Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food

Almojtaba Abd Alkhalig Ahmed Bakheet; Xia Shi Zhu

doi:doi:10.11648/j.ajhc.20170306.12

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Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe₃O₄@SiO₂ Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu

Published in American Journal of Heterocyclic Chemistry (Volume 3, Issue 6)

Received: 26 October 2017 Accepted: 10 November 2017 Published: 13 December 2017

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Abstract

Hydrophobic ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM] PF₆) coated Fe₃O₄@SiO₂ nanoparticles was employed in magnetic solid phase extraction (MSPE) method coupled with ultraviolet visible spectrophotometry for the analysis of safranineT (ST). The results showed that safranineT was adsorbed fast by Fe₃O₄@SiO₂@[OMIM] PF₆ and eluted by ethanol. Different parameters, such as; pH, temperature, ionic strength, eluent type, volume and temperature were studied. This method introduced wide linear range of 15-350 ng mL^-1, the correlation coefficient was 0.9991, the equations of calibration graph was A (absorbance) = 0.04+0.13c (g mL^-1), the detection limit was 0.37 ng mL^-1 (RSD = 5.1%). The current method could be applied for the analysis of ST in food samples with satisfactory results.

Published in	American Journal of Heterocyclic Chemistry (Volume 3, Issue 6)
DOI	10.11648/j.ajhc.20170306.12
Page(s)	67-73
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Safranine T, Ionic Liquid Loaded Magnetic Nanoparticles, Magnetic Solid Phase Extraction, UV- Spectrophotometry

