International Journal of Environmental Monitoring and Analysis

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Incident Monitoring of Glyphosate and Aminomethylphosphonic Acid in Natural Waters – Experimental Set-up and Validation

Received: Feb. 27, 2016    Accepted: Mar. 08, 2016    Published: Apr. 20, 2016
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Abstract

A measuring system based on sequential injection analysis (SIA) for the detection of the herbicide glyphosate and its main metabolite aminomethylphosphonic acid (AMPA) in natural waters is presented. The system is automated to enable an unattended monitoring of the analytes. Due to its compact manifold it can easily be integrated into existing observing systems or could be used on board of research vessels. Here we show the experimental setup and the results of the system’s performance during experimental periods of 20 hours in the laboratory as well as in an observing station situated at the Elbe river in Hamburg, Germany. An incident with elevated glyphosate and AMPA concentrations was simulated by injecting spiked river water samples. The results show a good stability of the system over the experimental period.

DOI 10.11648/j.ijema.20160403.12
Published in International Journal of Environmental Monitoring and Analysis ( Volume 4, Issue 3, June 2016 )
Page(s) 75-81
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Glyphosate, Roundup, AMPA, Sequential Injection Analysis, SIA, Phosphororganic Analysis

References
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[2] Deutscher Bundestag. Drucksache 16/13993. Einsatz von Pestiziden auf Strecken der deutschen Bahn. 07. 09. 2009.
[3] S. Daouk, L. F. de Alencastro, H. R. Pfeifer. The herbicide glyphosate and its metabolite AMPA in the Lavaux vineyard area, western Switzerland: Proof of widespread export to surface waters. Part II: The role of infiltration and surface runoff. J Environ Sci Heal B. vol. 48, pp. 725-736, 2013.
[4] H. Horth. Monitoring results for surface water and groundwater. European glyphosate environmental information source. 2010.
[5] T. Tang, W. Boenne, N. Desmet, P. Seuntjens, J. Bronders, A. van Griensven. Quantification and characterization of glyphosate use and loss in a residential area. Sci Total Environ. vol. 517, pp. 207-214, 2015.
[6] A. E. Rosenbom, P. Olsen, F. Plauborg, R. Grant, R. K. Juhler, W. Brusch, J. Kjaer. Pesticide leaching through sandy and loamy fields - long-term lessons learnt from the Danish pesticide leaching assessment programme. Environ Pollut. vol. 201, pp. 75-90, 2015.
[7] L. Puertolas, J. Damasio, C. Barata, A. M. V. M. Soares, N. Prat. Evaluation of side-effects of glyphosate mediated control of giant reed (Arundo donax) on the structure and function of a nearby Mediterranean river ecosystem. Environ Res. vol. 110, pp. 556-564, 2010.
[8] K. R. Solomon, D. G. Thompson. Ecological risk assessment for aquatic organisms from over-water uses of glyphosate. J Toxicol Env Heal B. vol. 6, pp. 289-324, 2003.
[9] K. Z. Guyton, D. Loomis, Y. Grosse, F. El Ghissassi, L. Benbrahim-Tallaa, N. Guha, C. Scoccianti, H. Mattock, K. Straif. Carcinogenicity of tetrachlorvinphos, parathion, malathion, diazinon, and glyphosate. Lancet Oncol. vol. 16, pp. 490-491, 2015.
[10] Fragen und Antworten zu Glyphosat. Bundesministerium für Ernährung und Landwirtschaft. http://www.bmel.de/DE/Landwirtschaft/Pflanzenbau/Pflanzenschutz/_Texte/GlyphosatFAQ.html (accessed 28. 12. 2015).
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[14] J. Ruzicka, G. D. Marshall. Sequential injection - a new concept for chemical sensors, process analysis and laboratory assays. Anal Chim Acta. vol. 237, pp. 329-343, 1990.
[15] N. Dantan. Fließinjektionsanalyse und sequentielle Injektionsanalyse für Prozessmonitoringaufgaben - Einsatzmöglichkeiten in der pharmazeutischen Industrie. Dissertation, Humboldt-Universität zu Berlin, Berlin, Germany, 2002.
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[20] P. Mulchandani, W. Chen, A. Mulchandani. Flow injection amperometric enzyme biosensor for direct determination of organophosphate nerve agents. Environ Sci Technol. vol. 35, pp. 2562-2565, 2001.
[21] K. Koshy, M. Mataki. Photochemical oxidation and flow injection conductivity determination of dissolved organic carbon in estuarine and coastal waters. Lab Robotics Automat. vol. 12, pp. 157-163, 2000.
[22] DIN 38407-22:2001-10 - Gemeinsam erfassbare Stoffgruppen (Gruppe F) Teil 22: Bestimmung von Glyphosat und Aminomethylphosphonsäure (AMPA) in Wasser durch Hochleistungs-Flüssigkeitschromatographie (HPLC). Deutsches Institut für Normung e. V.: Berlin, Germany, 2001.
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  • APA Style

