With the massive emission of greenhouse gases, global warming has become an important challenge for human beings at present. Storing carbon dioxide in the form of solid hydrates in the ocean is an effective strategy to mitigate climate warming. Clay in the ocean may have an effect on hydrate formation and CO2 storage. In this study, montmorillonite and kaolinite were selected as clay minerals, and the effects of clay particles on CO2 hydrate formation in suspensions with different mass fractions were experimentally analyzed. The results showed that the clay particles were able to promote hydrate nucleation and shorten the induction time, but the final amount of hydrate was reduced, which was related to the bound water. CO2 hydrate storage in clay minerals with different water contents was investigated. The amount of CO2 storage in montmorillonite minerals first decreased and then increased with the increase of water content, while the amount of storage in kaolinite minerals increased. The reason was that the amount of bound water on the surfaces of montmorillonite and kaolinite was different, and the stronger bound water was difficult to form hydrates. The results revealed the effect of clay particles on CO2 hydrate formation and provided some experimental support for the CO2 storage by hydrate method in the ocean.
| Published in | Science Discovery (Volume 12, Issue 2) |
| DOI | 10.11648/j.sd.20241202.12 |
| Page(s) | 27-32 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Carbon Dioxide Storage, Hydrate, Clay, Induction Time
| [1] | Gleick P H, Adams R M, Amasino R M, et al. Climate change and the integrity of science [J]. Science, 2010, 328(5979): 689-690. Doi: 10.1126/science. 328.5979.689. |
| [2] | Seinfeld J H. Insights on global warming [J]. Aiche Journal, 2011, 57(12): 3259-3284. Doi: 10.1002/aic. 12780. |
| [3] | Gasser T, Guivarch C, Tachiiri K, et al. Negative emissions physically needed to keep global warming below 2°C [J]. Nature Communications, 2015, 6. Doi: 10.1038/ncomms8958. |
| [4] | IPCC. AR5 climate change 2014: mitigation of climate change: contribution of working group iii to the fifth assessment report of the intergovernmental panel on climate change [R]. Cambridge: Cambridge University Press, 2014. |
| [5] | Saji A, Yoshida H, Sakai M, et al. Fixation of carbon dioxide by clathrate-hydrate [J]. Energy Conversion and Management, 1992, 33(5-8): 643-649. Doi: 10.1016/0196-8904(92)90067-7. |
| [6] | Veluswamy H P, Wong A, Babu P, et al. Rapid methane hydrate formation to develop a cost effective large scale energy storage system [J]. Chemical Engineering Journal, 2016, 290: 161-173. Doi: 10.1016/j.cej.2016.01.026. |
| [7] | Englezos P. Clathrate hydrates [J]. Industrial & Engineering Chemistry Research, 1993, 32(7): 1251-1274. Doi: 10.1021/ie00019a001. |
| [8] | Yang M J, Song Y C, Ruan X K, et al. Characteristics of CO2 hydrate formation and dissociation in glass beads and silica gel [J]. Energies, 2012, 5(4): 925-937. Doi: 10.3390/en5040925. |
| [9] | Veluswamy H P, Kumar A, Seo Y, et al. A review of solidified natural gas (sng) technology for gas storage via clathrate hydrates [J]. Applied Energy, 2018, 216: 262-285. Doi: 10.1016/j.apenergy.2018.02.059. |
| [10] | Falahieh M M, Bonyadi M, Lashanizadegan A. Effect of different salts on the kinetic parameters of the carbon dioxide hydrate formation [J]. Journal of Natural Gas Science and Engineering, 2022, 100. Doi: 10.1016/j.jngse.2022.104461. |
| [11] | Chong Z R, Chan A, Babu P, et al. Effect of nacl on methane hydrate formation and dissociation in porous media [J]. Journal of Natural Gas Science and Engineering, 2015, 27: 178-189. Doi: 10.1016/j.jngse. 2015.08.055. |
| [12] | Long Z, Liang D Q, Li D L. Kinetic effect of single MgCl2 and NaCl aqueous solutions on ethane hydrate formation [J]. Canadian Journal of Chemistry, 2015, 93(8): 891-896. Doi: 10.1139/cjc-2014-0535. |
| [13] | Liu Y Z, Feng Y, Zhang L X, et al. Effects of protein macromolecules and metabolic small molecules on kinetics of methane hydrate formation in marine clay [J]. Chemical Engineering Journal, 2021, 412. Doi: 10.1016/j.cej.2021.128496. |
| [14] | Liu Y Z, Zhang L X, Yang L, et al. Behaviors of CO2 hydrate formation in the presence of acid-dissolvable organic matters [J]. Environmental Science & Technology, 2021, 55(9): 6206-6213. Doi: 10.1021/acs.est.0c06407. |
| [15] | Jadav S, Sakthipriya N, Doble M, et al. Effect of biosurfactants produced by bacillus subtilis and pseudomonas aeruginosa on the formation kinetics of methane hydrates [J]. Journal of Natural Gas Science and Engineering, 2017, 43: 156-166. Doi: 10.1016/j.jngse.2017.03.032. |
| [16] | Kumar A, Sakpal T, Linga P, et al. Influence of contact medium and surfactants on carbon dioxide clathrate hydrate kinetics [J]. Fuel, 2013, 105: 664-671. Doi: 10.1016/j.fuel.2012.10.031. |
