“Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening

Karachevtseva Liudmyla; Kartel Mykola; Wang Bo; Lytvynenko Oleg; Onyshchenko Volodymyr; Sementsov Yurii; Trachevskyi Viacheslav

doi:doi:10.11648/j.ijmsa.20190806.15

“Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening

Karachevtseva Liudmyla, Kartel Mykola, Wang Bo, Lytvynenko Oleg, Onyshchenko Volodymyr, Sementsov Yurii, Trachevskyi Viacheslav

Published in International Journal of Materials Science and Applications (Volume 8, Issue 6)

Received: 20 August 2019 Published: 3 December 2019

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Abstract

We analyzed “semiconductor” model of the “polymer-CNTs” composite strengthening at 300 K and low (0.1-0.5) wt% CNTs concentration. Carbon nanotubes are among the most anisotropic materials known and have extremely high values of Young's modulus. We investigated influence of vibration bonds on polymer crystallization and strengthening in composite films of polyethylenimine, polyamide, polypropylene and rubber with multiwall carbon nanotubes. IR absorbance maxima we evaluated after formation of composite “polyethylenimine-carbon nanotube” in the spectral area of the sp³ hybridization bonds at the frequency of primary amino groups of polyethylenimine. High IR absorption in the spectral area of sp³ hybridization bonds of polypropylene, polyamide-6 with carbon nanotubes is determined by γ_ω(CН) and γ_ω(CH₂) vibrations. We measured IR reflectance maxima of composite “rubber-carbon nanotube” in the spectral area of CH valence and deformation vibrations. The IR peak dependence on the carbon nanotube content corresponds to 1D Gaussian curve for the diffusion equation in the electric field between electrons of nanotubes and protons in polymer according to “semiconductor” model of the composite structuring. For our case of the long-acting hundreds nanometer interactions, the polymer crystallization depends on sp³ C-C bonds organization in the intrinsic electric field according to the semiconductor n-p model. Tensile strength for polyamide-6 composites at 0.25% CNTs increases 1.7 times and tensile deformation – 2.3 times.

Published in	International Journal of Materials Science and Applications (Volume 8, Issue 6)
DOI	10.11648/j.ijmsa.20190806.15
Page(s)	120-126
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Polymer Composites, Multiwall Carbon Nanotubes, Electric Field

References

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Karachevtseva Liudmyla, Kartel Mykola, Wang Bo, Lytvynenko Oleg, Onyshchenko Volodymyr, et al. (2019). “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening. International Journal of Materials Science and Applications, 8(6), 120-126. https://doi.org/10.11648/j.ijmsa.20190806.15

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ACS Style

Karachevtseva Liudmyla; Kartel Mykola; Wang Bo; Lytvynenko Oleg; Onyshchenko Volodymyr, et al. “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening. Int. J. Mater. Sci. Appl. 2019, 8(6), 120-126. doi: 10.11648/j.ijmsa.20190806.15

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AMA Style

Karachevtseva Liudmyla, Kartel Mykola, Wang Bo, Lytvynenko Oleg, Onyshchenko Volodymyr, et al. “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening. Int J Mater Sci Appl. 2019;8(6):120-126. doi: 10.11648/j.ijmsa.20190806.15

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@article{10.11648/j.ijmsa.20190806.15,
  author = {Karachevtseva Liudmyla and Kartel Mykola and Wang Bo and Lytvynenko Oleg and Onyshchenko Volodymyr and Sementsov Yurii and Trachevskyi Viacheslav},
  title = {“Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening},
  journal = {International Journal of Materials Science and Applications},
  volume = {8},
  number = {6},
  pages = {120-126},
  doi = {10.11648/j.ijmsa.20190806.15},
  url = {https://doi.org/10.11648/j.ijmsa.20190806.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20190806.15},
  abstract = {We analyzed “semiconductor” model of the “polymer-CNTs” composite strengthening at 300 K and low (0.1-0.5) wt% CNTs concentration. Carbon nanotubes are among the most anisotropic materials known and have extremely high values of Young's modulus. We investigated influence of vibration bonds on polymer crystallization and strengthening in composite films of polyethylenimine, polyamide, polypropylene and rubber with multiwall carbon nanotubes. IR absorbance maxima we evaluated after formation of composite “polyethylenimine-carbon nanotube” in the spectral area of the sp3 hybridization bonds at the frequency of primary amino groups of polyethylenimine. High IR absorption in the spectral area of sp3 hybridization bonds of polypropylene, polyamide-6 with carbon nanotubes is determined by γω(CН) and γω(CH2) vibrations. We measured IR reflectance maxima of composite “rubber-carbon nanotube” in the spectral area of CH valence and deformation vibrations. The IR peak dependence on the carbon nanotube content corresponds to 1D Gaussian curve for the diffusion equation in the electric field between electrons of nanotubes and protons in polymer according to “semiconductor” model of the composite structuring. For our case of the long-acting hundreds nanometer interactions, the polymer crystallization depends on sp3 C-C bonds organization in the intrinsic electric field according to the semiconductor n-p model. Tensile strength for polyamide-6 composites at 0.25% CNTs increases 1.7 times and tensile deformation – 2.3 times.},
 year = {2019}
}

