In the present investigation, a three-step electrochemical as a novel method has been applied to fabricate multinanoporous thin film electrodes of pure TiO2 and the doped Pt-TiO2 (of approximately 15 nm) from the titanium sheet using sulfuric acid as electrolyte and chloroplatinic acid as platinum dopant precursor. Characterization techniques so far discussed in this work revealed that the fabricated products corresponded to pure TiO2 and to the doped Pt-TiO2 respectively. The prepared Pt-TiO2 thin film electrodes have photoresponse to visible light, which indicates a new possibility for improving intrinsic TiO2 photoresponse.
Published in | American Journal of Nanosciences (Volume 5, Issue 1) |
DOI | 10.11648/j.ajn.20190501.12 |
Page(s) | 9-17 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2019. Published by Science Publishing Group |
Pt-TiO2 Films, Anodic Oxidation, Visible Photo Response, Doping
[1] | Yan. W., Yungeng Z, Peichen L, IOP Conference Series, Earth and Environmental Science, 81 (1), (2017): 012-022. |
[2] | Piskalis Sahaya M K, Vinoh Kumar P, Koolath Rama K et al., J. Mater. Chem. A, 6, (2018), 23435–23444. |
[3] | Luis F. Arenas, Carlos Ponce de Leon, Richard P. Boardman, et al., Journal of The Electrochemical Society, 164 (2), (2017), D57-D66. |
[4] | Changkun Z, Hongmei Y, Yongkun L et al., Journal of Electroanalytical Chemistry 701 (2013), 14-19. |
[5] | Shaddad M. N., Al-Mayouf A. M., Ghanem M. A., et al., Int. J. Electrochem. Sci., 8 (2013), 2468 – 2478. |
[6] | Fereshteh C, Samira B, Sharifah B, et al., Sensors and Actuators B, 177 (2013), 898– 903. |
[7] | Agata MS, Paulina R, Kunlei W et al., Catalysts, 8 (8), (2018). 316-319. |
[8] | Der-Shan S, Jyh-Hwa K, Yaohsuan T et al., Nanomaterials, 6 (12), (2016), 237–239. |
[9] | Jadranka M, Sladana M, Nikola C et al., J. Electrochem. Soc, 165 (15), (2018), J 3253-J3258. |
[10] | Jinbo Z, Nan S, Faguan Z et al., RSC Advances, 7 (89), (2017), 56194-56203. |
[11] | Hang S. Qinrong H. Sahn Z, et al., New J. Chem 41, (2017), 7244-7252. |
[12] | Rettew R. E., Allam N. K., Alamgir F. M., et al., ACS Appl. Mater. Interfaces, 3, (2011), 147-149. |
[13] | Jinbo Z, Xuilan H, Faguan Z et al., Nanotechnology, 28 (50), (2017), 56194-56203. |
[14] | Košević M, Šekularac G, Živković L et al., Croat. Chem. Acta 90 (2) (2017), 251–258. |
[15] | Changkun Z, Hongmei Y, Yongkun et al., Journal of Electroanalytical Chemistry 701, (2013), 14–19. |
[16] | Shaddad M. N., Al-Mayouf A. M., Ghanem M. A., et al., Int. J. Electrochem. Sci. 8, (2013), 2468 – 2478. |
[17] | Susan S, Luis C Silvia, Maria E M., et al., Electrochimica Acta, 35 (6), (2017). |
[18] | Ekoko B. Gracien, Joseph K-K. Lobo, Omer M. Mvele et al., South African Journal of Chemistry, 66, (2013), 1-6. |
[19] | Ekoko B, Lobo K-K, Mvele M, et al., Pan African and South African Meeting of the International Year of Crystallography (IYCr 2014 Africa), 12-17, Octobre 2014, Bloemfontein, South Africa. |
[20] | Ekoko B Gracien, Jianian S, XianRong S, Dong Liu, et al, Photocatalytic activity of manganese, chromium and cobalt doped- anatase TiO2 nanoporous electrodes produced by re-anodization method. Thin Solid Films, Vol. 515, No 13, (2007), 5287-5297. |
[21] | Jianian S, Moucheng L, Dong L, et al, Effects of applied bias and dopants on the photocatalytic degradation of aqueous dye solution by TiO2/Ti electrode. Materials Science Forum, Vols. 539-543, (2007), 2240-2245. |
[22] | Ekoko Bakambo G., Joseph K. K. Lobo, Omer M. Mvele, et al, Effect of an external applied potential on the photocatalytic properties of manganese-doped titanium dioxide, American Journal of Physical Chemistry, 3 (4), (2014), 41-46. |
[23] | Toto Mabiala M, Albert Kazadi M B, Gracian Ekoko B et al, International Journal of Materials Science and Applications. 5 (5), (2016), 207-213. |
[24] | He Y. J., Peng J. F., Chu W et al, J. Mater. Chem. A, 2, (2014), 1721. |
[25] | Ismail A. A., Robben L., Bahnemann D. W, Chem Phys Chem, 12, (2011), 982. |
[26] | Zhang X., Zhou G, Xu J et al, Journal of Solid State Chemistry, 183 (2010), 1394–1399. |
[27] | Wagner, C. D. Naumkin A. V, Kraut-Vass A. et al., NIST X-ray Photoelectron Spectroscopy Database NIST Standard Reference Database 20, (2003), Version 3.5. |
[28] | Krstajic N. V, Vracar L. M, Radmilovic V. R, et al., Surf. Sci. 601 (2007) 1949–1966. |
[29] | Zhang J, Zhang M, Jin Z et al., Appl. Surf. Sci. 258 (2012) 3991–3999. |
