In this work we have synthesized Li (Ni1/3Co1/3Mn1/3) O2 using sulfates metals Ni, Co and Mn and LiCl salt. The used method is easy and led to yield higher than 75%. Identification and lamellar α-type NaFeO2 of the composite synthesized were demonstrated by X-ray diffraction and FTIR spectroscopy. We demonstrated that the product is pure and its crystallinity changes according to the parameters of the annealing step. The electronic structure of the compound has been modified by doping with monovalent Cupper cation. The results are encouraging and show that the lamellar structure is not altered. We noticed an increase in infill distances that can affect the mobility of lithium cations during the insertion cycles / extraction. Indeed, the charge on the surface of the doped product is -90mV after 60 minutes and that of the undoped compound is -241mV.
| Published in | International Journal of Science and Qualitative Analysis (Volume 2, Issue 3) |
| DOI | 10.11648/j.ijsqa.20160203.13 |
| Page(s) | 36-40 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2016. Published by Science Publishing Group |
Li (Ni1/3Co1/3Mn1/3) OH2, Battery Li-ion, LiCoO2, α-Type Layer NaFeO2
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APA Style
Gharibi El Khadir, Hatim Oumaima, El Bekkaye Yousfi, Oumnih Safae, Abou-salama Mohamed. (2016). Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped. International Journal of Science and Qualitative Analysis, 2(3), 36-40. https://doi.org/10.11648/j.ijsqa.20160203.13
ACS Style
Gharibi El Khadir; Hatim Oumaima; El Bekkaye Yousfi; Oumnih Safae; Abou-salama Mohamed. Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped. Int. J. Sci. Qual. Anal. 2016, 2(3), 36-40. doi: 10.11648/j.ijsqa.20160203.13
AMA Style
Gharibi El Khadir, Hatim Oumaima, El Bekkaye Yousfi, Oumnih Safae, Abou-salama Mohamed. Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped. Int J Sci Qual Anal. 2016;2(3):36-40. doi: 10.11648/j.ijsqa.20160203.13
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author = {Gharibi El Khadir and Hatim Oumaima and El Bekkaye Yousfi and Oumnih Safae and Abou-salama Mohamed},
title = {Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped},
journal = {International Journal of Science and Qualitative Analysis},
volume = {2},
number = {3},
pages = {36-40},
doi = {10.11648/j.ijsqa.20160203.13},
url = {https://doi.org/10.11648/j.ijsqa.20160203.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsqa.20160203.13},
abstract = {In this work we have synthesized Li (Ni1/3Co1/3Mn1/3) O2 using sulfates metals Ni, Co and Mn and LiCl salt. The used method is easy and led to yield higher than 75%. Identification and lamellar α-type NaFeO2 of the composite synthesized were demonstrated by X-ray diffraction and FTIR spectroscopy. We demonstrated that the product is pure and its crystallinity changes according to the parameters of the annealing step. The electronic structure of the compound has been modified by doping with monovalent Cupper cation. The results are encouraging and show that the lamellar structure is not altered. We noticed an increase in infill distances that can affect the mobility of lithium cations during the insertion cycles / extraction. Indeed, the charge on the surface of the doped product is -90mV after 60 minutes and that of the undoped compound is -241mV.},
year = {2016}
}
TY - JOUR T1 - Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped AU - Gharibi El Khadir AU - Hatim Oumaima AU - El Bekkaye Yousfi AU - Oumnih Safae AU - Abou-salama Mohamed Y1 - 2016/12/30 PY - 2016 N1 - https://doi.org/10.11648/j.ijsqa.20160203.13 DO - 10.11648/j.ijsqa.20160203.13 T2 - International Journal of Science and Qualitative Analysis JF - International Journal of Science and Qualitative Analysis JO - International Journal of Science and Qualitative Analysis SP - 36 EP - 40 PB - Science Publishing Group SN - 2469-8164 UR - https://doi.org/10.11648/j.ijsqa.20160203.13 AB - In this work we have synthesized Li (Ni1/3Co1/3Mn1/3) O2 using sulfates metals Ni, Co and Mn and LiCl salt. The used method is easy and led to yield higher than 75%. Identification and lamellar α-type NaFeO2 of the composite synthesized were demonstrated by X-ray diffraction and FTIR spectroscopy. We demonstrated that the product is pure and its crystallinity changes according to the parameters of the annealing step. The electronic structure of the compound has been modified by doping with monovalent Cupper cation. The results are encouraging and show that the lamellar structure is not altered. We noticed an increase in infill distances that can affect the mobility of lithium cations during the insertion cycles / extraction. Indeed, the charge on the surface of the doped product is -90mV after 60 minutes and that of the undoped compound is -241mV. VL - 2 IS - 3 ER -
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