| [17] | Mekala P, Busch M, Mech D, et al. Effect of silica sand size on the formation kinetics of CO2 hydrate in porous media in the presence of pure water and seawater relevant for CO2 sequestration [J]. Journal of Petroleum Science and Engineering, 2014, 122: 1-9. Doi: 10.1016/j.petrol.2014.08.017. |
| [18] | Linga P, Daraboina N, Ripmeester J A, et al. Enhanced rate of gas hydrate formation in a fixed bed column filled with sand compared to a stirred vessel [J]. Chemical Engineering Science, 2012, 68(1): 617-623. Doi: 10.1016/j.ces.2011.10.030. |
| [19] | Ning F L, Liang J Q, Wu N Y, et al. Reservoir characteristics of natural gas hydrates in China [J]. Natural Gas Industry, 2020, 40(08): 1-24. Doi: 10.3787/j.issn.1000-0976.2020.08.001. |
| [20] | Sha Z B, Liang J Q, Zhang G X, et al. A seepage gas hydrate system in northern south china sea: seismic and well log interpretations [J]. Marine Geology, 2015, 366: 69-78. Doi: 10.1016/j.margeo.2015.04.006. |
| [21] | Dutkiewicz A, O'Callaghan S, Müller R D. Controls on the distribution of deep-sea sediments [J]. Geochemistry Geophysics Geosystems, 2016, 17(8): 3075-3098. Doi: 10.1002/2016GC006428. |
| [22] | Luo H X. The composition microstructure and physico- chemical properties of marine soil in South China Sea [J]. Rock and Soil Mechanics, 1989(04): 45-53. Doi: 10.16285/j.rsm.1989.04.006. |
| [23] | Li Y L, Liu C L, Liao H L, et al. Mechanical properties of the mixed system of clayey-silt sediments and natural gas hydrates [J]. Natural Gas Industry, 2020, 40(08): 159-168. Doi: 10.3787/j.issn.1000-0976.2020.08.013. |
| [24] | Ren J J, Liu X H, Niu M Y, et al. Effect of sodium montmorillonite clay on the kinetics of ch4 hydrate-implication for energy recovery [J]. Chemical Engineering Journal, 2022, 437. Doi: 10.1016/j.cej.2022.135368. |
| [25] | Park T, Kwon T H. Effect of electric field on gas hydrate nucleation kinetics: evidence for the enhanced kinetics of hydrate nucleation by negatively charged clay surfaces [J]. Environmental Science & Technology, 2018, 52(5): 3267-3274. Doi: 10.1021/acs.est.7b05477. |
| [26] | van Groos A, Guggenheim S. The stability of methane hydrate intercalates of montmorillonite and nontronite: implications for carbon storage in ocean-floor environments [J]. American Mineralogist, 2009, 94(2-3): 372-379. Doi: 10.2138/am.2009.3018. |
| [27] | Feng Y, Zhao Y, Han Y Z, et al. Formation and dissociation of co2 hydrates in porous media in the presence of clay suspensions [J]. Chemical Engineering Journal, 2023, 465. Doi: 10.1016/j.cej.2023.142854. |
| [28] | Ma X L, Jiang D D, Lu J, et al. Hydrate formation and dissociation characteristics in clayey silt sediment [J]. Journal of Natural Gas Science and Engineering, 2022, 100. Doi: 10.1016/j.jngse.2022.104475. |
| [29] | Coquelet C, Chapoy A, Richon D. Development of a new alpha function for the peng-robinson equation of state: comparative study of alpha function models for pure gases (natural gas components) and water-gas systems [J]. International Journal of Thermophysics, 2004, 25(1): 133-158. |
| [30] | Sohnel O, Mullin J W. Interpretation of crystallization induction periods [J]. Journal of Colloid and Interface Science, 1988, 123(1): 43-50. Doi: 10.1016/0021-9797(88)90219-6. |
| [31] | Zhang Y P, Hyndman C L, Maini B B. Measurement of gas diffusivity in heavy oils [J]. Journal of Petroleum Science and Engineering, 2000, 25(1-2): 37-47. Doi: 10.1016/S0920-4105(99)00031-5. |
| [32] | Hamid K A, Azmi W H, Nabil M F, et al. Experimental investigation of thermal conductivity and dynamic viscosity on nanoparticle mixture ratios of Tio2-Sio2 nanofluids [J]. International Journal of Heat and Mass Transfer, 2018, 116: 1143-1152. Doi: 10.1016/j.ijheatmasstransfer.2017.09.087. |
| [33] | Li S, Wang C M, Zhang X W, et al. Classification and characterization of bound water in marine mucky silty clay [J]. Journal of Soils and Sediments, 2019, 19(5): 2509-2519. Doi: 10.1007/s11368-019-02242-5. |
| [34] | Kuligiewicz A, Derkowski A. Tightly bound water in smectites [J]. American Mineralogist, 2017, 102(5): 1073-1090. Doi: 10.2138/am-2017-5918. |
| [35] | Zhang Y, Zhang L, Chen C, et al. Role of different types of water in bentonite clay on hydrate formation and decomposition [J]. Chinese Journal of Chemical Engineering, 2022, 50: 310-316. Doi: 10.1016/j.cjche.2022.08.001. |
| [36] | Mbey J A, Thomas F, Razafitianamaharavo A, et al. A comparative study of some kaolinites surface properties [J]. Applied Clay Science, 2019, 172: 135-145. Doi: 10.1016/j.clay.2019.03.005. |
APA Style
Han, Y., Feng, Y., Ge, Y., Li, Q., Yang, L., et al. (2024). Study on the Effect of Clay Minerals on CO2 Hydrate Formation. Science Discovery, 12(2), 27-32. https://doi.org/10.11648/j.sd.20241202.12