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TY  - JOUR
T1  - “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening
AU  - Karachevtseva Liudmyla
AU  - Kartel Mykola
AU  - Wang Bo
AU  - Lytvynenko Oleg
AU  - Onyshchenko Volodymyr
AU  - Sementsov Yurii
AU  - Trachevskyi Viacheslav
Y1  - 2019/12/03
PY  - 2019
N1  - https://doi.org/10.11648/j.ijmsa.20190806.15
DO  - 10.11648/j.ijmsa.20190806.15
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 120
EP  - 126
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20190806.15
AB  - We analyzed “semiconductor” model of the “polymer-CNTs” composite strengthening at 300 K and low (0.1-0.5) wt% CNTs concentration. Carbon nanotubes are among the most anisotropic materials known and have extremely high values of Young's modulus. We investigated influence of vibration bonds on polymer crystallization and strengthening in composite films of polyethylenimine, polyamide, polypropylene and rubber with multiwall carbon nanotubes. IR absorbance maxima we evaluated after formation of composite “polyethylenimine-carbon nanotube” in the spectral area of the sp3 hybridization bonds at the frequency of primary amino groups of polyethylenimine. High IR absorption in the spectral area of sp3 hybridization bonds of polypropylene, polyamide-6 with carbon nanotubes is determined by γω(CН) and γω(CH2) vibrations. We measured IR reflectance maxima of composite “rubber-carbon nanotube” in the spectral area of CH valence and deformation vibrations. The IR peak dependence on the carbon nanotube content corresponds to 1D Gaussian curve for the diffusion equation in the electric field between electrons of nanotubes and protons in polymer according to “semiconductor” model of the composite structuring. For our case of the long-acting hundreds nanometer interactions, the polymer crystallization depends on sp3 C-C bonds organization in the intrinsic electric field according to the semiconductor n-p model. Tensile strength for polyamide-6 composites at 0.25% CNTs increases 1.7 times and tensile deformation – 2.3 times.
VL  - 8
IS  - 6
ER  -

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Author Information

Karachevtseva Liudmyla

Technology and Business Department, Ningbo University of Technology, Ningbo, China
Kartel Mykola

Technology and Business Department, Ningbo University of Technology, Ningbo, China
Wang Bo

Technology and Business Department, Ningbo University of Technology, Ningbo, China
Lytvynenko Oleg

Department of Photonic Crystals, V. Lashkaryov Institute of Semiconductor Physics, NAS of Ukraine, Kyiv, Ukraine
Onyshchenko Volodymyr

Department of Photonic Crystals, V. Lashkaryov Institute of Semiconductor Physics, NAS of Ukraine, Kyiv, Ukraine
Sementsov Yurii

Technology and Business Department, Ningbo University of Technology, Ningbo, China
Trachevskyi Viacheslav

Technology and Business Department, Ningbo University of Technology, Ningbo, China

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APA Style

Karachevtseva Liudmyla, Kartel Mykola, Wang Bo, Lytvynenko Oleg, Onyshchenko Volodymyr, et al. (2019). “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening. International Journal of Materials Science and Applications, 8(6), 120-126. https://doi.org/10.11648/j.ijmsa.20190806.15

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ACS Style

Karachevtseva Liudmyla; Kartel Mykola; Wang Bo; Lytvynenko Oleg; Onyshchenko Volodymyr, et al. “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening. Int. J. Mater. Sci. Appl. 2019, 8(6), 120-126. doi: 10.11648/j.ijmsa.20190806.15

