Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media

Arijit Mondal; Sanhati Das; Amit Das; Sukanta Paul; Deb Kumar Mukherjee

doi:doi:10.11648/j.ijec.20230702.12

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Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media

Arijit Mondal, Sanhati Das, Amit Das, Sukanta Paul, Deb Kumar Mukherjee

Published in International Journal of Environmental Chemistry (Volume 7, Issue 2)

Received: 14 June 2023 Accepted: 13 July 2023 Published: 10 August 2023

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Abstract

Reduction of organophosphate group of pesticides catalyzed by bimetallic nickel cobalt nanoparticles (NiCoNPs) in presence of sodium borohydride has been discussed. An easy, simple, quick and economically feasible approach has been made to synthesize the good ordered structures of hetero nanoparticles. These air stable nanoclusters could be synthesized most economically using nickel sulphate and cobalt sulphate salts with tetrabutyl ammonium bromide as surfactant and sodium borohydride as reducing reagent. The nanoparticles were used to degrade pesticides like profenofos and imidacloprid under ambient conditions in aqueous media. The concentrations of Profenofos (PFF) were quantified by measuring the absorption intensities at λ_max288 nm after treatment with KOH solution. The nickel nanocolloids in common organic solvents were found to be good catalysts for the reductive transformation of Profenofos but suffer considerable deactivation during recycling steps. The bimetallic group of particles containing cobalt and nickel however can be easily recovered and recycled three-four times without loss of catalytic activity. The bimetallic nanoclusters having average particle size 90-120 nm can degrade organophosphate group of pesticides within 120 minutes which is much less compared to photodegradation of such similar pesticides as reported in literatures. The study can become a protocol for waste water management with environmental benefits, strengthening the need of green chemistry in industrial projects.

Published in	International Journal of Environmental Chemistry (Volume 7, Issue 2)
DOI	10.11648/j.ijec.20230702.12
Page(s)	38-46
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Nickel Nanoparticles, Bimetallic Nanoclusters, Profenofos, Reduction, Catalytic Properties, Transmission Electron Microscopy

References

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APA Style

Arijit Mondal, Sanhati Das, Amit Das, Sukanta Paul, Deb Kumar Mukherjee. (2023). Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media. International Journal of Environmental Chemistry, 7(2), 38-46. https://doi.org/10.11648/j.ijec.20230702.12

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ACS Style

Arijit Mondal; Sanhati Das; Amit Das; Sukanta Paul; Deb Kumar Mukherjee. Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media. Int. J. Environ. Chem. 2023, 7(2), 38-46. doi: 10.11648/j.ijec.20230702.12

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AMA Style

Arijit Mondal, Sanhati Das, Amit Das, Sukanta Paul, Deb Kumar Mukherjee. Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media. Int J Environ Chem. 2023;7(2):38-46. doi: 10.11648/j.ijec.20230702.12

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@article{10.11648/j.ijec.20230702.12,
  author = {Arijit Mondal and Sanhati Das and Amit Das and Sukanta Paul and Deb Kumar Mukherjee},
  title = {Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media},
  journal = {International Journal of Environmental Chemistry},
  volume = {7},
  number = {2},
  pages = {38-46},
  doi = {10.11648/j.ijec.20230702.12},
  url = {https://doi.org/10.11648/j.ijec.20230702.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijec.20230702.12},
  abstract = {Reduction of organophosphate group of pesticides catalyzed by bimetallic nickel cobalt nanoparticles (NiCoNPs) in presence of sodium borohydride has been discussed. An easy, simple, quick and economically feasible approach has been made to synthesize the good ordered structures of hetero nanoparticles. These air stable nanoclusters could be synthesized most economically using nickel sulphate and cobalt sulphate salts with tetrabutyl ammonium bromide as surfactant and sodium borohydride as reducing reagent. The nanoparticles were used to degrade pesticides like profenofos and imidacloprid under ambient conditions in aqueous media. The concentrations of Profenofos (PFF) were quantified by measuring the absorption intensities at λmax288 nm after treatment with KOH solution. The nickel nanocolloids in common organic solvents were found to be good catalysts for the reductive transformation of Profenofos but suffer considerable deactivation during recycling steps. The bimetallic group of particles containing cobalt and nickel however can be easily recovered and recycled three-four times without loss of catalytic activity. The bimetallic nanoclusters having average particle size 90-120 nm can degrade organophosphate group of pesticides within 120 minutes which is much less compared to photodegradation of such similar pesticides as reported in literatures. The study can become a protocol for waste water management with environmental benefits, strengthening the need of green chemistry in industrial projects.},
 year = {2023}
}

