Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives

Yanyang Qu; Qun Zeng; Jun Wang; Guijuan Fan; Jinglun Huang; Gaungchen Yang

doi:doi:10.11648/j.ijmsa.20180702.13

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Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives

Yanyang Qu, Qun Zeng, Jun Wang, Guijuan Fan, Jinglun Huang, Gaungchen Yang

Published in International Journal of Materials Science and Applications (Volume 7, Issue 2)

Received: 7 October 2017 Accepted: 23 October 2017 Published: 26 March 2018

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Abstract

Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, ¹H and ¹³C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm^-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.

Published in	International Journal of Materials Science and Applications (Volume 7, Issue 2)
DOI	10.11648/j.ijmsa.20180702.13
Page(s)	49-57
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Fused Heterocycles, 1,2,4-triazoles, tris[1,2,4]triazolo[1,3,5]triazine, 1,3,5-triazines, Benzotriazole Nitrogen Oxides, Synthetic Methods

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APA Style

Yanyang Qu, Qun Zeng, Jun Wang, Guijuan Fan, Jinglun Huang, et al. (2018). Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. International Journal of Materials Science and Applications, 7(2), 49-57. https://doi.org/10.11648/j.ijmsa.20180702.13

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ACS Style

Yanyang Qu; Qun Zeng; Jun Wang; Guijuan Fan; Jinglun Huang, et al. Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. Int. J. Mater. Sci. Appl. 2018, 7(2), 49-57. doi: 10.11648/j.ijmsa.20180702.13

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AMA Style

Yanyang Qu, Qun Zeng, Jun Wang, Guijuan Fan, Jinglun Huang, et al. Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. Int J Mater Sci Appl. 2018;7(2):49-57. doi: 10.11648/j.ijmsa.20180702.13

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@article{10.11648/j.ijmsa.20180702.13,
  author = {Yanyang Qu and Qun Zeng and Jun Wang and Guijuan Fan and Jinglun Huang and Gaungchen Yang},
  title = {Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives},
  journal = {International Journal of Materials Science and Applications},
  volume = {7},
  number = {2},
  pages = {49-57},
  doi = {10.11648/j.ijmsa.20180702.13},
  url = {https://doi.org/10.11648/j.ijmsa.20180702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20180702.13},
  abstract = {Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, 1H and 13C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.},
 year = {2018}
}

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TY  - JOUR
T1  - Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives
AU  - Yanyang Qu
AU  - Qun Zeng
AU  - Jun Wang
AU  - Guijuan Fan
AU  - Jinglun Huang
AU  - Gaungchen Yang
Y1  - 2018/03/26
PY  - 2018
N1  - https://doi.org/10.11648/j.ijmsa.20180702.13
DO  - 10.11648/j.ijmsa.20180702.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 49
EP  - 57
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20180702.13
AB  - Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, 1H and 13C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.
VL  - 7
IS  - 2
ER  -

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Author Information

Yanyang Qu

Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China
Qun Zeng

Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China
Jun Wang

Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China
Guijuan Fan

Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China
Jinglun Huang

Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China
Gaungchen Yang

Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China

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Plain Text BibTeX RIS

APA Style

Yanyang Qu, Qun Zeng, Jun Wang, Guijuan Fan, Jinglun Huang, et al. (2018). Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. International Journal of Materials Science and Applications, 7(2), 49-57. https://doi.org/10.11648/j.ijmsa.20180702.13

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ACS Style

Yanyang Qu; Qun Zeng; Jun Wang; Guijuan Fan; Jinglun Huang, et al. Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. Int. J. Mater. Sci. Appl. 2018, 7(2), 49-57. doi: 10.11648/j.ijmsa.20180702.13

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AMA Style

Yanyang Qu, Qun Zeng, Jun Wang, Guijuan Fan, Jinglun Huang, et al. Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. Int J Mater Sci Appl. 2018;7(2):49-57. doi: 10.11648/j.ijmsa.20180702.13

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@article{10.11648/j.ijmsa.20180702.13,
  author = {Yanyang Qu and Qun Zeng and Jun Wang and Guijuan Fan and Jinglun Huang and Gaungchen Yang},
  title = {Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives},
  journal = {International Journal of Materials Science and Applications},
  volume = {7},
  number = {2},
  pages = {49-57},
  doi = {10.11648/j.ijmsa.20180702.13},
  url = {https://doi.org/10.11648/j.ijmsa.20180702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20180702.13},
  abstract = {Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, 1H and 13C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives
AU  - Yanyang Qu
AU  - Qun Zeng
AU  - Jun Wang
AU  - Guijuan Fan
AU  - Jinglun Huang
AU  - Gaungchen Yang
Y1  - 2018/03/26
PY  - 2018
N1  - https://doi.org/10.11648/j.ijmsa.20180702.13
DO  - 10.11648/j.ijmsa.20180702.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 49
EP  - 57
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20180702.13
AB  - Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, 1H and 13C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.
VL  - 7
IS  - 2
ER  -

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