In the paper is submitted opinion according to which, a part of the hydrated exchangeable cations in the montmorillonite is hydrolyzed. A new experimental method has been proposed, which allows to estimate the hydrated/hydrolyzed state of these cations. The method consists in the use of thermal analysis data of mineral, and is particularly effective in the study of homoionic forms of montmorillonite. The mathematical formulas have been proposed for processing the obtained experimental data.
Published in | International Journal of Materials Science and Applications (Volume 4, Issue 2) |
DOI | 10.11648/j.ijmsa.20150402.19 |
Page(s) | 124-129 |
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Thermal Analysis, Montmorillonite, Exchangeable Cations, Interlayer Water, Hydrolyzed Cations, Mathematical Processing of Data
[1] | Handbook of clay science (eds. Bergaya F., Theng B.K.G. and Lagaly G.). Amsterdam: Elsevier Ltd., 2006. |
[2] | Clay Minerals in Nature: Their Characterization, Modification and Application. (eds.Valašcova M. and Martynkova G.S.). Rijeka: InTech., 2012, - 312 p. DOI: 10.5772/2708. |
[3] | Wilson M.J. Rock-forming minerals. V.3C (second ed.). Sheet Silicates: Clay Minerals. London: The Geolog. Society Publ. House, 2013, pp. 210-256. |
[4] | The practical importance of bentonite. www.activator.ru/rus/5.php. |
[5] | McKeown Nancy K., Bishop Janice L., Cuadros Javier, Hiller Stefen, Amador Elena, Macarewicz Heather D., Parente Mario, and Silver Eli A.Interpretation of reflectance spectra of clay mineral-silica mixtures: implications for Martian clay Mineralogy at Mawrth Vallis – Clays and Clay Minerals, 2011, v.59, pp. 400-415. |
[6] | McKeown Nancy K. Water on ancient Mars: Forming the phyllosilicates (dissertation). udini.proquest.com/view/Water-on-ancient-mars-forming-the-goid: 751246813. |
[7] | Render D. Chemistry in Space: From Interstellar Matter to Origin of Life. Weinheim : Willey-VCH Verlag & Co.Kga, 2010, - 291 p. |
[8] | Ostrowski D.R., Lacy C.H., Gietzen K.M. and Sears D.W.G. IRTF spectra for 17 asteroids from C and X complexes: A discussion of continuum slopes and their relationships to chondrites and phillosilicates. – Icarus, 2011, v.212, No 2, pp. 682-696. |
[9] | Rietmeiyer F.J.M., Thiel K. An experimental study of phyllosilicate modification in comets during perihelion could be relevant to ferric iron-rich layer silicate formation at the martian surface. – Ground From Mars (2008). www.lpi.usra.edu/meetings/msr 2008/pdf/4008.pdf. |
[10] | Lisandro J., Campins H., Mothé-Diniz T.,Pinilla-Alonso N.,and de Leon J.. The nature of comet-asteroid transition object (3200) Phaethon. – Astronomy and Astrophysics, 2007, v.461, No 2, pp. 751-757. |
[11] | Saladino R., Crestini Claudia, Ciambecchini U., Cicirello F., Constanzo G., and Di Mauro E. Synthesis and Degradation of Nucleobases and Nucleic Acids by Formamid in Presence of Montmorillonite.– ChemBioChem., 2004, No 5, pp. 1-9. |
[12] | Ferris J.P. Mineral Catalysis and Prebiotic Synthesis: Montmorillonite – Catalized Formation of RNA – Elements, 2005, v.1, pp. 145-149. |
[13] | Ferris J.P. Montmorillonite – catalysed formation of RNA oligomers: the possible role of catalysis in the origin of life. – Phil. Trans. Soc. B., 2006, v.361, No 1474, pp.1777-1786. |