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TY  - JOUR
T1  - Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media
AU  - Arijit Mondal
AU  - Sanhati Das
AU  - Amit Das
AU  - Sukanta Paul
AU  - Deb Kumar Mukherjee
Y1  - 2023/08/10
PY  - 2023
N1  - https://doi.org/10.11648/j.ijec.20230702.12
DO  - 10.11648/j.ijec.20230702.12
T2  - International Journal of Environmental Chemistry
JF  - International Journal of Environmental Chemistry
JO  - International Journal of Environmental Chemistry
SP  - 38
EP  - 46
PB  - Science Publishing Group
SN  - 2640-1460
UR  - https://doi.org/10.11648/j.ijec.20230702.12
AB  - Reduction of organophosphate group of pesticides catalyzed by bimetallic nickel cobalt nanoparticles (NiCoNPs) in presence of sodium borohydride has been discussed. An easy, simple, quick and economically feasible approach has been made to synthesize the good ordered structures of hetero nanoparticles. These air stable nanoclusters could be synthesized most economically using nickel sulphate and cobalt sulphate salts with tetrabutyl ammonium bromide as surfactant and sodium borohydride as reducing reagent. The nanoparticles were used to degrade pesticides like profenofos and imidacloprid under ambient conditions in aqueous media. The concentrations of Profenofos (PFF) were quantified by measuring the absorption intensities at λmax288 nm after treatment with KOH solution. The nickel nanocolloids in common organic solvents were found to be good catalysts for the reductive transformation of Profenofos but suffer considerable deactivation during recycling steps. The bimetallic group of particles containing cobalt and nickel however can be easily recovered and recycled three-four times without loss of catalytic activity. The bimetallic nanoclusters having average particle size 90-120 nm can degrade organophosphate group of pesticides within 120 minutes which is much less compared to photodegradation of such similar pesticides as reported in literatures. The study can become a protocol for waste water management with environmental benefits, strengthening the need of green chemistry in industrial projects.
VL  - 7
IS  - 2
ER  -

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Author Information

Arijit Mondal

Department of Chemistry, Ramsaday College, Howrah, India
Sanhati Das

Department of Chemistry, Ramsaday College, Howrah, India
Amit Das

Department of Chemistry, Ramsaday College, Howrah, India
Sukanta Paul

Department of Chemistry, Ramsaday College, Howrah, India
Deb Kumar Mukherjee

Department of Chemistry, Ramsaday College, Howrah, India

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APA Style

Arijit Mondal, Sanhati Das, Amit Das, Sukanta Paul, Deb Kumar Mukherjee. (2023). Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media. International Journal of Environmental Chemistry, 7(2), 38-46. https://doi.org/10.11648/j.ijec.20230702.12

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ACS Style

Arijit Mondal; Sanhati Das; Amit Das; Sukanta Paul; Deb Kumar Mukherjee. Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media. Int. J. Environ. Chem. 2023, 7(2), 38-46. doi: 10.11648/j.ijec.20230702.12

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AMA Style

Arijit Mondal, Sanhati Das, Amit Das, Sukanta Paul, Deb Kumar Mukherjee. Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media. Int J Environ Chem. 2023;7(2):38-46. doi: 10.11648/j.ijec.20230702.12