[30] | Kuznetsov M. V, Ju. F. Zhuravlev, et al., J. Electron. Spectrosc. Relat. Phenom. 58 (1), (1992), 145. |
[31] | Mayer J. T., Diebold U, Madey T. E et al., J. Electron. Spectrosc. Relat. Phenom. 73 (1), (1995), 65. |
[32] | Zhao G. L, Kozuka H., Yoko T, Thin Solid Films, 277, (1996), 147-154. |
[33] | Li F. B., Li X. Z., Chromosphere, 48, (2002), 1103-1111. |
[34] | Kamat P. V, J. Phys. Chem. B, 106, (2002), 7729-7744. |
[35] | Kamat P. V, Pure Appl. Chem., 74, (2002), 1693-1706. |
[36] | Sasaki T, Koshizaki N, Yoon J. W et al., J. Photochem. Photobiol. A, 145, (2001), 11-16. |
[37] | Ohsaka T., Izumi F, Fujiki Y, J. Raman Spectrosc., 7, (1978), 321-324. |
[38] | Balachandran U, Eror N. G, J. Solid State Chem., 42, (1982), 276-282. |
APA Style
Ekoko Bakambo Gracien, Muswema Lunguya Jérémie, Mbongo Kimpanza Antoine, Nzazi Kambamba Nicole, Nduku Mafwa Fabrice, et al. (2019). Characterization of Multinanoporous Pt-TiO2 Thin Films Fabricated by a Three-Step Electrochemical Technique. American Journal of Nanosciences, 5(1), 9-17. https://doi.org/10.11648/j.ajn.20190501.12
ACS Style
Ekoko Bakambo Gracien; Muswema Lunguya Jérémie; Mbongo Kimpanza Antoine; Nzazi Kambamba Nicole; Nduku Mafwa Fabrice, et al. Characterization of Multinanoporous Pt-TiO2 Thin Films Fabricated by a Three-Step Electrochemical Technique. Am. J. Nanosci. 2019, 5(1), 9-17. doi: 10.11648/j.ajn.20190501.12
AMA Style
Ekoko Bakambo Gracien, Muswema Lunguya Jérémie, Mbongo Kimpanza Antoine, Nzazi Kambamba Nicole, Nduku Mafwa Fabrice, et al. Characterization of Multinanoporous Pt-TiO2 Thin Films Fabricated by a Three-Step Electrochemical Technique. Am J Nanosci. 2019;5(1):9-17. doi: 10.11648/j.ajn.20190501.12
@article{10.11648/j.ajn.20190501.12, author = {Ekoko Bakambo Gracien and Muswema Lunguya Jérémie and Mbongo Kimpanza Antoine and Nzazi Kambamba Nicole and Nduku Mafwa Fabrice and Musengele Bilasi Denis and Kidingi Kambasi Pierre and Ndonganzadi Tresor and Mukiatom Perbom}, title = {Characterization of Multinanoporous Pt-TiO2 Thin Films Fabricated by a Three-Step Electrochemical Technique}, journal = {American Journal of Nanosciences}, volume = {5}, number = {1}, pages = {9-17}, doi = {10.11648/j.ajn.20190501.12}, url = {https://doi.org/10.11648/j.ajn.20190501.12}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20190501.12}, abstract = {In the present investigation, a three-step electrochemical as a novel method has been applied to fabricate multinanoporous thin film electrodes of pure TiO2 and the doped Pt-TiO2 (of approximately 15 nm) from the titanium sheet using sulfuric acid as electrolyte and chloroplatinic acid as platinum dopant precursor. Characterization techniques so far discussed in this work revealed that the fabricated products corresponded to pure TiO2 and to the doped Pt-TiO2 respectively. The prepared Pt-TiO2 thin film electrodes have photoresponse to visible light, which indicates a new possibility for improving intrinsic TiO2 photoresponse.}, year = {2019} }
TY - JOUR T1 - Characterization of Multinanoporous Pt-TiO2 Thin Films Fabricated by a Three-Step Electrochemical Technique AU - Ekoko Bakambo Gracien AU - Muswema Lunguya Jérémie AU - Mbongo Kimpanza Antoine AU - Nzazi Kambamba Nicole AU - Nduku Mafwa Fabrice AU - Musengele Bilasi Denis AU - Kidingi Kambasi Pierre AU - Ndonganzadi Tresor AU - Mukiatom Perbom Y1 - 2019/08/13 PY - 2019 N1 - https://doi.org/10.11648/j.ajn.20190501.12 DO - 10.11648/j.ajn.20190501.12 T2 - American Journal of Nanosciences JF - American Journal of Nanosciences JO - American Journal of Nanosciences SP - 9 EP - 17 PB - Science Publishing Group SN - 2575-4858 UR - https://doi.org/10.11648/j.ajn.20190501.12 AB - In the present investigation, a three-step electrochemical as a novel method has been applied to fabricate multinanoporous thin film electrodes of pure TiO2 and the doped Pt-TiO2 (of approximately 15 nm) from the titanium sheet using sulfuric acid as electrolyte and chloroplatinic acid as platinum dopant precursor. Characterization techniques so far discussed in this work revealed that the fabricated products corresponded to pure TiO2 and to the doped Pt-TiO2 respectively. The prepared Pt-TiO2 thin film electrodes have photoresponse to visible light, which indicates a new possibility for improving intrinsic TiO2 photoresponse. VL - 5 IS - 1 ER -