[14] | Hashizume H. Role of Clay Minerals in Chemical Evolution and the Origin of Life In.: Clay Minerals in Nature: Their Characterization, Modification and Application. (eds.Valašcova M. and Martynkova G.S.), chapter 10. Rijeka: InTech., 2012. |
[15] | DOI: 10.5772/50172. |
[16] | Bishop J.L. and Murad E. Characterization of mineral and biogeochemical markers on Mars: A Raman and IR spectroscopic study of montmorillonite. – Journal of Raman Spectroscopy, 2004, v. 35, pp. 480 - 486. DOI: 10.1002/jrs.1173. |
[17] | Hoang-Minh Thao. Characterization on Clays and Clay Mine- rals for Industrial Applications: Substitution non-Natural Additives by Clays in UV Protection (dissertation). Greifswald (Germany), 2006, - 168 p. (d-nb.info/984459022/34). |
[18] | Földvári M., Kovács-Pálffy P., Nagy N.M., Konya J. Use of the second derivative of TG curves for investigation of the exchanged interlayer cation in montmorillonite. – J. Thermal Anal., 1998, v. 53, pp. 547-558. |
[19] | Yan L., Xiajun W. and Juanfang W. Cation exchange, interlayer spacing, and thermal analysis of Na/Ca - montmorillonite modified with alkaline and alkaline earth metal ions. – J.Thermal Anal. Calorimetry, 2012, v.110, No 3, pp.1199-1201. |
[20] | Maftuleac A., Dranca I. and Lupaşcu T. Study of interlayer water on the active sites of mineral sorbent. – Journal Thermal Anal. Calorimetry, 2002, v.69, pp. 589-598. |
[21] | Tarasevich Iu.I. and Ovcharenko F.D. Adsorbtion onto clay minerals. Kiev: Naukova dumka, 1975, - 351 p. (in Russian). |
[22] | Kuyanov-Prozument K., Choi Vong Myong and Vilesov A.F. Spectrum and intensities of OH-strenching bands of water dimmers. – J. Chem. Phys.,v.132, 014304(2010). DOI: 10.1063/1.3276459. |
[23] | Lo Sh.Y., Geng X. and Gann D. Evidence for the existence of stable-water-clusters at room temperature. – Phys. Letters A, 2009, DOI: 10.1016/j.physleta2009.08061. |
[24] | Zakharov S.D. and Mosyagina I.V. The cluster structure of water. Moscow: Preprint, Lebedev Phys. Inst. Acad. Sci., (prints.lebedev.ru/wp-content/uploads/2011/12/35_11_pr.pdf).2011, - 26 p. (in Russian). |
[25] | Sinyukov V.V. The structure of monoatomic liquids, water and aqueous solutions of electrolytes. Moscow: Nauka, 1976, - 256 p. (in Russian). |
[26] | Zundel G. Hydration and Intermolecular Interaction. Infrared Investigation with Polyelectrolyte Membranes. N.Y.- London: Academic Press, 1969 (in Russian: Mir, 1972). |
[27] | Melnichenko N.A. Modern ideas about the structure of water and aqueous solutions of electrolytes, including seawater. Vladivostok: Publ. Far East. Univ., 2009, - 76 p. (in Russian). |
[28] | Tarasevich Iu.I. The natural sorbents in water treatment processes. Kiev: Naukova dumka, 1981, - 207 p. (in Russian). |
[29] | Tarasevich Iu.I. Surface structure and chemistry of layer silicates. Kiev: Naukova dumka, 1988, - 247 p. (in Russian). |
[30] | Osipov V.I., Sokolov V.N. and Rumyantseva N.A . Microstructure of the clay rocks. Moskow: Nedra, 1989, pp. 61-64. (in Russian). |
[31] | Velde B. and Meuner A. The Origin of Clay Minerals in Soils and Weathered Rocks. Berlin, Heidelberg: Springer-Verlag, 2008. (Chapter 1.5.2, The Cristallite Outer Surface). |
[32] | Sposito G. The surface chemistry of soils. Oxford Univ. Press., New York, 1984. |
[33] | Sposito G., Skipper N.T., Sutton Rebecca et al. Surface geochemistry of the clay minerals.- Proc. Nat. Acad. Sci. USA, 1999, v.96, pp. 3358-3364. |