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@article{10.11648/j.ijec.20230702.12,
  author = {Arijit Mondal and Sanhati Das and Amit Das and Sukanta Paul and Deb Kumar Mukherjee},
  title = {Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media},
  journal = {International Journal of Environmental Chemistry},
  volume = {7},
  number = {2},
  pages = {38-46},
  doi = {10.11648/j.ijec.20230702.12},
  url = {https://doi.org/10.11648/j.ijec.20230702.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijec.20230702.12},
  abstract = {Reduction of organophosphate group of pesticides catalyzed by bimetallic nickel cobalt nanoparticles (NiCoNPs) in presence of sodium borohydride has been discussed. An easy, simple, quick and economically feasible approach has been made to synthesize the good ordered structures of hetero nanoparticles. These air stable nanoclusters could be synthesized most economically using nickel sulphate and cobalt sulphate salts with tetrabutyl ammonium bromide as surfactant and sodium borohydride as reducing reagent. The nanoparticles were used to degrade pesticides like profenofos and imidacloprid under ambient conditions in aqueous media. The concentrations of Profenofos (PFF) were quantified by measuring the absorption intensities at λmax288 nm after treatment with KOH solution. The nickel nanocolloids in common organic solvents were found to be good catalysts for the reductive transformation of Profenofos but suffer considerable deactivation during recycling steps. The bimetallic group of particles containing cobalt and nickel however can be easily recovered and recycled three-four times without loss of catalytic activity. The bimetallic nanoclusters having average particle size 90-120 nm can degrade organophosphate group of pesticides within 120 minutes which is much less compared to photodegradation of such similar pesticides as reported in literatures. The study can become a protocol for waste water management with environmental benefits, strengthening the need of green chemistry in industrial projects.},
 year = {2023}
}

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TY  - JOUR
T1  - Metal Nanoparticles as Recyclable Catalysts for Reductive Transformation of Profenofos Pesticide in Aqueous Media
AU  - Arijit Mondal
AU  - Sanhati Das
AU  - Amit Das
AU  - Sukanta Paul
AU  - Deb Kumar Mukherjee
Y1  - 2023/08/10
PY  - 2023
N1  - https://doi.org/10.11648/j.ijec.20230702.12
DO  - 10.11648/j.ijec.20230702.12
T2  - International Journal of Environmental Chemistry
JF  - International Journal of Environmental Chemistry
JO  - International Journal of Environmental Chemistry
SP  - 38
EP  - 46
PB  - Science Publishing Group
SN  - 2640-1460
UR  - https://doi.org/10.11648/j.ijec.20230702.12
AB  - Reduction of organophosphate group of pesticides catalyzed by bimetallic nickel cobalt nanoparticles (NiCoNPs) in presence of sodium borohydride has been discussed. An easy, simple, quick and economically feasible approach has been made to synthesize the good ordered structures of hetero nanoparticles. These air stable nanoclusters could be synthesized most economically using nickel sulphate and cobalt sulphate salts with tetrabutyl ammonium bromide as surfactant and sodium borohydride as reducing reagent. The nanoparticles were used to degrade pesticides like profenofos and imidacloprid under ambient conditions in aqueous media. The concentrations of Profenofos (PFF) were quantified by measuring the absorption intensities at λmax288 nm after treatment with KOH solution. The nickel nanocolloids in common organic solvents were found to be good catalysts for the reductive transformation of Profenofos but suffer considerable deactivation during recycling steps. The bimetallic group of particles containing cobalt and nickel however can be easily recovered and recycled three-four times without loss of catalytic activity. The bimetallic nanoclusters having average particle size 90-120 nm can degrade organophosphate group of pesticides within 120 minutes which is much less compared to photodegradation of such similar pesticides as reported in literatures. The study can become a protocol for waste water management with environmental benefits, strengthening the need of green chemistry in industrial projects.
VL  - 7
IS  - 2
ER  -

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