ACS Style
Han, Y.; Feng, Y.; Ge, Y.; Li, Q.; Yang, L., et al. Study on the Effect of Clay Minerals on CO2 Hydrate Formation. Sci. Discov. 2024, 12(2), 27-32. doi: 10.11648/j.sd.20241202.12
AMA Style
Han Y, Feng Y, Ge Y, Li Q, Yang L, et al. Study on the Effect of Clay Minerals on CO2 Hydrate Formation. Sci Discov. 2024;12(2):27-32. doi: 10.11648/j.sd.20241202.12
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Download@article{10.11648/j.sd.20241202.12,
author = {Yuze Han and Yu Feng and Yang Ge and Qingping Li and Lei Yang and Lunxiang Zhang and Yongchen Song},
title = {Study on the Effect of Clay Minerals on CO2 Hydrate Formation
},
journal = {Science Discovery},
volume = {12},
number = {2},
pages = {27-32},
doi = {10.11648/j.sd.20241202.12},
url = {https://doi.org/10.11648/j.sd.20241202.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20241202.12},
abstract = {With the massive emission of greenhouse gases, global warming has become an important challenge for human beings at present. Storing carbon dioxide in the form of solid hydrates in the ocean is an effective strategy to mitigate climate warming. Clay in the ocean may have an effect on hydrate formation and CO2 storage. In this study, montmorillonite and kaolinite were selected as clay minerals, and the effects of clay particles on CO2 hydrate formation in suspensions with different mass fractions were experimentally analyzed. The results showed that the clay particles were able to promote hydrate nucleation and shorten the induction time, but the final amount of hydrate was reduced, which was related to the bound water. CO2 hydrate storage in clay minerals with different water contents was investigated. The amount of CO2 storage in montmorillonite minerals first decreased and then increased with the increase of water content, while the amount of storage in kaolinite minerals increased. The reason was that the amount of bound water on the surfaces of montmorillonite and kaolinite was different, and the stronger bound water was difficult to form hydrates. The results revealed the effect of clay particles on CO2 hydrate formation and provided some experimental support for the CO2 storage by hydrate method in the ocean.
},
year = {2024}
}
TY - JOUR T1 - Study on the Effect of Clay Minerals on CO2 Hydrate Formation AU - Yuze Han AU - Yu Feng AU - Yang Ge AU - Qingping Li AU - Lei Yang AU - Lunxiang Zhang AU - Yongchen Song Y1 - 2024/04/12 PY - 2024 N1 - https://doi.org/10.11648/j.sd.20241202.12 DO - 10.11648/j.sd.20241202.12 T2 - Science Discovery JF - Science Discovery JO - Science Discovery SP - 27 EP - 32 PB - Science Publishing Group SN - 2331-0650 UR - https://doi.org/10.11648/j.sd.20241202.12 AB - With the massive emission of greenhouse gases, global warming has become an important challenge for human beings at present. Storing carbon dioxide in the form of solid hydrates in the ocean is an effective strategy to mitigate climate warming. Clay in the ocean may have an effect on hydrate formation and CO2 storage. In this study, montmorillonite and kaolinite were selected as clay minerals, and the effects of clay particles on CO2 hydrate formation in suspensions with different mass fractions were experimentally analyzed. The results showed that the clay particles were able to promote hydrate nucleation and shorten the induction time, but the final amount of hydrate was reduced, which was related to the bound water. CO2 hydrate storage in clay minerals with different water contents was investigated. The amount of CO2 storage in montmorillonite minerals first decreased and then increased with the increase of water content, while the amount of storage in kaolinite minerals increased. The reason was that the amount of bound water on the surfaces of montmorillonite and kaolinite was different, and the stronger bound water was difficult to form hydrates. The results revealed the effect of clay particles on CO2 hydrate formation and provided some experimental support for the CO2 storage by hydrate method in the ocean. VL - 12 IS - 2 ER -
Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China
Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China
State Key Laboratory of Natural Gas Hydrates, China National Offshore Oil Corporation, Beijing, China
State Key Laboratory of Natural Gas Hydrates, China National Offshore Oil Corporation, Beijing, China
Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China; Ningbo Institute of Dalian University of Technology, Ningbo, China
Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China; Ningbo Institute of Dalian University of Technology, Ningbo, China
Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China
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