Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions

Khakkulov Jakhongir Mardonovich; Kholmuminov Abdufatto Akhatovich

doi:doi:10.11648/j.ajmp.20221106.11

| Peer-Reviewed

Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions

Khakkulov Jakhongir Mardonovich, Kholmuminov Abdufatto Akhatovich

Published in American Journal of Modern Physics (Volume 11, Issue 6)

Received: 18 August 2022 Accepted: 14 September 2022 Published: 10 January 2023

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.

Published in	American Journal of Modern Physics (Volume 11, Issue 6)
DOI	10.11648/j.ajmp.20221106.11
Page(s)	92-94
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Macroion, Fibroin, Chitosan, Viscosity, Solution, Macromolecules

References

[1]	S. Hina, Y. Zhang and H. Wang. Rev. Adv. Mater Sci. 36 (2014) 165-176 p.
[2]	Picout DR, Ross-Murphy SB. Rheology of biopolymer solutions and gels. Scientific World Journal. 2003 Mar 24; 3: 105-21. doi: 10.1100/tsw.2003.15. PMID: 12806124; PMCID: PMC5974903.
[3]	Marucho M. A Java Application to Characterize Biomolecules and Nanomaterials in Electrolyte Aqueous Solutions. Comput Phys Commun. 2019 Sep; 242: 104-119. doi: 10.1016/j.cpc.2019.03.022. Epub 2019 Apr 30. PMID: 31827306; PMCID: PMC6905646.
[4]	Hamman JH. Chitosan based polyelectrolyte complexes as potential carrier materials in drug delivery systems. Mar Drugs. 2010 Apr 19; 8 (4): 1305-22. doi: 10.3390/md8041305. PMID: 20479980; PMCID: PMC2866488.
[5]	Singh R, Shitiz K, Singh A. Chitin and chitosan: biopolymers for wound management. Int Wound J. 2017 Dec; 14 (6): 1276-1289. doi: 10.1111/iwj.12797. Epub 2017 Aug 10. PMID: 28799228; PMCID: PMC7949833.
[6]	Khakkulov J. M. Chitosan and fibroin polyelectrolyte solutions and molecular characteristics. Republican Scientific Conference “Modern Problems of Polymer Science” 25-26 November 2020 p. 88-90.
[7]	Martin A. Masuelli. Intrinsic Viscosity Determination of High Molecular Weight Biopolymers by Different Plot Methods. Chia Gum Case. Journal of Polymer and Biopolymer Physics Chemistry. 2018, 6 (1), 13-25. Available online at http://pubs.sciepub.com/jpbpc/6/1/2
[8]	Gao, S.; Holkar, A.; Srivastava, S. Protein -Polyelectrolyte Complexes and Micellar Assemblies. Polymers 2019, 11, 1097. https://doi.org/10.3390/polym11071097.
[9]	Park J. W., Baik B. S. et al. The role of hyaluronic acid, chitosan, and calcium sulfate and their combined effect on early bony consolidation in distraction osteogenesis of a canine model // J. Craniofac. Surg. – 2002. – Vol. 13. – P. 783-793.
[10]	Kozlov G. V., Dolbin I. V. High molecular weight compounds. Series B, 2020. Vol. 44 No. 1. P. 115-118.
[11]	J. M. Khakkulov, Z. Sh. Temirov, & Sh. E. Khalilov. (2021). Electrochemical Reduction of Macroiones As A Surface-Active Nanocoating And Nanocomposites. The American Journal of Applied Sciences, 3 (06), 34–43. https://doi.org/10.37547/tajas/Volume03Issue06-06
[12]	Meenesh R. Singh, Youngkook Kwon, Yanwei Lum, Joel W. Ager, and Alexis T. Bell. Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO₂ over Ag and Cu. https://doi.org/10.1021/jacs.6b07612
[13]	Zhen Yao, Shao-jie Liu, Fei Lv, Kun Cao., Determination of Mark–Houwink parameters of ethylene–norbornene copolymers and molecular characteristics estimation. https://doi.org/10.1002/app.28498
[14]	Capitani, M. I., Corzo-Rios, L. J., Chel-Guerrero, L. A., BetancurAncona, D. A., Nolasco, S. M., & Tomás, M. C. (2015). Rheological properties of aqueous dispersions of chia (Salvia hispanica L.) mucilage. Journal of food engineering, 149, 70-77.
[15]	Masuelli, M. A. 2014. Mark-Houwink parameters for aqueoussoluble polymers and biopolymers at various temperatures. J. Pol. Biopol. Phys. Chem., 2, 2, 37-43.

