A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics.
Published in | International Journal of Materials Science and Applications (Volume 4, Issue 4) |
DOI | 10.11648/j.ijmsa.20150404.14 |
Page(s) | 246-255 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Copyright © The Author(s), 2015. Published by Science Publishing Group |
GO, Ag3PO4, AgCl, RhB and Simulated Sunlight Irradiation
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APA Style
Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Dong Dong Qin, Hind Baballa, Duoliang Shan, et al. (2015). Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. International Journal of Materials Science and Applications, 4(4), 246-255. https://doi.org/10.11648/j.ijmsa.20150404.14
ACS Style
Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris; Dong Dong Qin; Hind Baballa; Duoliang Shan, et al. Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. Int. J. Mater. Sci. Appl. 2015, 4(4), 246-255. doi: 10.11648/j.ijmsa.20150404.14
AMA Style
Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Dong Dong Qin, Hind Baballa, Duoliang Shan, et al. Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. Int J Mater Sci Appl. 2015;4(4):246-255. doi: 10.11648/j.ijmsa.20150404.14
@article{10.11648/j.ijmsa.20150404.14, author = {Mahgoub Ibrahim Shinger and Ahmed Mahmoud Idris and Dong Dong Qin and Hind Baballa and Duoliang Shan and Xiaoquan Lu}, title = {Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl}, journal = {International Journal of Materials Science and Applications}, volume = {4}, number = {4}, pages = {246-255}, doi = {10.11648/j.ijmsa.20150404.14}, url = {https://doi.org/10.11648/j.ijmsa.20150404.14}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20150404.14}, abstract = {A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics.}, year = {2015} }
TY - JOUR T1 - Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl AU - Mahgoub Ibrahim Shinger AU - Ahmed Mahmoud Idris AU - Dong Dong Qin AU - Hind Baballa AU - Duoliang Shan AU - Xiaoquan Lu Y1 - 2015/06/30 PY - 2015 N1 - https://doi.org/10.11648/j.ijmsa.20150404.14 DO - 10.11648/j.ijmsa.20150404.14 T2 - International Journal of Materials Science and Applications JF - International Journal of Materials Science and Applications JO - International Journal of Materials Science and Applications SP - 246 EP - 255 PB - Science Publishing Group SN - 2327-2643 UR - https://doi.org/10.11648/j.ijmsa.20150404.14 AB - A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics. VL - 4 IS - 4 ER -