The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments

Eugene Ehidiamhen Yakubu; Chiedu Owabor

doi:doi:10.11648/j.ajese.20180204.12

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The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments

Eugene Ehidiamhen Yakubu, Chiedu Owabor

Published in American Journal of Environmental Science and Engineering (Volume 2, Issue 4)

Received: 12 November 2018 Accepted: 27 November 2018 Published: 14 January 2019

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Abstract

This study was aimed at evaluating the effect of mass transfer resistance to the transport of phenol in soil sediments. Batch adsorption experiments were conducted using phenol in homogenous soil sediments (clay and sand). The Physico-chemical properties of the soil sediments were determined and sorption behaviour kinetically modelled using the Pseudo-first order, Pseudo-second order, Intra-particle, Elovich, and Power function models. The sorption behaviour was best modelled with the intra-particle model (R² ˃ 0.9628). The rate limiting step and mass transfer resistance were determined by the Boyd plot, Homogenous pore diffusion model (HPDM) and the modified Furusawa -Smith equation. The Boyd plots indicated external mass transfer as the rate-determining step for the phenol/clay and phenol/sand systems; the HPDM model gave a poor fit (R² ≈ 0.6) for the phenol sorbate systems, corresponding with projections from the Boyd plots. From the results of the study, the rate controlling step for phenol sorption in the sediments was predominantly due to external mass transfer resistance. A comparative analysis between the two sediments using the Furusawa -Smith equation gave the mass transfer coefficients for clay and sand to be 2.09205E-14 m s⁻¹ and 4.17537E-12 m s⁻¹ respectively, showing that as the particle size decreased, the more significant the effect of external mass transfer effect on the sorption rate.

Published in	American Journal of Environmental Science and Engineering (Volume 2, Issue 4)
DOI	10.11648/j.ajese.20180204.12
Page(s)	56-64
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Contaminants, Adsorption, Sediment, Adsorbate, Adsorbent, Resistance

References

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[3]	Kookana, R. (2010). The Role of Biochar in Modifying the Environmental Fate, Bioavailability and Efficacy of Pesticides in Soils: A Review. Soil Research, 48 (7), 627-637.
[4]	Gebremariam, S. (2011). Mineralization, Sorption and De- sorption of Chlorpyrifos in Aquatic Sediments and Soils, Ph.D. Thesis. Pullman: Washington State University.
[5]	Owabor, C., Ogbeide, S., and Susu, A. (2010b). Adsorption and Desorption Kinetics of Naphthalene, Anthracene and Pyrene in Soil Matrix. Petroleum Science and Technology, 28 (5), 504-514.
[6]	Ding, L. (2010). Mechanisms Of Competitive Adsorption Between Trace Organic Contaminants And Natural Organic Matter On Activated Carbon,. Ph.D Dissertation Submitted To The University Of Illinois.
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[10]	Ghogomu J. N, Dieudonné, Estella N. Tamungang N B, Ajifack D. L., Ndi J. N, Ketcha M J (2014) Adsorption of phenol from aqueous solutions onto natural and thermallymodified kaolinitic materials Int. J. Biol. Chem. Sci. 8 (5): 2325-2338
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[15]	Djebbar M, Djafri. F, Bouchekara M. and Djafri A. (2012) Adsorption of phenol on natural clay African Journal of Pure and Applied Chemistry Vol. 6 (2), pp. 15-25,
[16]	Ahmad, M., Puad, N., and Bello, O. (2014). Kinetic, equilibrium and thermodynamic studies of synthetic dye removal using pomegranate peel activated carbon prepared by microwave-induced KOH activation. Water Res Ind, 10 (4), 234-345.
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APA Style

Eugene Ehidiamhen Yakubu, Chiedu Owabor. (2019). The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments. American Journal of Environmental Science and Engineering, 2(4), 56-64. https://doi.org/10.11648/j.ajese.20180204.12

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ACS Style

Eugene Ehidiamhen Yakubu; Chiedu Owabor. The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments. Am. J. Environ. Sci. Eng. 2019, 2(4), 56-64. doi: 10.11648/j.ajese.20180204.12

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AMA Style

Eugene Ehidiamhen Yakubu, Chiedu Owabor. The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments. Am J Environ Sci Eng. 2019;2(4):56-64. doi: 10.11648/j.ajese.20180204.12

