Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl<sub>2</sub>O<sub>4</sub> Oxygen Carrier

Yang Luhan; Chen Duotian; Zhong Jianjun

doi:doi:10.11648/j.sd.20180603.14

| Peer-Reviewed

Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl₂O₄ Oxygen Carrier

Yang Luhan, Chen Duotian, Zhong Jianjun

Published in Science Discovery (Volume 6, Issue 3)

Received: 22 June 2018 Accepted: Published: 23 June 2018

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

China produces a large number of agricultural wastes annually, most of which are treated by incineration, and the utilization rate is very low. This paper had constructed a hydrogen production system for chemical chain of agricultural and forestry waste, focusing on the effects of loading capacity, promoter and baking temperature on the oxidation and catalytic performance of NiO/NiAl₂O₄ oxygen carrier and the characteristics of its reduction and physical properties. The results showed this oxygen carrier had good circulation ability. After many redox reactions, the output of H₂ had no obvious attenuation, and NiO could be attached to the surface of NiAl₂O₄ effectively. Therefore, NiO/NiAl₂O₄ oxygen carrier had certain mechanical properties, not only the pore was fine, but also the gas flew through the chain cycle reaction completely. The research of this paper has important significance for high-grade utilization of agricultural and forestry waste, environmental protection, energy saving and emission reduction.

Published in	Science Discovery (Volume 6, Issue 3)
DOI	10.11648/j.sd.20180603.14
Page(s)	164-170
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Agricultural and Forestry Waste, Chemical Chain Reaction, Oxygen Carrier, Hydrogen Production

References

[1]	陈婉.《2018年度全球碳市场进展报告》发布全球碳市场呈现新格局[J].环境经济,2018(05):44-47。
[2]	关海滨,张卫杰,范晓旭,赵保峰,孙荣峰,姜建国,董红海,薛旭方.生物质气化技术研究进展[J].山东科学,2017,30(04):58-66。
[3]	农业部关于推进农业供给侧结构性改革的实施意见[J].饲料研究,2017(05):46-52。
[4]	王红彦,王飞,孙仁华,高春雨,王亚静,孙宁,王磊,毕于运.国外农作物秸秆利用政策法规综述及其经验启示[J].农业工程学报,2016,32(16):216-222。
[5]	王斯晗,张瑀健.天然气蒸汽重整制氢技术研究现状[J].工业催化,2016,24(04):26-30。
[6]	孙兆松,梁皓,尹泽群.化学链制氢技术研究进展[J].化学工业与工程,2015,32(05):71-78。
[7]	曾亮,巩金龙.化学链重整直接制氢技术进展[J].化工学报,2015,66(08)：2854-2862。
[8]	罗明,王树众,王龙飞,吕明明,肖仲正,朱佳斌.基于化学链技术制氢的研究进展[J].化工进展,2014,33(05):1123-1133。
[9]	史奇良,陈时熠,薛志鹏,王东,向文国.铁基载氧体化学链制氢特性实验研究[J].中国电机工程学报,2011,31(S1):168-174。
[10]	胡月.生物质废物化学链制氢工艺中铁基载氧体制备与性能研究[D].清华大学,2014。
[11]	祝捷.生物质废物热解气单塔固定床化学链制氢系统实验研究[D].清华大学,2015。
[12]	蒋林林，赵海波，张少华，等.煤基化学链燃烧技术的Fe2O3/Al2O3氧载体研究[J].工程热物理学报，2010，(06):1053-1056。
[13]	梅道锋，赵海波，马兆军，等．Fe2O3/Al2O3氧载体制备方法的研究[J]．燃料化学学报，2012，(07):795-802。
[14]	刘自松，魏永刚，李孔斋，等．Fe2O3/Al2O3氧载体用于甲烷化学链燃烧:负载量与制备方法的影响[J]．燃料化学学报，2013，(11):1384-1392。
[15]	Ming Luo, Shuzhong Wang, Longfei Wang, et al. Reduction kinetics of iron-based oxygen carriers using methane for chemical-looping combustion[J]. Journal of Power Sources. 2014.
[16]	H.P. Hamers, F. Gallucci, P.D. Cobden, et al. CLC in packed beds using syngas and CuO/Al2O3:Model description and experimental validation[J]. Applied Energy. 2014.
[17]	Xing Cai, Xiaohong Wang, Xin Guo, et al. Mechanism study of reaction between CO and NiO surface during chemical-looping combustion: Role of oxygen[J]. Chemical Engineering Journal. 2014.

Cite This Article

Plain Text BibTeX RIS

APA Style

Yang Luhan, Chen Duotian, Zhong Jianjun. (2018). Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier. Science Discovery, 6(3), 164-170. https://doi.org/10.11648/j.sd.20180603.14

Copy | Download

ACS Style

Yang Luhan; Chen Duotian; Zhong Jianjun. Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier. Sci. Discov. 2018, 6(3), 164-170. doi: 10.11648/j.sd.20180603.14

Copy | Download

AMA Style

Yang Luhan, Chen Duotian, Zhong Jianjun. Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier. Sci Discov. 2018;6(3):164-170. doi: 10.11648/j.sd.20180603.14

