Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors

Vijay Shankar Pandey; Brajesh Kumar Shukla; Mithilesh Yadav

doi:doi:10.11648/j.ijbbmb.20170202.11

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Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors

Vijay Shankar Pandey, Brajesh Kumar Shukla, Mithilesh Yadav

Published in International Journal of Biochemistry, Biophysics & Molecular Biology (Volume 2, Issue 2)

Received: 10 March 2017 Accepted: 13 July 2017 Published: 1 August 2017

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Abstract

The present paper reports the modification of guar gum through the grafting of 2-acrylamidoglycolic acid by free radical polymerization using an efficient potassium peroxydiphosphate/thioacetamide redox system in nitrogen atmosphere. The reaction conditions for maximum grafting have been optimized by varying the reaction variables including the concentration of 2-acrylamidoglycolic acid (5.3×10^-2 mol dm^-3), potassium peroxydiphosphate (1.2×10^-2 mol dm^-3), thioacetamide (TA) (2×10^-3 mol dm^-3), sulphuric acid (4×10^-3 mol dm^-3), guar gum (1 g dm⁻³) along with time duration (150 min) and temperature (35°C). Water swelling capacity and flocculation and studies of synthesized graft copolymer have been performed with respect to the parent polymer. The graft copolymer has been characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.

Published in	International Journal of Biochemistry, Biophysics & Molecular Biology (Volume 2, Issue 2)
DOI	10.11648/j.ijbbmb.20170202.11
Page(s)	10-15
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Graftcopolymer, Fourier Transform Infrared Spectroscopy, Thermo Gravimetric Analysis

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Vijay Shankar Pandey, Brajesh Kumar Shukla, Mithilesh Yadav. (2017). Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors. International Journal of Biochemistry, Biophysics & Molecular Biology, 2(2), 10-15. https://doi.org/10.11648/j.ijbbmb.20170202.11

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ACS Style

Vijay Shankar Pandey; Brajesh Kumar Shukla; Mithilesh Yadav. Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors. Int. J. Biochem. Biophys. Mol. Biol. 2017, 2(2), 10-15. doi: 10.11648/j.ijbbmb.20170202.11

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AMA Style

Vijay Shankar Pandey, Brajesh Kumar Shukla, Mithilesh Yadav. Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors. Int J Biochem Biophys Mol Biol. 2017;2(2):10-15. doi: 10.11648/j.ijbbmb.20170202.11

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@article{10.11648/j.ijbbmb.20170202.11,
  author = {Vijay Shankar Pandey and Brajesh Kumar Shukla and Mithilesh Yadav},
  title = {Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors},
  journal = {International Journal of Biochemistry, Biophysics & Molecular Biology},
  volume = {2},
  number = {2},
  pages = {10-15},
  doi = {10.11648/j.ijbbmb.20170202.11},
  url = {https://doi.org/10.11648/j.ijbbmb.20170202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbbmb.20170202.11},
  abstract = {The present paper reports the modification of guar gum through the grafting of 2-acrylamidoglycolic acid by free radical polymerization using an efficient potassium peroxydiphosphate/thioacetamide redox system in nitrogen atmosphere. The reaction conditions for maximum grafting have been optimized by varying the reaction variables including the concentration of 2-acrylamidoglycolic acid (5.3×10-2 mol dm-3), potassium peroxydiphosphate (1.2×10-2 mol dm-3), thioacetamide (TA) (2×10-3 mol dm-3), sulphuric acid (4×10-3 mol dm-3), guar gum (1 g dm−3) along with time duration (150 min) and temperature (35°C). Water swelling capacity and flocculation and studies of synthesized graft copolymer have been performed with respect to the parent polymer. The graft copolymer has been characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.},
 year = {2017}
}

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TY  - JOUR
T1  - Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors
AU  - Vijay Shankar Pandey
AU  - Brajesh Kumar Shukla
AU  - Mithilesh Yadav
Y1  - 2017/08/01
PY  - 2017
N1  - https://doi.org/10.11648/j.ijbbmb.20170202.11
DO  - 10.11648/j.ijbbmb.20170202.11
T2  - International Journal of Biochemistry, Biophysics & Molecular Biology
JF  - International Journal of Biochemistry, Biophysics & Molecular Biology
JO  - International Journal of Biochemistry, Biophysics & Molecular Biology
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EP  - 15
PB  - Science Publishing Group
SN  - 2575-5862
UR  - https://doi.org/10.11648/j.ijbbmb.20170202.11
AB  - The present paper reports the modification of guar gum through the grafting of 2-acrylamidoglycolic acid by free radical polymerization using an efficient potassium peroxydiphosphate/thioacetamide redox system in nitrogen atmosphere. The reaction conditions for maximum grafting have been optimized by varying the reaction variables including the concentration of 2-acrylamidoglycolic acid (5.3×10-2 mol dm-3), potassium peroxydiphosphate (1.2×10-2 mol dm-3), thioacetamide (TA) (2×10-3 mol dm-3), sulphuric acid (4×10-3 mol dm-3), guar gum (1 g dm−3) along with time duration (150 min) and temperature (35°C). Water swelling capacity and flocculation and studies of synthesized graft copolymer have been performed with respect to the parent polymer. The graft copolymer has been characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.
VL  - 2
IS  - 2
ER  -