Cite This Article

Plain Text BibTeX RIS

APA Style

Khakkulov Jakhongir Mardonovich, Kholmuminov Abdufatto Akhatovich. (2023). Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. American Journal of Modern Physics, 11(6), 92-94. https://doi.org/10.11648/j.ajmp.20221106.11

Copy | Download

ACS Style

Khakkulov Jakhongir Mardonovich; Kholmuminov Abdufatto Akhatovich. Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. Am. J. Mod. Phys. 2023, 11(6), 92-94. doi: 10.11648/j.ajmp.20221106.11

Copy | Download

AMA Style

Khakkulov Jakhongir Mardonovich, Kholmuminov Abdufatto Akhatovich. Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. Am J Mod Phys. 2023;11(6):92-94. doi: 10.11648/j.ajmp.20221106.11

Copy | Download

@article{10.11648/j.ajmp.20221106.11,
  author = {Khakkulov Jakhongir Mardonovich and Kholmuminov Abdufatto Akhatovich},
  title = {Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions},
  journal = {American Journal of Modern Physics},
  volume = {11},
  number = {6},
  pages = {92-94},
  doi = {10.11648/j.ajmp.20221106.11},
  url = {https://doi.org/10.11648/j.ajmp.20221106.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmp.20221106.11},
  abstract = {Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.},
 year = {2023}
}

Copy | Download

TY  - JOUR
T1  - Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions
AU  - Khakkulov Jakhongir Mardonovich
AU  - Kholmuminov Abdufatto Akhatovich
Y1  - 2023/01/10
PY  - 2023
N1  - https://doi.org/10.11648/j.ajmp.20221106.11
DO  - 10.11648/j.ajmp.20221106.11
T2  - American Journal of Modern Physics
JF  - American Journal of Modern Physics
JO  - American Journal of Modern Physics
SP  - 92
EP  - 94
PB  - Science Publishing Group
SN  - 2326-8891
UR  - https://doi.org/10.11648/j.ajmp.20221106.11
AB  - Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.
VL  - 11
IS  - 6
ER  -

Copy | Download

Author Information

Khakkulov Jakhongir Mardonovich

"Physics of Semiconductors and Polymers" Department, Faculty of Physics, National University of Uzbekistan Named After M. Ulugbek, Tashkent, Republic of Uzbekistan
Kholmuminov Abdufatto Akhatovich

"Physics of Semiconductors and Polymers" Department, Faculty of Physics, National University of Uzbekistan Named After M. Ulugbek, Tashkent, Republic of Uzbekistan

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Khakkulov Jakhongir Mardonovich, Kholmuminov Abdufatto Akhatovich. (2023). Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. American Journal of Modern Physics, 11(6), 92-94. https://doi.org/10.11648/j.ajmp.20221106.11

Copy | Download

ACS Style

Khakkulov Jakhongir Mardonovich; Kholmuminov Abdufatto Akhatovich. Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. Am. J. Mod. Phys. 2023, 11(6), 92-94. doi: 10.11648/j.ajmp.20221106.11

Copy | Download

AMA Style

Khakkulov Jakhongir Mardonovich, Kholmuminov Abdufatto Akhatovich. Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions. Am J Mod Phys. 2023;11(6):92-94. doi: 10.11648/j.ajmp.20221106.11

Copy | Download

@article{10.11648/j.ajmp.20221106.11,
  author = {Khakkulov Jakhongir Mardonovich and Kholmuminov Abdufatto Akhatovich},
  title = {Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions},
  journal = {American Journal of Modern Physics},
  volume = {11},
  number = {6},
  pages = {92-94},
  doi = {10.11648/j.ajmp.20221106.11},
  url = {https://doi.org/10.11648/j.ajmp.20221106.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmp.20221106.11},
  abstract = {Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.},
 year = {2023}
}

Copy | Download

TY  - JOUR
T1  - Polyelektrolite Solutions and Molecular Descriptions of Biopolymer Macroions
AU  - Khakkulov Jakhongir Mardonovich
AU  - Kholmuminov Abdufatto Akhatovich
Y1  - 2023/01/10
PY  - 2023
N1  - https://doi.org/10.11648/j.ajmp.20221106.11
DO  - 10.11648/j.ajmp.20221106.11
T2  - American Journal of Modern Physics
JF  - American Journal of Modern Physics
JO  - American Journal of Modern Physics
SP  - 92
EP  - 94
PB  - Science Publishing Group
SN  - 2326-8891
UR  - https://doi.org/10.11648/j.ajmp.20221106.11
AB  - Molecular mass characteristics of samples of ionic biopolymers, including chitosan and fibroin, the manifestation of physical conditions depending on the concentration of macroions, and hydrodynamic, rheological methods were used in the implementation of these studies. These processes depend on the fact that ionic polymers exhibit viscosity in relation to their molecular mass and are sensitive to the effects of the electric field at the expense of ionogenic groups. In order to determine this, the results of studies on the molecular characteristics of basic polymer objects were discussed. When polyelectrolytes are affected by external forces, including mechanical or electrical stresses, gradient fields are created, and macroions move along the lines of force of these fields. Such fields are observed, for example, when a liquid flows from a capillary under mechanical pressure, when the liquid is turned into a stable laminar flow using a rotor, or when ions and macroions move towards the poles (electrodes) during electrophoresis and electrolysis. In general, in the gradient field created under the influence of mechanical influence, the macroions move along the lines of force in rotation and advance, while in the gradient field created under the influence of electric voltage, the functional groups of macroions move towards the anode or cathode as anions or cations. The reason for the choice of poles is the sensitivity of anions or cations to the effect of an electric field.
VL  - 11
IS  - 6
ER  -

Copy | Download