Nitrogen dioxide, carbon dioxide and sulphur dioxide are acidic gas and they produce corrosive medium for copper sculptures. These gases absorb moisture to form nitric acid, carbonic and sulphuric acid. It forms corrosion cell on the surface of copper and accelerate corrosion reactions. The corrosion cell formation is written as: Cu|Cu2+||H+|H2 thus corrosion reactions start and copper is oxidized into Cu2+surface and it is oxidized into Cu2+ whereas H+ ion is reduced into H2. Nitric acid environment copper exhibits galvanic, pitting, stress, crevice, blistering, embrittlement and intergranular corrosion. The corrosion reactions change physical, chemical and mechanical properties of corroded materials. Nanocoating compound tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazoneand SiC electrospray compounds used to control the corrosion of copperin nitrogen dioxide medium. For corrosion mitigation of copper metal interface was coated with tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone and SiC. The coating compound tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone was synthesized in laboratory. Nozzle sprays techniques used for nanocoating and electrospraying. The corrosion rate of copper was determined by gravimetric loss method at different temperatures, concentrations and days in nitrogen dioxide medium. Potentiostatic polarization technique used for the determination of electrode potential, corrosion current and current density. Nanocoating and electrospraying compounds formed a composite barrier on the surface of base metal by chemical bonding. The nanocoating and electrospray compounds adhered on base metal by chemisorptions to confirm byactivation energy, heat of adsorption, free energy, enthalpy and entropy. The nanocoating and electrospray deposited on copper confirmed by Langmuir, Frundlich and Temkin isotherm. Copperformed a complex compound to interact with tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone and SiC. Electrospraying SiC blocked porosities of nanocoating compound and checked osmosis process of nitrogen dioxide. The nanocoating and electrospray compounds decreased corrosion rate and increased surface coverage areas and percentage coating efficiencies.
| Published in | International Journal of Materials Science and Applications (Volume 11, Issue 4) |
| DOI | 10.11648/j.ijmsa.20221104.12 |
| Page(s) | 95-101 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2022. Published by Science Publishing Group |
Copper, Composite Barrier, Nanocoating, Electrospraying, Nozzle Spray, Thermal Parameters, SiC
| [1] | R K Singh & Noor Alam (2019), Study the corrosion & corrosion protection of brass sculpture by atmospheric pollutants in winter season, Modern Approach on Material Science 1 (3), 54-62. |
| [2] | Szabo T, Molnar-Nagy L, and Telegdi J (2011), Self-healing microcapsules and slow release microspheres in paints, Progress in Organic Coatings, 72, 52-57. |
| [3] | Videla H and L K Herrera (2009), Understanding microbial inhibition of corrosion, Electrochem Acta, 39 229-234. |
| [4] | R K Singh (2017), Corrosion protection of transport vehicles by nanocoating of Dechydrobenzo[8]annulene-5,10-dihydrazone in corrosive environments and weather change, Journal of Powder Metallurgy and Mining, 6 (1) 1-8. |
| [5] | Wen N T, Lin C S, Bai C Y, and Ger M D (2008), Structures and characteristics of Cr (III) based conversion coatings on electrogalvanized steels, Surf. Coat Technol, 203, 317. |
| [6] | Boerio F J, Shah P (2005), Adhesion of injection molded PVC to steel substrates, J of Adhesion 81 (6) 645-675. |
| [7] | R K Singh, Manjay K Thakur & Sabana Latif (2018), Mild Steel corrosion control by nanocoating and filler compounds in hostile environments, J of J Material Science 4 (3), 1-12. |
| [8] | Deveci H, Ahmetti G and Ersoz M, (2012), Modified styrenes: Corrosion physico-mechanical and thermal properties evaluation, Prog. Org. Coat. 73, 1-7. |
| [9] | Genzer J (2005), Templating Surfaces with Gradient Assemblies, J of Adhesion 81, 417-435. |
| [10] | Leon-Silva U, Nicho M E (2010), Poly(3-octylthiophhene) and polystyrene blends thermally treated as coating for corrosion protection of stainless steel 304, J. Solid State Electrochem, 14, 1487-1497. |