References

[1]	Ding X P, Tang D B, Li T, Wang S F& Zhou, YY. (2011). A novel spectrofluorometric method for the determination of methiocarb using an amphiphilic p-sulfonatocalix [4] arene. Spectrochim. Acta, PartA. 81:44–47.
[2]	Liu Q, Shi J B, Wang T, Guo F, Liu L H & Jiang G B.(2012) Hemimicelles/admicelles supported on magnetic grapheme sheets for enhanced magnetic solid-phase extraction, J.Chromatogr.A.1257:1–8.
[3]	Kirsch P, Fleig I, Frentzel-Beyme R, Gembardt C, Steinborn J, Thiess A M., et al. (1978) Ar-beitsmed. Sozialmed. Pr/iventivmed, 13:1-28.
[4]	Ministry of Health of the People's Republic of China (2008) The China National Standardization Management Committee: Hygienic standards for uses of food additives (GB2760-2007). Standards Press of China.
[5]	IARC. Monographs on the evaluation of carcinogenic risk to humans. (1987)118:1–42.
[6]	Jiang H M, Yang T, Wang Y H, Lian H Z, & Hu X. (2013) Magnetic solid-phase extraction combined with graphite furnace atomic absorption spectrometry for speciation of Cr (III) and Cr (VI) in environmental waters. Talanta, 116: 361–367.
[7]	Mashhadizadeh MH &Amoli-Diva Pourghazi M K. (2013) Magnetic nanoparticles solid phase extraction for determination of ochratoxin A in cereals using high-performance liquid chromatography with fluorescence detection, J. Chromatogr. A. 1320: 17–26.
[8]	Rastkari N, Ahmadkhaniha R. (2013) Magnetic solid-phase extraction based onmagnetic multi-walled carbon nanotubes for the determination of phthalatemonoesters in urine samples, J. Chromatogr. A, 1286: 22–28.
[9]	Galan-Cano F, Alcudia-Leon Mdel C, Lucena R, Cardenas S, ValcarcelM. (2013) Dispersive micro-solid phase extraction with ionic liquid-modified silica for the determination of organophosphate pesticides in water by ultra performance liquid chromatography, Microchem. J. 106: 311-317.
[10]	Dupont, J, de Souza RF, Suarez PAZ. (2002) Ionic liquid (molten salt) phase organo- metallic catalysis, Chem. Rev. 102: 3667–3692.
[11]	Liu X D, Yu Y J, Zhao M Y, Zhang H Y, Li Y, &Duan G L. (2014) Solid phase extraction using magnetic core mesoporous shell microspheres with C18-modified interior pore-walls for residue analysis of cephalosporins in milk by LC-MS/MS. Food Chem. 150: 206–212.
[12]	Vidal L, Riekkola ML & Canals A. (2012) Ionic liquid-modified materials for solid-phaseextraction and separation, Anal. Chim. Acta, 715: 19–41.
[13]	Fontanals N, Borrull F & Marcé RM. (2012) Ionic liquids in solid-phase extraction, Trends Anal. Chem. 41: 15–26.
[14]	Gao Q, Zheng H B, Luo D, Ding J, & Feng YQ. (2012) Facile synthesis of magnetic one-dimensional polyaniline and its application in magnetic solid phase extraction for fluoroquinolones in honey samples. Anal. Chim. Acta 720: 57–62.
[15]	Pardasani D, Kanaujia PK, Purohit A K, Shrivastava A R, Dubey DK. (2011) Magnetic multi-walled carbon nanotubes assisted dispersive solid phase extraction of nerve agents and their markers from muddy water. Talanta, 86: 248–255.
[16]	Dzyuba SV, & Bartsch RA. (2001) Efficient synthesis of 1-alkyl (aralkyl)-3-methyl (ethyl) imidazolium halids: precursors for room-temperature ionic liquids. Journal of Heteroc. Chem. 38: 265–268.
[17]	Tokuda H, Hayamizu K, Ishii K, Susan MABH, Tsuzuki S, Hayamizu K, & Watanabe M. (2004) Physicochemical properties and structures of room temperature ionic liquids. 1. variation of anionic species. J. Physic. Chem. B. 108: 16593–16600.
[18]	Hong RY, Zhang S Z, Han Y P, Li HZ, Ding J, & Zheng Y. (2006) Preparation, characterization and application of bilayer surfactant-stabilized ferrofluids. Powder Technol. 170: 1–11.
[19]	Hou YH, Han XY, Chen J, Li Z L, Chen XC, &Gai, LG. (2013) Isolation of PCR-ready genomic DNA from Aspergillus niger cells with Fe3O4/SiO2 microspheres. Sep. Purif. Technol. 116: 101–106.
[20]	Zhao X, Shi Y, Wang T, Cai Y & Jiang G. (2008) Preparation of silica-magnetite nanoparticle mixed hemimicelle sorbents for extraction of several typical phenolic compounds from environmental water samples J. Chromatogr. A. 1188: 140–147.
[21]	Chen, J. P., & Zhu, X. S. (2015) Ionic liquid coated magnetic core/shell Fe₃O₄@SiO₂ nanoparticles for the separation/analysis of linuron in food samples SpectrochimicaActa Part A: 137. 456–462.
[22]	Dang GF, Ma XG, & Zhou JP. (2012) Preparation of Silica-coated Magnetic Nanomaterials Modified with ionic liquid and its application in detection of trace cadmium ion in water. Chin. J. Instrumen. Anal. 7: 823–827.
[23]	Ho TD, Canestraro AJ & Anderson JL. (2011) Ionic liquids in solid-phase microextraction: a review, Anal. Chim. Acta. 695: 18-43.
[24]	Hu YQ, Guo T, Ye X S, Li Q, Guo M, Liu H N, & Wu Z J. (2013) Dye adsorption by resins: Effect of ionic strength on hydrophobic and electrostatic interactions. Chem. Eng. J. 228: 392-397.
[25]	Ho T D, Cole W T S, Augusto F, & Anderson J L. (2013) Insight into the extraction mechanism of polymeric ionic liquid sorbent coatings in solid-phase microextraction. J. of Chromatogr. A. 1298: 146-151.
[26]	He S K. (2009). Determination of safranine T in food by high performance liquid chromatography. Fujian Analysis & Testing; 2: 9–11.
[27]	Zheng X Y. (2009) Determination of safranine T in foods by ultra performance liquid chromatography-tandem mass spectrometry. J. Fuzhou Univ. 37, 752–755.
[28]	Wang WJ, Zhu X S & Yan CG. (2013) Determination of safranine T in food samples by CTAB sensitized fluorescence quenching method of the derivatives of calix [4] arene Food Chem. 141: 2207-2212.

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APA Style

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. (2017). Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food. American Journal of Heterocyclic Chemistry, 3(6), 67-73. https://doi.org/10.11648/j.ajhc.20170306.12

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ACS Style

Almojtaba Abd Alkhalig Ahmed Bakheet; Xia Shi Zhu. Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food. Am. J. Heterocycl. Chem. 2017, 3(6), 67-73. doi: 10.11648/j.ajhc.20170306.12

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AMA Style

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food. Am J Heterocycl Chem. 2017;3(6):67-73. doi: 10.11648/j.ajhc.20170306.12

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@article{10.11648/j.ajhc.20170306.12,
  author = {Almojtaba Abd Alkhalig Ahmed Bakheet and Xia Shi Zhu},
  title = {Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {3},
  number = {6},
  pages = {67-73},
  doi = {10.11648/j.ajhc.20170306.12},
  url = {https://doi.org/10.11648/j.ajhc.20170306.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20170306.12},
  abstract = {Hydrophobic ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM] PF6) coated Fe3O4@SiO2 nanoparticles was employed in magnetic solid phase extraction (MSPE) method coupled with ultraviolet visible spectrophotometry for the analysis of safranineT (ST). The results showed that safranineT was adsorbed fast by Fe3O4@SiO2@[OMIM] PF6 and eluted by ethanol. Different parameters, such as; pH, temperature, ionic strength, eluent type, volume and temperature were studied. This method introduced wide linear range of 15-350 ng mL-1, the correlation coefficient was 0.9991, the equations of calibration graph was A (absorbance) = 0.04+0.13c (g mL-1), the detection limit was 0.37 ng mL-1 (RSD = 5.1%). The current method could be applied for the analysis of ST in food samples with satisfactory results.},
 year = {2017}
}

