Science. 2019, 136 (8): 4707-47075.
[4] Braga N F, LaChance A M, Liu B, et al. Influence of compatibilizer and carbon nanotubes on mechanical, electrical, and barrier properties of PTT/ABS blends [J]. Advanced Industrial and Engineering Polymer Research, 2019, 2 (3): 121-125.
[5] Wen Y D, Fang L U, Mei F H, Jun Q Z, Heng T W. Yong J L. Phenomenon of LCST-type phase behavior in SAN/PMMA systems and its effect on the PLLA/ABS blend compatibilized by PMMA-type polymers: Interface stabilization or micelle formation [J]. Polymer. 2019, 163 (000): 36-47.
[6] S Singh, N Singh, M Gupta, C Prakash, R Singh. Mechanical feasibility of ABS/HIPS-based multi-material structures primed by low-cost polymer printer [J]. Rapid Prototyping Journal. 2019, 25 (1): 152-161.
[7] A Olad, L Ranjbarian. Influence of natural clinoptilolite nanoparticles on thermal stability, scratch resistance and adherence properties of Acrylonitrile butadiene styrene (ABS) [J]. Fibers and Polymers. 2013, 14 (3): 447-452.
[8] S. M. Hosseini, S. S. Madaeni, A. R. Khodabakhshi. Preparation and characterization of ABS/HIPS heterogeneous anion exchange membrane filled with activated carbon [J]. Journal of Applied Polymer Science. 2010, 118 (6): 3371-3383.
[9] Oluwakayode B, Gbadebo O, Mulugeta A H., Jaret C R. The influence of load direction, microstructure, raster orientation on the quasi-static response of fused deposition modeling ABS [J]. Rapid Prototyping Journal. 2019, 25 (3): 462-472.
[10] Li, H. M., Fouracre, R. A., Crichton, B. H., Banks, V. A. The influence of ions on the thermally stimulated discharge current spectra of water-treed additive-free low-density polyethylene [J]. Dielectrics and Electrical Insulation, IEEE Transactions on. 1994, 1 (6): 1084-1093.
[11] Stringari G B., Zupančič B, Kubyshkina G, et al. Time-dependent properties of bimodal POM—Application in powder injection molding [J]. Powder Technology, 2011, 208 (3): 590-595.
[12] Uthaman N, Majeed A. Impact modification of polyoxymethyl-ene (POM) [J]. e-Polymers, 2006, 6 (1) 34-42.
[13] Arslan C, Dogan M. Effect of fiber amount on mechanical and thermal properties of (3-aminopropyl) triethoxysilane treated basalt fiber reinforced ABS composites [J]. Materials Research Express, 2019, 6 (11): 115-122.
[14] Chang B P., Mohanty A K., Misra M. Sustainable biocarbon as an alternative of traditional fillers for poly (butylene terephthalate)-based composites: Thermo-oxidative aging and durability [J]. Journal of Applied Polymer Science, 2019, 136 (27): 477-482.
[15] Frank, Z. Michael B. Fracture of a saddle fusion (weld) joint in high density polyethylene (HDPE) pipe [J]. Engineering Failure Analysis. 2017, 82 (000): 481-492.
[16] Olad A, Ranjbarian L. Influence of natural clinoptilolite nanoparticles on thermal stability, scratch resistance and adherence properties of Acrylonitrile butadiene styrene (ABS) [J]. Fibers and Polymers, 2013, 14 (3): 447-452.
[17] Fu Z, Mao Y, Li S, et al. Preparation and characterization of ABS and copper (II) sulfate coordination composites by planetary ball mill [J]. Polymer Bulletin, 2018, 75 (2): 453-468.
[18] Hosseini S M., Madaeni S S., Khodabakhshi A R. Preparation and characterization of ABS/HIPS heterogeneous anion exchange membrane filled with activated carbon [J]. Journal of Applied Polymer Science, 2010, 118 (6): 3371-3383.
[19] Li H L., Zhang L X., Ding X L. Effect of PP-g-MAH on Properties of ABS/PP Blends [C]. Applied Mechanics and Materials. Trans Tech Publications Ltd, 2015, 727: 313-317.
[20] Zhang J. Research on thermostability of flame-retardant PC/ABS-Blends with PyGC [J]. Procedia Eng, 2016, 135: 83-89.
[21] Kim S L., Lyu M Y. Adhesive strengths between glass fiber-filled ABS and metal in insert molding with engraved and embossed metal surface treatments [J]. Polymer Engineering & Science, 2019, 59 (S1): E93-E100.
[22] Kumar R M., Rajini N, Mayandi K, et al. Friction and wear properties of PTFE blended ABS polymer composite [C]. AIP Conference Proceedings. AIP Publishing LLC, 2019, 2057 (1): 75-83.
Cite This Article
  • APA Style