| [11] | Baier R E (2006), Surface behaviour of biomaterials: Surface for biocompatibility, J. Mater. Sci. Mater. Med. 17 1057-1062. |
| [12] | R K Singh 58 (2016), Corrosion protection of transport vehicles by nanocoating of decahydrobenzo[8]annulene -5,10-dihydrazone and SiC filler in H2O, O2 (moist), CO2, SO2 environments and weather change, Journal of Metallurgy and Materials Science, 58, 167-179. |
| [13] | Rao BVA, Iqbal M Y and Sreehar B (2010), Electrochemical and surface analytical studies of the self assembled monolayer of 5-methoxy-2-(octadeclthiol) benzimidazole in corrosion protection of copper, Electrochim, Acta, 55 620-631. |
| [14] | Liu X Y, Ma H Y and Hou M Z (2009), Self-assembled monolayers of stearic imidazoline on copper electrodes detected using electro chemical measurement, XPS, molecular simulation and FTIR, Chinese Sci. Bull. 54 374-381. |
| [15] | Liao Q Q, Yue Z W and Zhou Q (2009), Corrosion inhibition effect of self-assembled monolayers of ammonium pyrrolidine dithiocarbamate on copper, Acta Phys. Chin. Sin. 25, 1655-1661. |
| [16] | Zhang D Q, He X M and Kim G S (2009), Arginine self-assembled monolayers against copper corrosion and synergitic effect of iodide ion, J. Appl. Electrochem 39, 1193-1198. |
| [17] | Ghareba G S and Omanovic S (2010), Interaction of 12-aminododecanoic acid with a carbon steel surface: Towards the development of ‘green’ corrosion inhibitors, Corrosion Sci. 52 2104-2113. |
| [18] | Sahoo R R and Biswas S K (2009), Frictional response of fatty acids on steel, J. Colloid Interf. Sci. 333 707-718. |
| [19] | Raman R and Gawalt E S (2007), Selfassembled monolayers of alkanoic acid on the native oxide surface of SS316L by solution deposition, Langmuir, 23 2284-2288. |
| [20] | R K Singh (2015), Building materials corrosion control by fiber reinforced polymers, Journal of Powder Metallurgy and Mining 4 (2) 1-5. |
| [21] | Li D G, Chen S H and Zhao S Y (2006), The corrosion Inhibition of the self-assembled Au and Ag nanoparticles films on the surface of copper, Colloid. Surface A, 273, 16-23. |
| [22] | Cristiani P, Perboni G and Debenedetti A (2008), Effect of chlorination on the corrosion of Cu|Ni 70|30 condenser tubing, Electrochim. Acta 54 100-107. |
| [23] | Cristiani P (2005), Solutions fouling in power station condensers, Appl. Therm. Eng. 25 2630-2640. |
| [24] | R K Singh & Rajeev Kumar (2014), Study corrosion and corrosion protection of stainless steel in phosphate fertilizer industry, American Journal of Mining and Metallurgy, 2, 27-31. |
APA Style
Rajesh Kumar Singh, Hema Kesavan, Jay Prakash Singh. (2022). Corrosion Protection of Copper Sculptures by Corrosive Pollutants. International Journal of Materials Science and Applications, 11(4), 95-101. https://doi.org/10.11648/j.ijmsa.20221104.12
ACS Style
Rajesh Kumar Singh; Hema Kesavan; Jay Prakash Singh. Corrosion Protection of Copper Sculptures by Corrosive Pollutants. Int. J. Mater. Sci. Appl. 2022, 11(4), 95-101. doi: 10.11648/j.ijmsa.20221104.12
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Download@article{10.11648/j.ijmsa.20221104.12,
author = {Rajesh Kumar Singh and Hema Kesavan and Jay Prakash Singh},
title = {Corrosion Protection of Copper Sculptures by Corrosive Pollutants},
journal = {International Journal of Materials Science and Applications},
volume = {11},
number = {4},
pages = {95-101},
doi = {10.11648/j.ijmsa.20221104.12},
url = {https://doi.org/10.11648/j.ijmsa.20221104.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20221104.12},
abstract = {Nitrogen dioxide, carbon dioxide and sulphur dioxide are acidic gas and they produce corrosive medium for copper sculptures. These gases absorb moisture to form nitric acid, carbonic and sulphuric acid. It forms corrosion cell on the surface of copper and accelerate corrosion reactions. The corrosion cell formation is written as: Cu|Cu2+||H+|H2 thus corrosion reactions start and copper is oxidized into Cu2+surface and it is oxidized into Cu2+ whereas H+ ion is reduced into H2. Nitric acid environment copper exhibits galvanic, pitting, stress, crevice, blistering, embrittlement and intergranular corrosion. The corrosion reactions change physical, chemical and mechanical properties of corroded materials. Nanocoating compound tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazoneand SiC electrospray compounds