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Morphological and Optical Properties of Pure and Mg Doped Tin Oxide Thin Films Prepared by Spray Pyrolysis Method

Received: 8 February 2017     Accepted: 1 March 2017     Published: 8 May 2017
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Abstract

Pure Tin Oxide (SnO2) and Magnesium (Mg) doped SnO2 thin films have been deposited onto glass substrates by spray pyrolysis technique at the substrate temperature of 450°C. The doping concentration of Mg was varied from 1 to 9 wt% (with 2 wt% step) while all other deposition parameters such as substrate temperature, spray rate, carrier gas pressure and distance between spray nozzle to substrate were kept constant. The surface morphology and optical properties of the deposited thin films have been studied by Scanning Electron Microscopy (SEM) and UV visible spectroscopy. Average optical transmittance in the 400–900 nm range varies from 18.21% to 58.99% with varying Mg concentration in the film. Maximum band gap value of 3.90 eV is obtained for undoped SnO2.

Published in American Journal of Nanosciences (Volume 3, Issue 2)
DOI 10.11648/j.ajn.20170302.11
Page(s) 19-23
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Thin Films, Spray Pyrolysis, Mg Doped Tin Oxide, Optical Properties, Scanning Electron Microscope

References
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[2] S. S. ROY, J. PODDER (2010), “Synthesis and optical characterization of pure and Cu doped SnO2 thin films deposited by spray pyrolysis”, Journal of Optoelectronics and Advanced Materials, Vol. 12, No. 7, pp. 1479-1484.
[3] TURGUT G., KESKENLER E. F., Aydin S., SONMEZ E., DOGAN S., DUZGUN B., ERTUGRUL M. (2013), “Effect of Nb Doping on Structural, Electrical and Optical Properties of Spray Deposited SnO2 Thin Films”, Super lattices and Microstructures, 56, pp. 107-116.
[4] GANDHI T., BABU R. & RAMAMURTHI K. (2013) “Structural, Morphological, Electrical and Optical Studies of Cr Doped SnO2 Thin Films Deposited by The Spray Pyrolysis Technique”, Materials Science in Semiconductor Processing, 16, pp. 427-479.
[5] JARZEBSKI Z. & MARTON J. (1976) “Physical Properties of SnO2 Materials”, Journal of the Electrochemical Society, pp. 199-205.
[6] KHANAA V. & MOHANTA K. (2013) “Synthesis and Structural Characterization of SnO2 Thin Films Prepared by Spray Pyrolysis Technique”, International Journal of Advanced Research, 1 (7), pp. 666-669.
[7] RAÜL DÍAZ DELGADO, “Tin Oxide Gas Sensors: An Electrochemical Approach”, Ph. D Thesis, Universitat De Barcelona, 2002.
[8] MOHAMMAD-MEHDI BAGHERI-MOHAGHEGHI, MEHRDAD SHOKOOH-SAREMI (2004) “Electrical, Optical and Structural Properties of Li-Doped SnO2 Transparent Conducting Films Deposited by The Spray Pyrolysis Technique: a Carrier-Type Conversion Study”, Semiconductor Science and Technology, 19, pp. 764-769.
[9] A. R. BABAR, S. S. SHINDE, A. V. MOHOLKAR, C. H. BHOSALE, J. H. KIM, K. Y. RAJPURE (2010) “Structural and Optoelectronic Properties of Antimony Incorporated Tin Oxide Thin Films”, Journal of Alloys and Compounds, pp. 416-422.
[10] VIJAYALAKSHMI S., VENKATARAJ S., Subramanian M., JAYAVEL R. (2008) “Physical Properties Of Zinc Doped Tin Oxide Films Prepared by Spray Pyrolysis Technique”, Journal of Physics D: Applied Physics, 41, pp. 210-216.
[11] PEREDNIS D. & GAUCKLER L. (2005) “Thin Film Deposition Using Spray Pyrolysis”, Journal of Electroceramics, 14, pp. 103-111.
[12] BABAR A. & RAJPURE K. Y. (2015) “Effect of Intermittent Time on Structural, Optoelectronic, Luminescence Properties of Sprayed Antimony Doped Tin Oxide Thin Films”, Journal of Analytical and Applied Pyrolysis, 112, pp. 214-220.
[13] T. INDIRA GANDHI, R. RAMESH BABU, K. RAMAMURTHI, M. ARIVANANDHAN (2016) “Effect of Mn Doping on The Electrical and Optical Properties of SnO2 Thin Films Deposited by Chemical Spray Pyrolysis Technique”, Thin Solid Films, 598, pp. 195-203.
[14] SIBEL GÜRAKAR, TÜLAY SERIN, NECMI SERIN (2014) “Electrical and microstructural properties of (Cu, Al, In)-doped SnO2 films deposited by spray pyrolysis”, Advanced Materials Letters, 5 (6), pp. 309-314.
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  • APA Style

