Removal of Pb<sup>+2</sup> and Cd<sup>+2</sup> from Aqueous Solution by Using Faujasite

Fatma Mohamed Dardir; Ezzat Abdalla Ahmed; Mamdouh Farag Soliman; Mostafa Ragab Abukhadra

doi:doi:10.11648/j.ijmpem.20230801.11

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Removal of Pb⁺² and Cd⁺² from Aqueous Solution by Using Faujasite

Fatma Mohamed Dardir, Ezzat Abdalla Ahmed, Mamdouh Farag Soliman, Mostafa Ragab Abukhadra

Published in International Journal of Mineral Processing and Extractive Metallurgy (Volume 8, Issue 1)

Received: 16 March 2023 Accepted: 7 April 2023 Published: 17 May 2023

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Abstract

The excess amount of lead (Pb⁺²) and cadmium (Cd⁺²) in the drinking water system lead to affect immunity and kidney failure problems. To overcome such troubles by developing well-crystalline faujasite minerals that are synthesized from claystone by the hydrothermal process may be the current trend For the effective adsorption of these cations. The active functional group, thermal nature, crystallinity surface, texture properties, and porous surface nature of faujasite were investigated using X-ray diffraction, scanning electron microscopy, Fourier-transform infrared, and nitrogen sorption 77k studies. The maximum removal of Pb⁺² and Cd⁺² was found to be 98% and 85% respectively using 60 mg and 70 mg from the adsorbent material. Moreover, the measured uptake capacity of Pb⁺² and Cd⁺² was 351.3 mg/g and 97.2 mg/g at equilibrium times of 50 min and 80 min respectively. Therefore, different adsorption isotherm and kinetic models were investigated. Accordingly, adsorption isotherms were the best fit for the Langmuir isotherm model. Moreover, the adsorption process for the two adsorbate cation was followed by the pseudo-second-order kinetics (R² >0.9), Elovich (R² >0.9 for Pb⁺² and 0.86 for Cd⁺²), and Langmuir (R² >0.9 for Pb⁺² and 0.85 for Cd⁺²). This indicates that the adsorption process via monolayer formation with chemical sharing or/and ion exchange process occurs on the energetically heterogeneous surface.

Published in	International Journal of Mineral Processing and Extractive Metallurgy (Volume 8, Issue 1)
DOI	10.11648/j.ijmpem.20230801.11
Page(s)	1-8
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Claystone, Faujasite, Adsorption, Lead, Cadmium, Kinetic, Isothermal Models

References

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Fatma Mohamed Dardir, Ezzat Abdalla Ahmed, Mamdouh Farag Soliman, Mostafa Ragab Abukhadra. (2023). Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite. International Journal of Mineral Processing and Extractive Metallurgy, 8(1), 1-8. https://doi.org/10.11648/j.ijmpem.20230801.11

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ACS Style

Fatma Mohamed Dardir; Ezzat Abdalla Ahmed; Mamdouh Farag Soliman; Mostafa Ragab Abukhadra. Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite. Int. J. Miner. Process. Extr. Metall. 2023, 8(1), 1-8. doi: 10.11648/j.ijmpem.20230801.11

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AMA Style

Fatma Mohamed Dardir, Ezzat Abdalla Ahmed, Mamdouh Farag Soliman, Mostafa Ragab Abukhadra. Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite. Int J Miner Process Extr Metall. 2023;8(1):1-8. doi: 10.11648/j.ijmpem.20230801.11