    Britta Jahnke, Bernd Niemeyer. (2016). Incident Monitoring of Glyphosate and Aminomethylphosphonic Acid in Natural Waters – Experimental Set-up and Validation. International Journal of Environmental Monitoring and Analysis, 4(3), 75-81. https://doi.org/10.11648/j.ijema.20160403.12

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    ACS Style

    Britta Jahnke; Bernd Niemeyer. Incident Monitoring of Glyphosate and Aminomethylphosphonic Acid in Natural Waters – Experimental Set-up and Validation. Int. J. Environ. Monit. Anal. 2016, 4(3), 75-81. doi: 10.11648/j.ijema.20160403.12

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    AMA Style

    Britta Jahnke, Bernd Niemeyer. Incident Monitoring of Glyphosate and Aminomethylphosphonic Acid in Natural Waters – Experimental Set-up and Validation. Int J Environ Monit Anal. 2016;4(3):75-81. doi: 10.11648/j.ijema.20160403.12

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  • @article{10.11648/j.ijema.20160403.12,
      author = {Britta Jahnke and Bernd Niemeyer},
      title = {Incident Monitoring of Glyphosate and Aminomethylphosphonic Acid in Natural Waters – Experimental Set-up and Validation},
      journal = {International Journal of Environmental Monitoring and Analysis},
      volume = {4},
      number = {3},
      pages = {75-81},
      doi = {10.11648/j.ijema.20160403.12},
      url = {https://doi.org/10.11648/j.ijema.20160403.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ijema.20160403.12},
      abstract = {A measuring system based on sequential injection analysis (SIA) for the detection of the herbicide glyphosate and its main metabolite aminomethylphosphonic acid (AMPA) in natural waters is presented. The system is automated to enable an unattended monitoring of the analytes. Due to its compact manifold it can easily be integrated into existing observing systems or could be used on board of research vessels. Here we show the experimental setup and the results of the system’s performance during experimental periods of 20 hours in the laboratory as well as in an observing station situated at the Elbe river in Hamburg, Germany. An incident with elevated glyphosate and AMPA concentrations was simulated by injecting spiked river water samples. The results show a good stability of the system over the experimental period.},
     year = {2016}
    }
    

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    T2  - International Journal of Environmental Monitoring and Analysis
    JF  - International Journal of Environmental Monitoring and Analysis
    JO  - International Journal of Environmental Monitoring and Analysis
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    AB  - A measuring system based on sequential injection analysis (SIA) for the detection of the herbicide glyphosate and its main metabolite aminomethylphosphonic acid (AMPA) in natural waters is presented. The system is automated to enable an unattended monitoring of the analytes. Due to its compact manifold it can easily be integrated into existing observing systems or could be used on board of research vessels. Here we show the experimental setup and the results of the system’s performance during experimental periods of 20 hours in the laboratory as well as in an observing station situated at the Elbe river in Hamburg, Germany. An incident with elevated glyphosate and AMPA concentrations was simulated by injecting spiked river water samples. The results show a good stability of the system over the experimental period.
    VL  - 4
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Author Information
  • Institute of Coastal Research / Molecular Recognition and Separation, Helmholtz-Zentrum Geesthacht, Geesthacht, Germany

  • Institute of Coastal Research / Molecular Recognition and Separation, Helmholtz-Zentrum Geesthacht, Geesthacht, Germany; Institute of Thermodynamics, Helmut-Schmidt-University / University of the Federal Armed Forces Hamburg, Hamburg, Germany

  • Section