    Wangping Qin, Jingfeng Fu, Xiaoyun Yang, Nanbiao Ye. (2020). Preparation and Properties of Flame Retardant ABS/POK Alloy. American Journal of Mechanical and Materials Engineering, 4(1), 12-17. https://doi.org/10.11648/j.ajmme.20200401.12

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    ACS Style

    Wangping Qin; Jingfeng Fu; Xiaoyun Yang; Nanbiao Ye. Preparation and Properties of Flame Retardant ABS/POK Alloy. Am. J. Mech. Mater. Eng. 2020, 4(1), 12-17. doi: 10.11648/j.ajmme.20200401.12

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    AMA Style

    Wangping Qin, Jingfeng Fu, Xiaoyun Yang, Nanbiao Ye. Preparation and Properties of Flame Retardant ABS/POK Alloy. Am J Mech Mater Eng. 2020;4(1):12-17. doi: 10.11648/j.ajmme.20200401.12

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  • @article{10.11648/j.ajmme.20200401.12,
      author = {Wangping Qin and Jingfeng Fu and Xiaoyun Yang and Nanbiao Ye},
      title = {Preparation and Properties of Flame Retardant ABS/POK Alloy},
      journal = {American Journal of Mechanical and Materials Engineering},
      volume = {4},
      number = {1},
      pages = {12-17},
      doi = {10.11648/j.ajmme.20200401.12},
      url = {https://doi.org/10.11648/j.ajmme.20200401.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmme.20200401.12},
      abstract = {Background ABS material has excellent mechanical properties, but its solvent resistance is poor. Acid solvents are prone to cracking, which will affect the normal use of the product. Technical research is needed to improve this performance defect and solve the technical bottleneck of poor solvent resistance of ABS material, so as to meet the technical demand of energy and other fields and improve the market application field of ABS material. Subject Using ABS and POK resin alloy as matrix resin, a high performance flame retardant ABS alloy material was prepared by developing a high efficiency flame retardant system of brominated antimony. Methods The mechanical properties, crystallization behavior, wear resistance, solvent resistance and heat resistance of the alloy materials were characterized by Fourier infrared spectroscopy, differential scanning calorimeter, universal testing machine, scanning electron microscope and friction tester. Result ABS has a good compatibility with POK, and the alloy material containing 20% POK has excellent mechanical properties and heat resistance, good ice acetic acid resistance and excellent solvent resistance. Through the DSC curve of the alloy material, the relationship between the melting peak area and the content of POK resin was obtained. POK resin can significantly improve the wear resistance of ABS and has a good glossiness retention rate.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Preparation and Properties of Flame Retardant ABS/POK Alloy
    AU  - Wangping Qin
    AU  - Jingfeng Fu
    AU  - Xiaoyun Yang
    AU  - Nanbiao Ye
    Y1  - 2020/04/14
    PY  - 2020
    N1  - https://doi.org/10.11648/j.ajmme.20200401.12
    DO  - 10.11648/j.ajmme.20200401.12
    T2  - American Journal of Mechanical and Materials Engineering
    JF  - American Journal of Mechanical and Materials Engineering
    JO  - American Journal of Mechanical and Materials Engineering
    SP  - 12
    EP  - 17
    PB  - Science Publishing Group
    SN  - 2639-9652
    UR  - https://doi.org/10.11648/j.ajmme.20200401.12
    AB  - Background ABS material has excellent mechanical properties, but its solvent resistance is poor. Acid solvents are prone to cracking, which will affect the normal use of the product. Technical research is needed to improve this performance defect and solve the technical bottleneck of poor solvent resistance of ABS material, so as to meet the technical demand of energy and other fields and improve the market application field of ABS material. Subject Using ABS and POK resin alloy as matrix resin, a high performance flame retardant ABS alloy material was prepared by developing a high efficiency flame retardant system of brominated antimony. Methods The mechanical properties, crystallization behavior, wear resistance, solvent resistance and heat resistance of the alloy materials were characterized by Fourier infrared spectroscopy, differential scanning calorimeter, universal testing machine, scanning electron microscope and friction tester. Result ABS has a good compatibility with POK, and the alloy material containing 20% POK has excellent mechanical properties and heat resistance, good ice acetic acid resistance and excellent solvent resistance. Through the DSC curve of the alloy material, the relationship between the melting peak area and the content of POK resin was obtained. POK resin can significantly improve the wear resistance of ABS and has a good glossiness retention rate.
    VL  - 4
    IS  - 1
    ER  - 

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Author Information
  • National Engineering Laboratory for Plastic Modification and Processing, Kingfa Science and Technology Co., Ltd., Guangzhou, China

  • National Engineering Laboratory for Plastic Modification and Processing, Kingfa Science and Technology Co., Ltd., Guangzhou, China

  • National Engineering Laboratory for Plastic Modification and Processing, Kingfa Science and Technology Co., Ltd., Guangzhou, China

  • National Engineering Laboratory for Plastic Modification and Processing, Kingfa Science and Technology Co., Ltd., Guangzhou, China

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