Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid

Hari Paudyal; Bimala Pangeni; Katsutoshi Inoue; Hiroyuki Harada; Hidetaka Kawakita; Keisuke Ohto; Shafiq Alam

doi:doi:10.11648/j.ijmsa.20170604.18

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Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid

Hari Paudyal, Bimala Pangeni, Katsutoshi Inoue, Hiroyuki Harada, Hidetaka Kawakita, Keisuke Ohto, Shafiq Alam

Published in International Journal of Materials Science and Applications (Volume 6, Issue 4)

Received: 7 June 2017 Accepted: 21 June 2017 Published: 24 July 2017

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Abstract

Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.

Published in	International Journal of Materials Science and Applications (Volume 6, Issue 4)
DOI	10.11648/j.ijmsa.20170604.18
Page(s)	212-222
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Fluoride Removal, Adsorption, Orange Juice Residue, Sulfuric Acid Treatment, Zr(IV) Loading

References

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APA Style

Hari Paudyal, Bimala Pangeni, Katsutoshi Inoue, Hiroyuki Harada, Hidetaka Kawakita, et al. (2017). Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. International Journal of Materials Science and Applications, 6(4), 212-222. https://doi.org/10.11648/j.ijmsa.20170604.18

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ACS Style

Hari Paudyal; Bimala Pangeni; Katsutoshi Inoue; Hiroyuki Harada; Hidetaka Kawakita, et al. Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. Int. J. Mater. Sci. Appl. 2017, 6(4), 212-222. doi: 10.11648/j.ijmsa.20170604.18

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AMA Style

Hari Paudyal, Bimala Pangeni, Katsutoshi Inoue, Hiroyuki Harada, Hidetaka Kawakita, et al. Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. Int J Mater Sci Appl. 2017;6(4):212-222. doi: 10.11648/j.ijmsa.20170604.18

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@article{10.11648/j.ijmsa.20170604.18,
  author = {Hari Paudyal and Bimala Pangeni and Katsutoshi Inoue and Hiroyuki Harada and Hidetaka Kawakita and Keisuke Ohto and Shafiq Alam},
  title = {Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid},
  journal = {International Journal of Materials Science and Applications},
  volume = {6},
  number = {4},
  pages = {212-222},
  doi = {10.11648/j.ijmsa.20170604.18},
  url = {https://doi.org/10.11648/j.ijmsa.20170604.18},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20170604.18},
  abstract = {Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.},
 year = {2017}
}

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TY  - JOUR
T1  - Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid
AU  - Hari Paudyal
AU  - Bimala Pangeni
AU  - Katsutoshi Inoue
AU  - Hiroyuki Harada
AU  - Hidetaka Kawakita
AU  - Keisuke Ohto
AU  - Shafiq Alam
Y1  - 2017/07/24
PY  - 2017
N1  - https://doi.org/10.11648/j.ijmsa.20170604.18
DO  - 10.11648/j.ijmsa.20170604.18
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 212
EP  - 222
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20170604.18
AB  - Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.
VL  - 6
IS  - 4
ER  -

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Author Information

Hari Paudyal

Department of Applied Chemistry, Saga University, Saga, Japan
Bimala Pangeni

Department of Applied Chemistry, Saga University, Saga, Japan
Katsutoshi Inoue

Department of Applied Chemistry, Saga University, Saga, Japan
Hiroyuki Harada

Department of Environmental Sciences, Prefectural University of Hiroshima, Hiroshima, Japan
Hidetaka Kawakita

Department of Applied Chemistry, Saga University, Saga, Japan
Keisuke Ohto

Department of Applied Chemistry, Saga University, Saga, Japan
Shafiq Alam

Department of Science, Memorial University, St. John’s, NL, Canada

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APA Style

Hari Paudyal, Bimala Pangeni, Katsutoshi Inoue, Hiroyuki Harada, Hidetaka Kawakita, et al. (2017). Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. International Journal of Materials Science and Applications, 6(4), 212-222. https://doi.org/10.11648/j.ijmsa.20170604.18

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ACS Style

Hari Paudyal; Bimala Pangeni; Katsutoshi Inoue; Hiroyuki Harada; Hidetaka Kawakita, et al. Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. Int. J. Mater. Sci. Appl. 2017, 6(4), 212-222. doi: 10.11648/j.ijmsa.20170604.18

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AMA Style

Hari Paudyal, Bimala Pangeni, Katsutoshi Inoue, Hiroyuki Harada, Hidetaka Kawakita, et al. Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. Int J Mater Sci Appl. 2017;6(4):212-222. doi: 10.11648/j.ijmsa.20170604.18

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@article{10.11648/j.ijmsa.20170604.18,
  author = {Hari Paudyal and Bimala Pangeni and Katsutoshi Inoue and Hiroyuki Harada and Hidetaka Kawakita and Keisuke Ohto and Shafiq Alam},
  title = {Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid},
  journal = {International Journal of Materials Science and Applications},
  volume = {6},
  number = {4},
  pages = {212-222},
  doi = {10.11648/j.ijmsa.20170604.18},
  url = {https://doi.org/10.11648/j.ijmsa.20170604.18},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20170604.18},
  abstract = {Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.},
 year = {2017}
}

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TY  - JOUR
T1  - Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid
AU  - Hari Paudyal
AU  - Bimala Pangeni
AU  - Katsutoshi Inoue
AU  - Hiroyuki Harada
AU  - Hidetaka Kawakita
AU  - Keisuke Ohto
AU  - Shafiq Alam
Y1  - 2017/07/24
PY  - 2017
N1  - https://doi.org/10.11648/j.ijmsa.20170604.18
DO  - 10.11648/j.ijmsa.20170604.18
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 212
EP  - 222
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20170604.18
AB  - Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.
VL  - 6
IS  - 4
ER  -

Copy | Download