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Author Information

Vijay Shankar Pandey

Department of Chemistry, S. V. M. Science & Technology P. G. College, Pratapgarh, Uttar Pradesh, India
Brajesh Kumar Shukla

Department of Chemistry, University of Allahabad, Allahabad, India
Mithilesh Yadav

Department of Chemistry, Jamia Millia Islamia, New Delhi, India

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Vijay Shankar Pandey, Brajesh Kumar Shukla, Mithilesh Yadav. (2017). Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors. International Journal of Biochemistry, Biophysics & Molecular Biology, 2(2), 10-15. https://doi.org/10.11648/j.ijbbmb.20170202.11

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ACS Style

Vijay Shankar Pandey; Brajesh Kumar Shukla; Mithilesh Yadav. Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors. Int. J. Biochem. Biophys. Mol. Biol. 2017, 2(2), 10-15. doi: 10.11648/j.ijbbmb.20170202.11

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AMA Style

Vijay Shankar Pandey, Brajesh Kumar Shukla, Mithilesh Yadav. Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors. Int J Biochem Biophys Mol Biol. 2017;2(2):10-15. doi: 10.11648/j.ijbbmb.20170202.11

Copy | Download

@article{10.11648/j.ijbbmb.20170202.11,
  author = {Vijay Shankar Pandey and Brajesh Kumar Shukla and Mithilesh Yadav},
  title = {Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors},
  journal = {International Journal of Biochemistry, Biophysics & Molecular Biology},
  volume = {2},
  number = {2},
  pages = {10-15},
  doi = {10.11648/j.ijbbmb.20170202.11},
  url = {https://doi.org/10.11648/j.ijbbmb.20170202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbbmb.20170202.11},
  abstract = {The present paper reports the modification of guar gum through the grafting of 2-acrylamidoglycolic acid by free radical polymerization using an efficient potassium peroxydiphosphate/thioacetamide redox system in nitrogen atmosphere. The reaction conditions for maximum grafting have been optimized by varying the reaction variables including the concentration of 2-acrylamidoglycolic acid (5.3×10-2 mol dm-3), potassium peroxydiphosphate (1.2×10-2 mol dm-3), thioacetamide (TA) (2×10-3 mol dm-3), sulphuric acid (4×10-3 mol dm-3), guar gum (1 g dm−3) along with time duration (150 min) and temperature (35°C). Water swelling capacity and flocculation and studies of synthesized graft copolymer have been performed with respect to the parent polymer. The graft copolymer has been characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Graft Copolymer (Guar Gum-G-Poly 2-Acrylamidoglycolic Acid): Synthesis, Swelling and Flocculation Behaviors
AU  - Vijay Shankar Pandey
AU  - Brajesh Kumar Shukla
AU  - Mithilesh Yadav
Y1  - 2017/08/01
PY  - 2017
N1  - https://doi.org/10.11648/j.ijbbmb.20170202.11
DO  - 10.11648/j.ijbbmb.20170202.11
T2  - International Journal of Biochemistry, Biophysics & Molecular Biology
JF  - International Journal of Biochemistry, Biophysics & Molecular Biology
JO  - International Journal of Biochemistry, Biophysics & Molecular Biology
SP  - 10
EP  - 15
PB  - Science Publishing Group
SN  - 2575-5862
UR  - https://doi.org/10.11648/j.ijbbmb.20170202.11
AB  - The present paper reports the modification of guar gum through the grafting of 2-acrylamidoglycolic acid by free radical polymerization using an efficient potassium peroxydiphosphate/thioacetamide redox system in nitrogen atmosphere. The reaction conditions for maximum grafting have been optimized by varying the reaction variables including the concentration of 2-acrylamidoglycolic acid (5.3×10-2 mol dm-3), potassium peroxydiphosphate (1.2×10-2 mol dm-3), thioacetamide (TA) (2×10-3 mol dm-3), sulphuric acid (4×10-3 mol dm-3), guar gum (1 g dm−3) along with time duration (150 min) and temperature (35°C). Water swelling capacity and flocculation and studies of synthesized graft copolymer have been performed with respect to the parent polymer. The graft copolymer has been characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.
VL  - 2
IS  - 2
ER  -

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