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@article{10.11648/j.ijmpem.20230801.11,
  author = {Fatma Mohamed Dardir and Ezzat Abdalla Ahmed and Mamdouh Farag Soliman and Mostafa Ragab Abukhadra},
  title = {Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite},
  journal = {International Journal of Mineral Processing and Extractive Metallurgy},
  volume = {8},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.ijmpem.20230801.11},
  url = {https://doi.org/10.11648/j.ijmpem.20230801.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmpem.20230801.11},
  abstract = {The excess amount of lead (Pb+2) and cadmium (Cd+2) in the drinking water system lead to affect immunity and kidney failure problems. To overcome such troubles by developing well-crystalline faujasite minerals that are synthesized from claystone by the hydrothermal process may be the current trend For the effective adsorption of these cations. The active functional group, thermal nature, crystallinity surface, texture properties, and porous surface nature of faujasite were investigated using X-ray diffraction, scanning electron microscopy, Fourier-transform infrared, and nitrogen sorption 77k studies. The maximum removal of Pb+2 and Cd+2 was found to be 98% and 85% respectively using 60 mg and 70 mg from the adsorbent material. Moreover, the measured uptake capacity of Pb+2 and Cd+2 was 351.3 mg/g and 97.2 mg/g at equilibrium times of 50 min and 80 min respectively. Therefore, different adsorption isotherm and kinetic models were investigated. Accordingly, adsorption isotherms were the best fit for the Langmuir isotherm model. Moreover, the adsorption process for the two adsorbate cation was followed by the pseudo-second-order kinetics (R2 >0.9), Elovich (R2 >0.9 for Pb+2 and 0.86 for Cd+2), and Langmuir (R2 >0.9 for Pb+2 and 0.85 for Cd+2). This indicates that the adsorption process via monolayer formation with chemical sharing or/and ion exchange process occurs on the energetically heterogeneous surface.},
 year = {2023}
}

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TY  - JOUR
T1  - Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite
AU  - Fatma Mohamed Dardir
AU  - Ezzat Abdalla Ahmed
AU  - Mamdouh Farag Soliman
AU  - Mostafa Ragab Abukhadra
Y1  - 2023/05/17
PY  - 2023
N1  - https://doi.org/10.11648/j.ijmpem.20230801.11
DO  - 10.11648/j.ijmpem.20230801.11
T2  - International Journal of Mineral Processing and Extractive Metallurgy
JF  - International Journal of Mineral Processing and Extractive Metallurgy
JO  - International Journal of Mineral Processing and Extractive Metallurgy
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-1859
UR  - https://doi.org/10.11648/j.ijmpem.20230801.11
AB  - The excess amount of lead (Pb+2) and cadmium (Cd+2) in the drinking water system lead to affect immunity and kidney failure problems. To overcome such troubles by developing well-crystalline faujasite minerals that are synthesized from claystone by the hydrothermal process may be the current trend For the effective adsorption of these cations. The active functional group, thermal nature, crystallinity surface, texture properties, and porous surface nature of faujasite were investigated using X-ray diffraction, scanning electron microscopy, Fourier-transform infrared, and nitrogen sorption 77k studies. The maximum removal of Pb+2 and Cd+2 was found to be 98% and 85% respectively using 60 mg and 70 mg from the adsorbent material. Moreover, the measured uptake capacity of Pb+2 and Cd+2 was 351.3 mg/g and 97.2 mg/g at equilibrium times of 50 min and 80 min respectively. Therefore, different adsorption isotherm and kinetic models were investigated. Accordingly, adsorption isotherms were the best fit for the Langmuir isotherm model. Moreover, the adsorption process for the two adsorbate cation was followed by the pseudo-second-order kinetics (R2 >0.9), Elovich (R2 >0.9 for Pb+2 and 0.86 for Cd+2), and Langmuir (R2 >0.9 for Pb+2 and 0.85 for Cd+2). This indicates that the adsorption process via monolayer formation with chemical sharing or/and ion exchange process occurs on the energetically heterogeneous surface.
VL  - 8
IS  - 1
ER  -

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Author Information

Fatma Mohamed Dardir

Geology Department, Faculty of Science, Assiut University, Asyut, Egypt
Ezzat Abdalla Ahmed

Geology Department, Faculty of Science, Assiut University, Asyut, Egypt
Mamdouh Farag Soliman

Geology Department, Faculty of Science, Assiut University, Asyut, Egypt
Mostafa Ragab Abukhadra

Geology Department, Faculty of Science, Beni-Suef University, Beni Suef, Egypt

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Fatma Mohamed Dardir, Ezzat Abdalla Ahmed, Mamdouh Farag Soliman, Mostafa Ragab Abukhadra. (2023). Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite. International Journal of Mineral Processing and Extractive Metallurgy, 8(1), 1-8. https://doi.org/10.11648/j.ijmpem.20230801.11

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Fatma Mohamed Dardir; Ezzat Abdalla Ahmed; Mamdouh Farag Soliman; Mostafa Ragab Abukhadra. Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite. Int. J. Miner. Process. Extr. Metall. 2023, 8(1), 1-8. doi: 10.11648/j.ijmpem.20230801.11