used to control the corrosion of copperin nitrogen dioxide medium. For corrosion mitigation of copper metal interface was coated with tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone and SiC. The coating compound tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone was synthesized in laboratory. Nozzle sprays techniques used for nanocoating and electrospraying. The corrosion rate of copper was determined by gravimetric loss method at different temperatures, concentrations and days in nitrogen dioxide medium. Potentiostatic polarization technique used for the determination of electrode potential, corrosion current and current density. Nanocoating and electrospraying compounds formed a composite barrier on the surface of base metal by chemical bonding. The nanocoating and electrospray compounds adhered on base metal by chemisorptions to confirm byactivation energy, heat of adsorption, free energy, enthalpy and entropy. The nanocoating and electrospray deposited on copper confirmed by Langmuir, Frundlich and Temkin isotherm. Copperformed a complex compound to interact with tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone and SiC. Electrospraying SiC blocked porosities of nanocoating compound and checked osmosis process of nitrogen dioxide. The nanocoating and electrospray compounds decreased corrosion rate and increased surface coverage areas and percentage coating efficiencies.},
year = {2022}
}
TY - JOUR T1 - Corrosion Protection of Copper Sculptures by Corrosive Pollutants AU - Rajesh Kumar Singh AU - Hema Kesavan AU - Jay Prakash Singh Y1 - 2022/10/31 PY - 2022 N1 - https://doi.org/10.11648/j.ijmsa.20221104.12 DO - 10.11648/j.ijmsa.20221104.12 T2 - International Journal of Materials Science and Applications JF - International Journal of Materials Science and Applications JO - International Journal of Materials Science and Applications SP - 95 EP - 101 PB - Science Publishing Group SN - 2327-2643 UR - https://doi.org/10.11648/j.ijmsa.20221104.12 AB - Nitrogen dioxide, carbon dioxide and sulphur dioxide are acidic gas and they produce corrosive medium for copper sculptures. These gases absorb moisture to form nitric acid, carbonic and sulphuric acid. It forms corrosion cell on the surface of copper and accelerate corrosion reactions. The corrosion cell formation is written as: Cu|Cu2+||H+|H2 thus corrosion reactions start and copper is oxidized into Cu2+surface and it is oxidized into Cu2+ whereas H+ ion is reduced into H2. Nitric acid environment copper exhibits galvanic, pitting, stress, crevice, blistering, embrittlement and intergranular corrosion. The corrosion reactions change physical, chemical and mechanical properties of corroded materials. Nanocoating compound tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazoneand SiC electrospray compounds used to control the corrosion of copperin nitrogen dioxide medium. For corrosion mitigation of copper metal interface was coated with tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone and SiC. The coating compound tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone was synthesized in laboratory. Nozzle sprays techniques used for nanocoating and electrospraying. The corrosion rate of copper was determined by gravimetric loss method at different temperatures, concentrations and days in nitrogen dioxide medium. Potentiostatic polarization technique used for the determination of electrode potential, corrosion current and current density. Nanocoating and electrospraying compounds formed a composite barrier on the surface of base metal by chemical bonding. The nanocoating and electrospray compounds adhered on base metal by chemisorptions to confirm byactivation energy, heat of adsorption, free energy, enthalpy and entropy. The nanocoating and electrospray deposited on copper confirmed by Langmuir, Frundlich and Temkin isotherm. Copperformed a complex compound to interact with tetrahydro-dibenzo[a,d][7]annulene-5,11-disemicarbazone and SiC. Electrospraying SiC blocked porosities of nanocoating compound and checked osmosis process of nitrogen dioxide. The nanocoating and electrospray compounds decreased corrosion rate and increased surface coverage areas and percentage coating efficiencies. VL - 11 IS - 4 ER -
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