Copy | Download

@article{10.11648/j.sd.20180603.14,
  author = {Yang Luhan and Chen Duotian and Zhong Jianjun},
  title = {Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier},
  journal = {Science Discovery},
  volume = {6},
  number = {3},
  pages = {164-170},
  doi = {10.11648/j.sd.20180603.14},
  url = {https://doi.org/10.11648/j.sd.20180603.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20180603.14},
  abstract = {China produces a large number of agricultural wastes annually, most of which are treated by incineration, and the utilization rate is very low. This paper had constructed a hydrogen production system for chemical chain of agricultural and forestry waste, focusing on the effects of loading capacity, promoter and baking temperature on the oxidation and catalytic performance of NiO/NiAl2O4 oxygen carrier and the characteristics of its reduction and physical properties. The results showed this oxygen carrier had good circulation ability. After many redox reactions, the output of H2 had no obvious attenuation, and NiO could be attached to the surface of NiAl2O4 effectively. Therefore, NiO/NiAl2O4 oxygen carrier had certain mechanical properties, not only the pore was fine, but also the gas flew through the chain cycle reaction completely. The research of this paper has important significance for high-grade utilization of agricultural and forestry waste, environmental protection, energy saving and emission reduction.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier
AU  - Yang Luhan
AU  - Chen Duotian
AU  - Zhong Jianjun
Y1  - 2018/06/23
PY  - 2018
N1  - https://doi.org/10.11648/j.sd.20180603.14
DO  - 10.11648/j.sd.20180603.14
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 164
EP  - 170
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20180603.14
AB  - China produces a large number of agricultural wastes annually, most of which are treated by incineration, and the utilization rate is very low. This paper had constructed a hydrogen production system for chemical chain of agricultural and forestry waste, focusing on the effects of loading capacity, promoter and baking temperature on the oxidation and catalytic performance of NiO/NiAl2O4 oxygen carrier and the characteristics of its reduction and physical properties. The results showed this oxygen carrier had good circulation ability. After many redox reactions, the output of H2 had no obvious attenuation, and NiO could be attached to the surface of NiAl2O4 effectively. Therefore, NiO/NiAl2O4 oxygen carrier had certain mechanical properties, not only the pore was fine, but also the gas flew through the chain cycle reaction completely. The research of this paper has important significance for high-grade utilization of agricultural and forestry waste, environmental protection, energy saving and emission reduction.
VL  - 6
IS  - 3
ER  -

Copy | Download

Author Information

Yang Luhan

College of Materials and Energy, South China Agricultural University, Guangzhou, China
Chen Duotian

College of Materials and Energy, South China Agricultural University, Guangzhou, China
Zhong Jianjun

College of Materials and Energy, South China Agricultural University, Guangzhou, China

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Yang Luhan, Chen Duotian, Zhong Jianjun. (2018). Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier. Science Discovery, 6(3), 164-170. https://doi.org/10.11648/j.sd.20180603.14

Copy | Download

ACS Style

Yang Luhan; Chen Duotian; Zhong Jianjun. Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier. Sci. Discov. 2018, 6(3), 164-170. doi: 10.11648/j.sd.20180603.14

Copy | Download

AMA Style

Yang Luhan, Chen Duotian, Zhong Jianjun. Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier. Sci Discov. 2018;6(3):164-170. doi: 10.11648/j.sd.20180603.14

Copy | Download

@article{10.11648/j.sd.20180603.14,
  author = {Yang Luhan and Chen Duotian and Zhong Jianjun},
  title = {Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier},
  journal = {Science Discovery},
  volume = {6},
  number = {3},
  pages = {164-170},
  doi = {10.11648/j.sd.20180603.14},
  url = {https://doi.org/10.11648/j.sd.20180603.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20180603.14},
  abstract = {China produces a large number of agricultural wastes annually, most of which are treated by incineration, and the utilization rate is very low. This paper had constructed a hydrogen production system for chemical chain of agricultural and forestry waste, focusing on the effects of loading capacity, promoter and baking temperature on the oxidation and catalytic performance of NiO/NiAl2O4 oxygen carrier and the characteristics of its reduction and physical properties. The results showed this oxygen carrier had good circulation ability. After many redox reactions, the output of H2 had no obvious attenuation, and NiO could be attached to the surface of NiAl2O4 effectively. Therefore, NiO/NiAl2O4 oxygen carrier had certain mechanical properties, not only the pore was fine, but also the gas flew through the chain cycle reaction completely. The research of this paper has important significance for high-grade utilization of agricultural and forestry waste, environmental protection, energy saving and emission reduction.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Research on Producing Pure Hydrogen by Chemical Chain Reaction Using Pyrolysis Gas from Agricultural Waste Based on NiO/NiAl2O4 Oxygen Carrier
AU  - Yang Luhan
AU  - Chen Duotian
AU  - Zhong Jianjun
Y1  - 2018/06/23
PY  - 2018
N1  - https://doi.org/10.11648/j.sd.20180603.14
DO  - 10.11648/j.sd.20180603.14
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 164
EP  - 170
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20180603.14
AB  - China produces a large number of agricultural wastes annually, most of which are treated by incineration, and the utilization rate is very low. This paper had constructed a hydrogen production system for chemical chain of agricultural and forestry waste, focusing on the effects of loading capacity, promoter and baking temperature on the oxidation and catalytic performance of NiO/NiAl2O4 oxygen carrier and the characteristics of its reduction and physical properties. The results showed this oxygen carrier had good circulation ability. After many redox reactions, the output of H2 had no obvious attenuation, and NiO could be attached to the surface of NiAl2O4 effectively. Therefore, NiO/NiAl2O4 oxygen carrier had certain mechanical properties, not only the pore was fine, but also the gas flew through the chain cycle reaction completely. The research of this paper has important significance for high-grade utilization of agricultural and forestry waste, environmental protection, energy saving and emission reduction.
VL  - 6
IS  - 3
ER  -

Copy | Download