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@article{10.11648/j.ajese.20180204.12,
  author = {Eugene Ehidiamhen Yakubu and Chiedu Owabor},
  title = {The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments},
  journal = {American Journal of Environmental Science and Engineering},
  volume = {2},
  number = {4},
  pages = {56-64},
  doi = {10.11648/j.ajese.20180204.12},
  url = {https://doi.org/10.11648/j.ajese.20180204.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajese.20180204.12},
  abstract = {This study was aimed at evaluating the effect of mass transfer resistance to the transport of phenol in soil sediments. Batch adsorption experiments were conducted using phenol in homogenous soil sediments (clay and sand). The Physico-chemical properties of the soil sediments were determined and sorption behaviour kinetically modelled using the Pseudo-first order, Pseudo-second order, Intra-particle, Elovich, and Power function models. The sorption behaviour was best modelled with the intra-particle model (R2 ˃ 0.9628). The rate limiting step and mass transfer resistance were determined by the Boyd plot, Homogenous pore diffusion model (HPDM) and the modified Furusawa -Smith equation. The Boyd plots indicated external mass transfer as the rate-determining step for the phenol/clay and phenol/sand systems; the HPDM model gave a poor fit (R2 ≈ 0.6) for the phenol sorbate systems, corresponding with projections from the Boyd plots. From the results of the study, the rate controlling step for phenol sorption in the sediments was predominantly due to external mass transfer resistance. A comparative analysis between the two sediments using the Furusawa -Smith equation gave the mass transfer coefficients for clay and sand to be 2.09205E-14 m s−1 and 4.17537E-12 m s−1 respectively, showing that as the particle size decreased, the more significant the effect of external mass transfer effect on the sorption rate.},
 year = {2019}
}

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TY  - JOUR
T1  - The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments
AU  - Eugene Ehidiamhen Yakubu
AU  - Chiedu Owabor
Y1  - 2019/01/14
PY  - 2019
N1  - https://doi.org/10.11648/j.ajese.20180204.12
DO  - 10.11648/j.ajese.20180204.12
T2  - American Journal of Environmental Science and Engineering
JF  - American Journal of Environmental Science and Engineering
JO  - American Journal of Environmental Science and Engineering
SP  - 56
EP  - 64
PB  - Science Publishing Group
SN  - 2578-7993
UR  - https://doi.org/10.11648/j.ajese.20180204.12
AB  - This study was aimed at evaluating the effect of mass transfer resistance to the transport of phenol in soil sediments. Batch adsorption experiments were conducted using phenol in homogenous soil sediments (clay and sand). The Physico-chemical properties of the soil sediments were determined and sorption behaviour kinetically modelled using the Pseudo-first order, Pseudo-second order, Intra-particle, Elovich, and Power function models. The sorption behaviour was best modelled with the intra-particle model (R2 ˃ 0.9628). The rate limiting step and mass transfer resistance were determined by the Boyd plot, Homogenous pore diffusion model (HPDM) and the modified Furusawa -Smith equation. The Boyd plots indicated external mass transfer as the rate-determining step for the phenol/clay and phenol/sand systems; the HPDM model gave a poor fit (R2 ≈ 0.6) for the phenol sorbate systems, corresponding with projections from the Boyd plots. From the results of the study, the rate controlling step for phenol sorption in the sediments was predominantly due to external mass transfer resistance. A comparative analysis between the two sediments using the Furusawa -Smith equation gave the mass transfer coefficients for clay and sand to be 2.09205E-14 m s−1 and 4.17537E-12 m s−1 respectively, showing that as the particle size decreased, the more significant the effect of external mass transfer effect on the sorption rate.
VL  - 2
IS  - 4
ER  -

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Author Information

Eugene Ehidiamhen Yakubu

Department of Chemical Engineering, University of Benin, Benin City, Nigeria
Chiedu Owabor

Department of Chemical Engineering, Federal University of Petroleum Resources Effurun, Effurun, Nigeria

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APA Style

Eugene Ehidiamhen Yakubu, Chiedu Owabor. (2019). The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments. American Journal of Environmental Science and Engineering, 2(4), 56-64. https://doi.org/10.11648/j.ajese.20180204.12