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AMA Style

Karachevtseva Liudmyla, Kartel Mykola, Wang Bo, Lytvynenko Oleg, Onyshchenko Volodymyr, et al. “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening. Int J Mater Sci Appl. 2019;8(6):120-126. doi: 10.11648/j.ijmsa.20190806.15

Copy | Download

@article{10.11648/j.ijmsa.20190806.15,
  author = {Karachevtseva Liudmyla and Kartel Mykola and Wang Bo and Lytvynenko Oleg and Onyshchenko Volodymyr and Sementsov Yurii and Trachevskyi Viacheslav},
  title = {“Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening},
  journal = {International Journal of Materials Science and Applications},
  volume = {8},
  number = {6},
  pages = {120-126},
  doi = {10.11648/j.ijmsa.20190806.15},
  url = {https://doi.org/10.11648/j.ijmsa.20190806.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20190806.15},
  abstract = {We analyzed “semiconductor” model of the “polymer-CNTs” composite strengthening at 300 K and low (0.1-0.5) wt% CNTs concentration. Carbon nanotubes are among the most anisotropic materials known and have extremely high values of Young's modulus. We investigated influence of vibration bonds on polymer crystallization and strengthening in composite films of polyethylenimine, polyamide, polypropylene and rubber with multiwall carbon nanotubes. IR absorbance maxima we evaluated after formation of composite “polyethylenimine-carbon nanotube” in the spectral area of the sp3 hybridization bonds at the frequency of primary amino groups of polyethylenimine. High IR absorption in the spectral area of sp3 hybridization bonds of polypropylene, polyamide-6 with carbon nanotubes is determined by γω(CН) and γω(CH2) vibrations. We measured IR reflectance maxima of composite “rubber-carbon nanotube” in the spectral area of CH valence and deformation vibrations. The IR peak dependence on the carbon nanotube content corresponds to 1D Gaussian curve for the diffusion equation in the electric field between electrons of nanotubes and protons in polymer according to “semiconductor” model of the composite structuring. For our case of the long-acting hundreds nanometer interactions, the polymer crystallization depends on sp3 C-C bonds organization in the intrinsic electric field according to the semiconductor n-p model. Tensile strength for polyamide-6 composites at 0.25% CNTs increases 1.7 times and tensile deformation – 2.3 times.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - “Semiconductor” Model of the “Polymer-CNTs” Composite Strengthening
AU  - Karachevtseva Liudmyla
AU  - Kartel Mykola
AU  - Wang Bo
AU  - Lytvynenko Oleg
AU  - Onyshchenko Volodymyr
AU  - Sementsov Yurii
AU  - Trachevskyi Viacheslav
Y1  - 2019/12/03
PY  - 2019
N1  - https://doi.org/10.11648/j.ijmsa.20190806.15
DO  - 10.11648/j.ijmsa.20190806.15
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 120
EP  - 126
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20190806.15
AB  - We analyzed “semiconductor” model of the “polymer-CNTs” composite strengthening at 300 K and low (0.1-0.5) wt% CNTs concentration. Carbon nanotubes are among the most anisotropic materials known and have extremely high values of Young's modulus. We investigated influence of vibration bonds on polymer crystallization and strengthening in composite films of polyethylenimine, polyamide, polypropylene and rubber with multiwall carbon nanotubes. IR absorbance maxima we evaluated after formation of composite “polyethylenimine-carbon nanotube” in the spectral area of the sp3 hybridization bonds at the frequency of primary amino groups of polyethylenimine. High IR absorption in the spectral area of sp3 hybridization bonds of polypropylene, polyamide-6 with carbon nanotubes is determined by γω(CН) and γω(CH2) vibrations. We measured IR reflectance maxima of composite “rubber-carbon nanotube” in the spectral area of CH valence and deformation vibrations. The IR peak dependence on the carbon nanotube content corresponds to 1D Gaussian curve for the diffusion equation in the electric field between electrons of nanotubes and protons in polymer according to “semiconductor” model of the composite structuring. For our case of the long-acting hundreds nanometer interactions, the polymer crystallization depends on sp3 C-C bonds organization in the intrinsic electric field according to the semiconductor n-p model. Tensile strength for polyamide-6 composites at 0.25% CNTs increases 1.7 times and tensile deformation – 2.3 times.
VL  - 8
IS  - 6
ER  -

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