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TY  - JOUR
T1  - Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food
AU  - Almojtaba Abd Alkhalig Ahmed Bakheet
AU  - Xia Shi Zhu
Y1  - 2017/12/13
PY  - 2017
N1  - https://doi.org/10.11648/j.ajhc.20170306.12
DO  - 10.11648/j.ajhc.20170306.12
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 67
EP  - 73
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20170306.12
AB  - Hydrophobic ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM] PF6) coated Fe3O4@SiO2 nanoparticles was employed in magnetic solid phase extraction (MSPE) method coupled with ultraviolet visible spectrophotometry for the analysis of safranineT (ST). The results showed that safranineT was adsorbed fast by Fe3O4@SiO2@[OMIM] PF6 and eluted by ethanol. Different parameters, such as; pH, temperature, ionic strength, eluent type, volume and temperature were studied. This method introduced wide linear range of 15-350 ng mL-1, the correlation coefficient was 0.9991, the equations of calibration graph was A (absorbance) = 0.04+0.13c (g mL-1), the detection limit was 0.37 ng mL-1 (RSD = 5.1%). The current method could be applied for the analysis of ST in food samples with satisfactory results.
VL  - 3
IS  - 6
ER  -

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Author Information

Almojtaba Abd Alkhalig Ahmed Bakheet

Department of Family Sciences, Faculty of Education, University of Khartoum, Khartoum, Sudan; College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, China
Xia Shi Zhu

College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, China

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APA Style

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. (2017). Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food. American Journal of Heterocyclic Chemistry, 3(6), 67-73. https://doi.org/10.11648/j.ajhc.20170306.12

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ACS Style

Almojtaba Abd Alkhalig Ahmed Bakheet; Xia Shi Zhu. Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food. Am. J. Heterocycl. Chem. 2017, 3(6), 67-73. doi: 10.11648/j.ajhc.20170306.12

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AMA Style

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food. Am J Heterocycl Chem. 2017;3(6):67-73. doi: 10.11648/j.ajhc.20170306.12

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@article{10.11648/j.ajhc.20170306.12,
  author = {Almojtaba Abd Alkhalig Ahmed Bakheet and Xia Shi Zhu},
  title = {Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {3},
  number = {6},
  pages = {67-73},
  doi = {10.11648/j.ajhc.20170306.12},
  url = {https://doi.org/10.11648/j.ajhc.20170306.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20170306.12},
  abstract = {Hydrophobic ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM] PF6) coated Fe3O4@SiO2 nanoparticles was employed in magnetic solid phase extraction (MSPE) method coupled with ultraviolet visible spectrophotometry for the analysis of safranineT (ST). The results showed that safranineT was adsorbed fast by Fe3O4@SiO2@[OMIM] PF6 and eluted by ethanol. Different parameters, such as; pH, temperature, ionic strength, eluent type, volume and temperature were studied. This method introduced wide linear range of 15-350 ng mL-1, the correlation coefficient was 0.9991, the equations of calibration graph was A (absorbance) = 0.04+0.13c (g mL-1), the detection limit was 0.37 ng mL-1 (RSD = 5.1%). The current method could be applied for the analysis of ST in food samples with satisfactory results.},
 year = {2017}
}

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TY  - JOUR
T1  - Magnetic Solid Phase Extraction Using Ionic Liquid Coated Magnetic Core Fe3O4@SiO2 Nanoparticles Followed by UV Spectrophotometry for Separation/Analysis of Safranine T in Food
AU  - Almojtaba Abd Alkhalig Ahmed Bakheet
AU  - Xia Shi Zhu
Y1  - 2017/12/13
PY  - 2017
N1  - https://doi.org/10.11648/j.ajhc.20170306.12
DO  - 10.11648/j.ajhc.20170306.12
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 67
EP  - 73
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20170306.12
AB  - Hydrophobic ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM] PF6) coated Fe3O4@SiO2 nanoparticles was employed in magnetic solid phase extraction (MSPE) method coupled with ultraviolet visible spectrophotometry for the analysis of safranineT (ST). The results showed that safranineT was adsorbed fast by Fe3O4@SiO2@[OMIM] PF6 and eluted by ethanol. Different parameters, such as; pH, temperature, ionic strength, eluent type, volume and temperature were studied. This method introduced wide linear range of 15-350 ng mL-1, the correlation coefficient was 0.9991, the equations of calibration graph was A (absorbance) = 0.04+0.13c (g mL-1), the detection limit was 0.37 ng mL-1 (RSD = 5.1%). The current method could be applied for the analysis of ST in food samples with satisfactory results.
VL  - 3
IS  - 6
ER  -

Copy | Download