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ACS Style

Eugene Ehidiamhen Yakubu; Chiedu Owabor. The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments. Am. J. Environ. Sci. Eng. 2019, 2(4), 56-64. doi: 10.11648/j.ajese.20180204.12

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AMA Style

Eugene Ehidiamhen Yakubu, Chiedu Owabor. The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments. Am J Environ Sci Eng. 2019;2(4):56-64. doi: 10.11648/j.ajese.20180204.12

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@article{10.11648/j.ajese.20180204.12,
  author = {Eugene Ehidiamhen Yakubu and Chiedu Owabor},
  title = {The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments},
  journal = {American Journal of Environmental Science and Engineering},
  volume = {2},
  number = {4},
  pages = {56-64},
  doi = {10.11648/j.ajese.20180204.12},
  url = {https://doi.org/10.11648/j.ajese.20180204.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajese.20180204.12},
  abstract = {This study was aimed at evaluating the effect of mass transfer resistance to the transport of phenol in soil sediments. Batch adsorption experiments were conducted using phenol in homogenous soil sediments (clay and sand). The Physico-chemical properties of the soil sediments were determined and sorption behaviour kinetically modelled using the Pseudo-first order, Pseudo-second order, Intra-particle, Elovich, and Power function models. The sorption behaviour was best modelled with the intra-particle model (R2 ˃ 0.9628). The rate limiting step and mass transfer resistance were determined by the Boyd plot, Homogenous pore diffusion model (HPDM) and the modified Furusawa -Smith equation. The Boyd plots indicated external mass transfer as the rate-determining step for the phenol/clay and phenol/sand systems; the HPDM model gave a poor fit (R2 ≈ 0.6) for the phenol sorbate systems, corresponding with projections from the Boyd plots. From the results of the study, the rate controlling step for phenol sorption in the sediments was predominantly due to external mass transfer resistance. A comparative analysis between the two sediments using the Furusawa -Smith equation gave the mass transfer coefficients for clay and sand to be 2.09205E-14 m s−1 and 4.17537E-12 m s−1 respectively, showing that as the particle size decreased, the more significant the effect of external mass transfer effect on the sorption rate.},
 year = {2019}
}

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TY  - JOUR
T1  - The Effect of Mass Transfer Resistance on the Adsorption Rate of Phenol in Soil Sediments
AU  - Eugene Ehidiamhen Yakubu
AU  - Chiedu Owabor
Y1  - 2019/01/14
PY  - 2019
N1  - https://doi.org/10.11648/j.ajese.20180204.12
DO  - 10.11648/j.ajese.20180204.12
T2  - American Journal of Environmental Science and Engineering
JF  - American Journal of Environmental Science and Engineering
JO  - American Journal of Environmental Science and Engineering
SP  - 56
EP  - 64
PB  - Science Publishing Group
SN  - 2578-7993
UR  - https://doi.org/10.11648/j.ajese.20180204.12
AB  - This study was aimed at evaluating the effect of mass transfer resistance to the transport of phenol in soil sediments. Batch adsorption experiments were conducted using phenol in homogenous soil sediments (clay and sand). The Physico-chemical properties of the soil sediments were determined and sorption behaviour kinetically modelled using the Pseudo-first order, Pseudo-second order, Intra-particle, Elovich, and Power function models. The sorption behaviour was best modelled with the intra-particle model (R2 ˃ 0.9628). The rate limiting step and mass transfer resistance were determined by the Boyd plot, Homogenous pore diffusion model (HPDM) and the modified Furusawa -Smith equation. The Boyd plots indicated external mass transfer as the rate-determining step for the phenol/clay and phenol/sand systems; the HPDM model gave a poor fit (R2 ≈ 0.6) for the phenol sorbate systems, corresponding with projections from the Boyd plots. From the results of the study, the rate controlling step for phenol sorption in the sediments was predominantly due to external mass transfer resistance. A comparative analysis between the two sediments using the Furusawa -Smith equation gave the mass transfer coefficients for clay and sand to be 2.09205E-14 m s−1 and 4.17537E-12 m s−1 respectively, showing that as the particle size decreased, the more significant the effect of external mass transfer effect on the sorption rate.
VL  - 2
IS  - 4
ER  -

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