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AMA Style

Fatma Mohamed Dardir, Ezzat Abdalla Ahmed, Mamdouh Farag Soliman, Mostafa Ragab Abukhadra. Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite. Int J Miner Process Extr Metall. 2023;8(1):1-8. doi: 10.11648/j.ijmpem.20230801.11

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@article{10.11648/j.ijmpem.20230801.11,
  author = {Fatma Mohamed Dardir and Ezzat Abdalla Ahmed and Mamdouh Farag Soliman and Mostafa Ragab Abukhadra},
  title = {Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite},
  journal = {International Journal of Mineral Processing and Extractive Metallurgy},
  volume = {8},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.ijmpem.20230801.11},
  url = {https://doi.org/10.11648/j.ijmpem.20230801.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmpem.20230801.11},
  abstract = {The excess amount of lead (Pb+2) and cadmium (Cd+2) in the drinking water system lead to affect immunity and kidney failure problems. To overcome such troubles by developing well-crystalline faujasite minerals that are synthesized from claystone by the hydrothermal process may be the current trend For the effective adsorption of these cations. The active functional group, thermal nature, crystallinity surface, texture properties, and porous surface nature of faujasite were investigated using X-ray diffraction, scanning electron microscopy, Fourier-transform infrared, and nitrogen sorption 77k studies. The maximum removal of Pb+2 and Cd+2 was found to be 98% and 85% respectively using 60 mg and 70 mg from the adsorbent material. Moreover, the measured uptake capacity of Pb+2 and Cd+2 was 351.3 mg/g and 97.2 mg/g at equilibrium times of 50 min and 80 min respectively. Therefore, different adsorption isotherm and kinetic models were investigated. Accordingly, adsorption isotherms were the best fit for the Langmuir isotherm model. Moreover, the adsorption process for the two adsorbate cation was followed by the pseudo-second-order kinetics (R2 >0.9), Elovich (R2 >0.9 for Pb+2 and 0.86 for Cd+2), and Langmuir (R2 >0.9 for Pb+2 and 0.85 for Cd+2). This indicates that the adsorption process via monolayer formation with chemical sharing or/and ion exchange process occurs on the energetically heterogeneous surface.},
 year = {2023}
}

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TY  - JOUR
T1  - Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite
AU  - Fatma Mohamed Dardir
AU  - Ezzat Abdalla Ahmed
AU  - Mamdouh Farag Soliman
AU  - Mostafa Ragab Abukhadra
Y1  - 2023/05/17
PY  - 2023
N1  - https://doi.org/10.11648/j.ijmpem.20230801.11
DO  - 10.11648/j.ijmpem.20230801.11
T2  - International Journal of Mineral Processing and Extractive Metallurgy
JF  - International Journal of Mineral Processing and Extractive Metallurgy
JO  - International Journal of Mineral Processing and Extractive Metallurgy
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-1859
UR  - https://doi.org/10.11648/j.ijmpem.20230801.11
AB  - The excess amount of lead (Pb+2) and cadmium (Cd+2) in the drinking water system lead to affect immunity and kidney failure problems. To overcome such troubles by developing well-crystalline faujasite minerals that are synthesized from claystone by the hydrothermal process may be the current trend For the effective adsorption of these cations. The active functional group, thermal nature, crystallinity surface, texture properties, and porous surface nature of faujasite were investigated using X-ray diffraction, scanning electron microscopy, Fourier-transform infrared, and nitrogen sorption 77k studies. The maximum removal of Pb+2 and Cd+2 was found to be 98% and 85% respectively using 60 mg and 70 mg from the adsorbent material. Moreover, the measured uptake capacity of Pb+2 and Cd+2 was 351.3 mg/g and 97.2 mg/g at equilibrium times of 50 min and 80 min respectively. Therefore, different adsorption isotherm and kinetic models were investigated. Accordingly, adsorption isotherms were the best fit for the Langmuir isotherm model. Moreover, the adsorption process for the two adsorbate cation was followed by the pseudo-second-order kinetics (R2 >0.9), Elovich (R2 >0.9 for Pb+2 and 0.86 for Cd+2), and Langmuir (R2 >0.9 for Pb+2 and 0.85 for Cd+2). This indicates that the adsorption process via monolayer formation with chemical sharing or/and ion exchange process occurs on the energetically heterogeneous surface.
VL  - 8
IS  - 1
ER  -

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