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Isotherm Studies of Adsorption of Cr (Vi) Ions onto Coconut Husk

Received: 8 March 2017     Accepted: 20 January 2018     Published: 23 August 2018
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Abstract

In this study, the application of ground coconut husk GCH for removal of Cr (VI) from its aqueous solution was investigated. Several batch experiments were carried out with different values of test conditions including sorbent concentration, contact time, temperature and pH. The results obtained showed that adsorption of Cr (VI) followed Freundlich isotherm model. Dubinin-Radushkevich isotherm revealed that adsorption of the three metal ions principally followed chemical adsorption process. Adsorption kinetics was best described by pseudo-second order. Thermodynamic studies revealed that adsorption of Cr (VI) were endothermic process since ∆H was positive. Adsorption of Cr (VI) was spontaneous as evident from the negative value ∆G. Uptake of metal ion from their aqueous solution increases with increase in pH but decreases slightly at pH of 8.

Published in International Journal of Biochemistry, Biophysics & Molecular Biology (Volume 3, Issue 2)
DOI 10.11648/j.ijbbmb.20180302.13
Page(s) 38-44
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Chromium (VI), Adsorption, Coconut Husk

References
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Cite This Article
  • APA Style

    Egwuatu Chinyelu Ijeamaka, Odebeatu Chinonso Christian, Obumselu Onyeka Fabian, Iloamaeke Ifeoma MaryJane, Kammeje Tochukwu Joseph. (2018). Isotherm Studies of Adsorption of Cr (Vi) Ions onto Coconut Husk. International Journal of Biochemistry, Biophysics & Molecular Biology, 3(2), 38-44. https://doi.org/10.11648/j.ijbbmb.20180302.13

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    ACS Style

    Egwuatu Chinyelu Ijeamaka; Odebeatu Chinonso Christian; Obumselu Onyeka Fabian; Iloamaeke Ifeoma MaryJane; Kammeje Tochukwu Joseph. Isotherm Studies of Adsorption of Cr (Vi) Ions onto Coconut Husk. Int. J. Biochem. Biophys. Mol. Biol. 2018, 3(2), 38-44. doi: 10.11648/j.ijbbmb.20180302.13

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    AMA Style

    Egwuatu Chinyelu Ijeamaka, Odebeatu Chinonso Christian, Obumselu Onyeka Fabian, Iloamaeke Ifeoma MaryJane, Kammeje Tochukwu Joseph. Isotherm Studies of Adsorption of Cr (Vi) Ions onto Coconut Husk. Int J Biochem Biophys Mol Biol. 2018;3(2):38-44. doi: 10.11648/j.ijbbmb.20180302.13

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  • @article{10.11648/j.ijbbmb.20180302.13,
      author = {Egwuatu Chinyelu Ijeamaka and Odebeatu Chinonso Christian and Obumselu Onyeka Fabian and Iloamaeke Ifeoma MaryJane and Kammeje Tochukwu Joseph},
      title = {Isotherm Studies of Adsorption of Cr (Vi) Ions onto Coconut Husk},
      journal = {International Journal of Biochemistry, Biophysics & Molecular Biology},
      volume = {3},
      number = {2},
      pages = {38-44},
      doi = {10.11648/j.ijbbmb.20180302.13},
      url = {https://doi.org/10.11648/j.ijbbmb.20180302.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbbmb.20180302.13},
      abstract = {In this study, the application of ground coconut husk GCH for removal of Cr (VI) from its aqueous solution was investigated. Several batch experiments were carried out with different values of test conditions including sorbent concentration, contact time, temperature and pH. The results obtained showed that adsorption of Cr (VI) followed Freundlich isotherm model. Dubinin-Radushkevich isotherm revealed that adsorption of the three metal ions principally followed chemical adsorption process. Adsorption kinetics was best described by pseudo-second order. Thermodynamic studies revealed that adsorption of Cr (VI) were endothermic process since ∆H was positive. Adsorption of Cr (VI) was spontaneous as evident from the negative value ∆G. Uptake of metal ion from their aqueous solution increases with increase in pH but decreases slightly at pH of 8.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Isotherm Studies of Adsorption of Cr (Vi) Ions onto Coconut Husk
    AU  - Egwuatu Chinyelu Ijeamaka
    AU  - Odebeatu Chinonso Christian
    AU  - Obumselu Onyeka Fabian
    AU  - Iloamaeke Ifeoma MaryJane
    AU  - Kammeje Tochukwu Joseph
    Y1  - 2018/08/23
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ijbbmb.20180302.13
    DO  - 10.11648/j.ijbbmb.20180302.13
    T2  - International Journal of Biochemistry, Biophysics & Molecular Biology
    JF  - International Journal of Biochemistry, Biophysics & Molecular Biology
    JO  - International Journal of Biochemistry, Biophysics & Molecular Biology
    SP  - 38
    EP  - 44
    PB  - Science Publishing Group
    SN  - 2575-5862
    UR  - https://doi.org/10.11648/j.ijbbmb.20180302.13
    AB  - In this study, the application of ground coconut husk GCH for removal of Cr (VI) from its aqueous solution was investigated. Several batch experiments were carried out with different values of test conditions including sorbent concentration, contact time, temperature and pH. The results obtained showed that adsorption of Cr (VI) followed Freundlich isotherm model. Dubinin-Radushkevich isotherm revealed that adsorption of the three metal ions principally followed chemical adsorption process. Adsorption kinetics was best described by pseudo-second order. Thermodynamic studies revealed that adsorption of Cr (VI) were endothermic process since ∆H was positive. Adsorption of Cr (VI) was spontaneous as evident from the negative value ∆G. Uptake of metal ion from their aqueous solution increases with increase in pH but decreases slightly at pH of 8.
    VL  - 3
    IS  - 2
    ER  - 

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Author Information
  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

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