[34] | Avena M.J. Acid-Base Behavior of Clay Surface in Aqueous Media. In: Encyclopedia of Surface and Colloid Science, v.3, (ed.Somasundaran P.), UK: Taylor and Francis, 2006, pp. 17- 46. |
[35] | Gerken M. Hydrolysis of cations and acidity of aqua complexes of metal cations. In: Chemistry 2810 Lecture Notes, (classes.uleth.ca/200501/chem2810a/lecture_8.pdf). |
[36] | Maftuleac A., Lupaşcu T., and Motoc V. Adsorption of Fulvic Acids on Montmorillonite and its Dependence on pH. – Bull. Acad. Sci. of Moldova (Biol.,Chem.), 1996, No 2, pp. 54-59. (in Romanian). |
APA Style
Alexei Maftuleac. (2015). The Hydrated and Hydrolyzed States of Exchangeable Cations in the Montmorillonite and Their Quantitative Assessment. International Journal of Materials Science and Applications, 4(2), 124-129. https://doi.org/10.11648/j.ijmsa.20150402.19
ACS Style
Alexei Maftuleac. The Hydrated and Hydrolyzed States of Exchangeable Cations in the Montmorillonite and Their Quantitative Assessment. Int. J. Mater. Sci. Appl. 2015, 4(2), 124-129. doi: 10.11648/j.ijmsa.20150402.19
AMA Style
Alexei Maftuleac. The Hydrated and Hydrolyzed States of Exchangeable Cations in the Montmorillonite and Their Quantitative Assessment. Int J Mater Sci Appl. 2015;4(2):124-129. doi: 10.11648/j.ijmsa.20150402.19
@article{10.11648/j.ijmsa.20150402.19, author = {Alexei Maftuleac}, title = {The Hydrated and Hydrolyzed States of Exchangeable Cations in the Montmorillonite and Their Quantitative Assessment}, journal = {International Journal of Materials Science and Applications}, volume = {4}, number = {2}, pages = {124-129}, doi = {10.11648/j.ijmsa.20150402.19}, url = {https://doi.org/10.11648/j.ijmsa.20150402.19}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20150402.19}, abstract = {In the paper is submitted opinion according to which, a part of the hydrated exchangeable cations in the montmorillonite is hydrolyzed. A new experimental method has been proposed, which allows to estimate the hydrated/hydrolyzed state of these cations. The method consists in the use of thermal analysis data of mineral, and is particularly effective in the study of homoionic forms of montmorillonite. The mathematical formulas have been proposed for processing the obtained experimental data.}, year = {2015} }
TY - JOUR T1 - The Hydrated and Hydrolyzed States of Exchangeable Cations in the Montmorillonite and Their Quantitative Assessment AU - Alexei Maftuleac Y1 - 2015/04/09 PY - 2015 N1 - https://doi.org/10.11648/j.ijmsa.20150402.19 DO - 10.11648/j.ijmsa.20150402.19 T2 - International Journal of Materials Science and Applications JF - International Journal of Materials Science and Applications JO - International Journal of Materials Science and Applications SP - 124 EP - 129 PB - Science Publishing Group SN - 2327-2643 UR - https://doi.org/10.11648/j.ijmsa.20150402.19 AB - In the paper is submitted opinion according to which, a part of the hydrated exchangeable cations in the montmorillonite is hydrolyzed. A new experimental method has been proposed, which allows to estimate the hydrated/hydrolyzed state of these cations. The method consists in the use of thermal analysis data of mineral, and is particularly effective in the study of homoionic forms of montmorillonite. The mathematical formulas have been proposed for processing the obtained experimental data. VL - 4 IS - 2 ER -