    Abdul Rahman Abdul Aziz Sakhta, Ahmad Hamed Khdro, Ali Naji Darwisho. (2017). Morphological and Optical Properties of Pure and Mg Doped Tin Oxide Thin Films Prepared by Spray Pyrolysis Method. American Journal of Nanosciences, 3(2), 19-23. https://doi.org/10.11648/j.ajn.20170302.11

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    ACS Style

    Abdul Rahman Abdul Aziz Sakhta; Ahmad Hamed Khdro; Ali Naji Darwisho. Morphological and Optical Properties of Pure and Mg Doped Tin Oxide Thin Films Prepared by Spray Pyrolysis Method. Am. J. Nanosci. 2017, 3(2), 19-23. doi: 10.11648/j.ajn.20170302.11

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    AMA Style

    Abdul Rahman Abdul Aziz Sakhta, Ahmad Hamed Khdro, Ali Naji Darwisho. Morphological and Optical Properties of Pure and Mg Doped Tin Oxide Thin Films Prepared by Spray Pyrolysis Method. Am J Nanosci. 2017;3(2):19-23. doi: 10.11648/j.ajn.20170302.11

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  • @article{10.11648/j.ajn.20170302.11,
      author = {Abdul Rahman Abdul Aziz Sakhta and Ahmad Hamed Khdro and Ali Naji Darwisho},
      title = {Morphological and Optical Properties of Pure and Mg Doped Tin Oxide Thin Films Prepared by Spray Pyrolysis Method},
      journal = {American Journal of Nanosciences},
      volume = {3},
      number = {2},
      pages = {19-23},
      doi = {10.11648/j.ajn.20170302.11},
      url = {https://doi.org/10.11648/j.ajn.20170302.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20170302.11},
      abstract = {Pure Tin Oxide (SnO2) and Magnesium (Mg) doped SnO2 thin films have been deposited onto glass substrates by spray pyrolysis technique at the substrate temperature of 450°C. The doping concentration of Mg was varied from 1 to 9 wt% (with 2 wt% step) while all other deposition parameters such as substrate temperature, spray rate, carrier gas pressure and distance between spray nozzle to substrate were kept constant. The surface morphology and optical properties of the deposited thin films have been studied by Scanning Electron Microscopy (SEM) and UV visible spectroscopy. Average optical transmittance in the 400–900 nm range varies from 18.21% to 58.99% with varying Mg concentration in the film. Maximum band gap value of 3.90 eV is obtained for undoped SnO2.},
     year = {2017}
    }
    

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    T1  - Morphological and Optical Properties of Pure and Mg Doped Tin Oxide Thin Films Prepared by Spray Pyrolysis Method
    AU  - Abdul Rahman Abdul Aziz Sakhta
    AU  - Ahmad Hamed Khdro
    AU  - Ali Naji Darwisho
    Y1  - 2017/05/08
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ajn.20170302.11
    DO  - 10.11648/j.ajn.20170302.11
    T2  - American Journal of Nanosciences
    JF  - American Journal of Nanosciences
    JO  - American Journal of Nanosciences
    SP  - 19
    EP  - 23
    PB  - Science Publishing Group
    SN  - 2575-4858
    UR  - https://doi.org/10.11648/j.ajn.20170302.11
    AB  - Pure Tin Oxide (SnO2) and Magnesium (Mg) doped SnO2 thin films have been deposited onto glass substrates by spray pyrolysis technique at the substrate temperature of 450°C. The doping concentration of Mg was varied from 1 to 9 wt% (with 2 wt% step) while all other deposition parameters such as substrate temperature, spray rate, carrier gas pressure and distance between spray nozzle to substrate were kept constant. The surface morphology and optical properties of the deposited thin films have been studied by Scanning Electron Microscopy (SEM) and UV visible spectroscopy. Average optical transmittance in the 400–900 nm range varies from 18.21% to 58.99% with varying Mg concentration in the film. Maximum band gap value of 3.90 eV is obtained for undoped SnO2.
    VL  - 3
    IS  - 2
    ER  - 

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Author Information
  • Department of Physics, Faculty of Science, Tishreen University, Latakia, Syria

  • Department of Physics, Faculty of Science, Tishreen University, Latakia, Syria

  • Department of Physics, Faculty of Science, Tishreen University, Latakia, Syria

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